Dynamics of the reaction-diffusion system $A + B \to 0 $ with input of particles
Abstract
We study dynamics of filling of an initially empty finite medium by diffusing particles and , which arise on the surface upon dissociation of molecules, impinging on it with a fixed flux density , and desorb from it by the reaction . We show that once the bulk diffusivities differ (), there exists a critical flux density , above which the relaxation dynamics to the steady state is qualitatively changed: on time dependencies of ( being the steady state concentration at ) a maximum appears, the amplitude of which grows both with and with ratio. In the diffusion-controlled limit at the reaction "selects" the {\it universal laws} for the particles number growth and the evolution of the surface concentrations , which are approached by one of the {\it two characteristic regimes} with the corresponding hierarchy of the intermediate power-law asymptotics. In the first of these goes through a comparatively {\it sharp} max, the amplitude of which is -independent, in the second one goes through a {\itplateau-like} max, the amplitude of which is -independent. We demonstrate that on the main filling stage the evolution of the and trajectories with changing or between the limiting regimes is unambiguously defined by the value of the scaling parameter ( being the reduced flux density) and is described by the set of {\it scaling laws}, which we study in detail analytically and numerically.
Keywords
Cite
@article{arxiv.cond-mat/0201331,
title = {Dynamics of the reaction-diffusion system $A + B \to 0 $ with input of particles},
author = {Boris M. Shipilevsky},
journal= {arXiv preprint arXiv:cond-mat/0201331},
year = {2007}
}
Comments
15 pages, 15 figures. Submitted to Physical Review E