Related papers: Interfacial Reactions: Mixed Order Kinetics and Se…
We consider a diffusion-limited reaction in case the reacting entities are not available simultaneously. Due to the fact that the reaction takes place after a spatiotemporal accumulation of reactants, the underlying rate equation has to be…
We study the effects of an external electric field on both the motion of the reaction zone and the spatial distribution of the reaction product, $C$, in an irreversible $A^- +B^+ \to C$ reaction-diffusion process. The electrolytes $A\equiv…
Extensive simulations are performed of the diffusion-limited reaction A$+$B$\to 0$ in one dimension, with initially separated reagents. The reaction rate profile, and the probability distributions of the separation and midpoint of the…
We study theoretically and numerically the steady state diffusion controlled reaction $A+B\rightarrow\emptyset$, where currents $J$ of $A$ and $B$ particles are applied at opposite boundaries. For a reaction rate $\lambda$, and equal…
The long time behavior of a model for a first order, weakly reversible chemical reaction network is considered, where the movement of the reacting species is described by kinetic transport. The reactions are triggered by collisions with a…
We examine the long time behaviour of A+B->0 reaction diffusion systems with initially segregated species A and B. All of our analysis is carried out for arbitrary (positive) values of the diffusion constants $D_A$, $D_B$, and initial…
We study the effect of fractal initial conditions in closed reactive systems in the cases of both mobile and immobile reactants. For the reaction $A+A\to A$, in the absence of diffusion, the mean number of particles $A$ is shown to decay…
We propose a simple model for reaction-diffusion systems with orientational constraints on the reactivity of particles, and map it onto a field theory with upper critical dimension d_c=2. To two-loop level the long-time particle density…
Spatial scale separation often leads to sharp interfaces that can be fully localized pulses or transition layer fronts connecting different states. This paper concerns the asymptotic interaction laws of pulses and fronts in the so-called…
We consider the properties of the diffusion controlled reaction A+B->0 in the steady state, where fixed currents of A and B particles are maintained at opposite edges of the system. Using renormalisation group methods, we explicitly…
Kinetics of model catalytic processes proceeding on inhomogeneous surfaces is studied. We employ an extended mean-field model that takes into account surface inhomogeneities. The influence of surface diffusion of adsorbent on the kinetics…
Atomistic simulations are used to study segregation-induced intergranular film formation in Cu-Zr and Cu-Nb alloys. While Cu-Zr forms structurally disordered or amorphous films, ordered films comprised of a second phase usually precipitate…
We derive the long-time behavior of the ${A} + {B} \to \emptyset$ reaction in two dimensions, finding a universal exponent and prefactor in the absence of disorder. Sufficiently singular disorder leads to a (sub)diffusion-limited reaction…
A theory is constructed for dense ionic solutions near charged planar walls that is valid for strong inter-ionic correlations. This theory predicts a fluctuation-induced, first-order transition and spontaneous charge density ordering at the…
We study dynamics of filling of an initially empty finite medium by diffusing particles $A$ and $B$, which arise on the surface upon dissociation of $AB$ molecules, impinging on it with a fixed flux density $I$, and desorb from it by the…
We study the kinetics of two-species annihilation, A+B--->0, when all particles undergo strictly biased motion in the same direction and with an excluded volume repulsion between same species particles. It was recently shown that the…
Originating from the pioneering study of Alan Turing, the bifurcation analysis predicting spatial pattern formation from a spatially uniform state for diffusing morphogens or chemical species that interact through nonlinear reactions is a…
The kinetics of dislocation reactions, such as dislocation multiplication, controls the plastic deformation in crystals beyond their elastic limit, therefore critical mechanisms in a number of applications in materials science. We present a…
We discuss stationary concentrations of reactants in an A + B -> 0 reaction under subdiffusion and show that they are described by stationary reaction-diffusion equations with a nonlinear diffusion term. We consider stationary profiles of…
We investigate the subtle effects of diffuse charge on interfacial kinetics by solving the governing equations for ion transport (Nernst-Planck) with realistic boundary conditions representing reaction kinetics (Butler-Volmer) and…