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We develop a theory of reversible diffusion-controlled reactions with generalized binding/unbinding kinetics. In this framework, a diffusing particle can bind to the reactive substrate after a random number of arrivals onto it, with a given…

Chemical Physics · Physics 2023-10-03 Denis S. Grebenkov

Second-order phase transitions appear as a divergence in one of the linear response functions. For a system of correlated electrons, the relevant divergent response can and does involve many-particle observables, most famously the double…

Strongly Correlated Electrons · Physics 2024-06-17 Erik G. C. P. van Loon

We study the reaction front for the process A+B -> C in which the reagents move subdiffusively. Our theoretical description is based on a fractional reaction-subdiffusion equation in which both the motion and the reaction terms are affected…

Statistical Mechanics · Physics 2007-05-23 S. B. Yuste , L. Acedo , Katja Lindenberg

Within the atom-vacancy exchange mechanism in a nearest-neighbor interaction model we investigate the kinetics of surface-induced ordering processes close to the (001) surface of an fcc A_3B-alloy. After a sudden quench into the ordered…

Statistical Mechanics · Physics 2009-11-07 Michael Kessler , Wolfgang Dieterich , Andrzej Majhofer

The prevalent scheme of a diffusion-mediated bimolecular reaction $A+B\rightarrow P$ is an adaptation of that proposed by Briggs and Haldane for enzyme action [{\em Biochem J.\/}, 19:338--339, 1925]. The purpose of this Note is to explain,…

Chemical Physics · Physics 2014-11-11 K. Razi Naqvi

The global existence of bounded solutions to reaction-diffusion systems with fractional diffusion in the whole space $\mathbb R^N$ is investigated. The systems are assumed to preserve the non-negativity of initial data and to dissipate…

Analysis of PDEs · Mathematics 2025-02-25 Phuoc-Tai Nguyen , Bao Quoc Tang

Diffusion and reaction of initially separated ions A- and B+ in the presence of counter ions A'+ and B'- is studied. The dynamics is described in terms of reaction-diffusion equations obeying local electroneutrality, and the time-evolution…

Statistical Mechanics · Physics 2009-10-31 T. Unger , Z. Racz

By combining the upper and lower bounds to the free energy as given by the Gibbs inequality for two systems with the same intermolecular interactions but with external fields differing from each other only in a finite region of space Gamma,…

Statistical Mechanics · Physics 2016-08-31 John D. Weeks

We present a theory for the coagulation reaction A+A -> A for particles moving subdiffusively in one dimension. Our theory is tested against numerical simulations of the concentration of $A$ particles as a function of time (``anomalous…

Statistical Mechanics · Physics 2015-05-13 S. B. Yuste , J. J. Ruiz-Lorenzo , Katja Lindenberg

Systems driven far from equilibrium may exhibit anomalous density fluctuations: active matter with orientational order display giant density fluctuations at large scale, while systems of interacting particles close to an absorbing phase…

Statistical Mechanics · Physics 2026-03-23 Sara Dal Cengio , Romain Mari , Eric Bertin

We study the evolution of fronts in a bistable reaction-diffusion system when the nonlinear reaction term is spatially non-homogeneous. This equation has been used to model wave propagation in various biological systems. Extending previous…

Pattern Formation and Solitons · Physics 2009-10-31 Horacio G. Rotstein , Anatol M. Zhabotinsky , Irving R. Epstein

We study the kinetics of diffusion-limited coalescence, A+A-->A, and annihilation, A+A-->0, in the Bethe lattice of coordination number z. Correlations build up over time so that the probability to find a particle next to another varies…

Statistical Mechanics · Physics 2007-05-23 Daniel ben-Avraham , M. Lawrence Glasser

We investigate the A+B=0 bimolecular chemical reaction taking place in low-dimensional spaces when the mobilities of the two reacting species are not equal. While the case of different reactant mobilities has been previously reported as not…

Statistical Mechanics · Physics 2015-06-11 Panos Argyrakis , Raoul Kopelman

We look at the influence of external fields on systems described by generic free energy functional of the order parameter. The external force may have arbitrary spatial dependence, and the order parameter coupling may be nonlinear. The…

Statistical Mechanics · Physics 2023-01-05 Roni Kroll , Yoav Tsori

We develop an effective numerical method of studying large-time properties of reversible reaction-diffusion systems of type A + B <-> C with initially separated reactants. Using it we find that there are three types of asymptotic reaction…

Statistical Mechanics · Physics 2009-11-10 Zbigniew Koza

We study a two-species reaction-diffusion model where A+A->0, A+B->0 and B+B->0, with annihilation rates lambda0, delta0 > lambda0 and lambda0, respectively. The initial particle configuration is taken to be randomly mixed with mean…

Statistical Mechanics · Physics 2009-10-31 Zoran Konkoli , Henrik Johannesson

We introduce and study a new class of fronts in finite particle number reaction-diffusion systems, corresponding to propagating up a reaction rate gradient. We show that these systems have no traditional mean-field limit, as the nature of…

Statistical Mechanics · Physics 2007-05-23 Elisheva Cohen , David A. Kessler , Herbert Levine

We present an exact calculation of the mean first-passage time to a small target on the surface of a 2D or 3D spherical domain, for a molecule performing surface-mediated diffusion. This minimal model of interfacial reactions, which…

Statistical Mechanics · Physics 2015-05-18 O. Bénichou , D. Grebenkov , P. Levitz , C. Loverdo , R. Voituriez

Phase transitions of reaction-diffusion systems with site occupation restriction and with particle creation that requires n>1 parents and where explicit diffusion of single particles (A) exists are reviewed. Arguments based on mean-field…

Statistical Mechanics · Physics 2015-06-24 Geza Odor

We generalize the reaction-diffusion model A + B -> 0 in order to study the impact of an excess of A (or B) at the reaction front. We provide an exact solution of the model, which shows that linear response breaks down: the average…

Statistical Mechanics · Physics 2015-01-07 Iacopo Mastromatteo , Bence Toth , Jean-Philippe Bouchaud