English

Dynamics of the reaction-diffusion system $A + B \to 0 $ with input of particles

Statistical Mechanics 2007-05-23 v1 Soft Condensed Matter

Abstract

We study dynamics of filling of an initially empty finite medium by diffusing particles AA and BB, which arise on the surface upon dissociation of ABAB molecules, impinging on it with a fixed flux density II, and desorb from it by the reaction A+BAB0A + B\to AB\to 0. We show that once the bulk diffusivities differ (p=DA/DB<1p=D_{A}/D_{B}<1), there exists a critical flux density Ic(p)I_{c}(p), above which the relaxation dynamics to the steady state is qualitatively changed: on time dependencies of cAs/cec_{As}/c_{e} (cec_{e} being the steady state concentration at tt\to \infty) a maximum appears, the amplitude of which grows both with II and with DB/DAD_{B}/D_{A} ratio. In the diffusion-controlled limit IIcI \gg I_{c} at p1p \ll 1 the reaction "selects" the {\it universal laws} for the particles number growth NA=NBt1/4{\cal N}_{A}={\cal N}_{B}\propto t^{1/4} and the evolution of the surface concentrations cAst1/4,cBst1/4c_{As}\propto t^{-1/4},c_{Bs}\propto t^{1/4}, which are approached by one of the {\it two characteristic regimes} with the corresponding hierarchy of the intermediate power-law asymptotics. In the first of these cAsc_{As} goes through a comparatively {\it sharp} max(cAs/ce)I1/6(c_{As}/c_{e})\propto I^{1/6}, the amplitude of which is pp-independent, in the second one cAsc_{As} goes through a {\itplateau-like} max(cAs/ce)p1/4(c_{As}/c_{e})\propto p^{-1/4}, the amplitude of which is II-independent. We demonstrate that on the main filling stage the evolution of the N(t)/Ne,cAs(t)/ce,{\cal N}(t)/{\cal N}_{e}, c_{As}(t)/c_{e}, and cBs(t)/cec_{Bs}(t)/c_{e} trajectories with changing pp or JJ between the limiting regimes is unambiguously defined by the value of the scaling parameter K=p3/2J{\cal K}=p^{3/2}J (JJ being the reduced flux density) and is described by the set of {\it scaling laws}, which we study in detail analytically and numerically.

Keywords

Cite

@article{arxiv.cond-mat/0201331,
  title  = {Dynamics of the reaction-diffusion system $A + B \to 0 $ with input of particles},
  author = {Boris M. Shipilevsky},
  journal= {arXiv preprint arXiv:cond-mat/0201331},
  year   = {2007}
}

Comments

15 pages, 15 figures. Submitted to Physical Review E