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We investigate the equilibrium properties of a colloidal solution in contact with a soft interface. As a result of symmetry breaking, surface effects are generally prevailing in confined colloidal systems. In this Letter, particular…

Statistical Mechanics · Physics 2015-06-24 Hamid Kaidi , Thomas Bickel , Mabrouk Benhamou

Colloidal dispersions are prized as model systems to understand basic properties of materials, and are central to a wide range of industries from cosmetics to foods to agrichemicals. Among the key developments in using colloids to address…

Soft Condensed Matter · Physics 2022-06-22 Jun Dong , Francesco Turci , Robert L. Jack , Malcolm A. Faers , C. Patrick Royall

We have developed a simulation model to describe particle adsorption to and desorption from liquid interfaces. Using this model we formulate a closed interfacial equation of state for repulsive elastic spheres. The effect of a long-range…

Soft Condensed Matter · Physics 2011-02-24 Robert D. Groot , Simeon D. Stoyanov

The electrostatic interaction between two non-identical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically…

Soft Condensed Matter · Physics 2018-04-30 Arghya Majee , Timo Schmetzer , Markus Bier

The mechanical properties of aggregated colloids depend on the mutual interplay of inter-particle potentials, contact forces, aggregate structure and material properties of the bare particles. Owing to this variety of influences…

Soft Condensed Matter · Physics 2012-05-15 Marcel Roth , Carsten Schilde , Philipp Lellig , Arno Kwade , Günter K. Auernhammer

We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

Soft Condensed Matter · Physics 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

In geometrically frustrated assemblies local inter-subunit misfits propagate to intra-assembly strain gradients, giving rise to anomalous self-limiting assembly thermodynamics. Here, we use theory and coarse-grained simulation to study a…

Soft Condensed Matter · Physics 2024-03-05 Kyle T. Sullivan , Ryan C. Hayward , Gregory M. Grason

Colloidal particles are considered ideal building blocks to produce materials with enhanced physical properties. The state-of-the-art techniques for synthesizing these particles provide control over shape, size, and directionality of the…

Soft Condensed Matter · Physics 2016-12-21 N. A. M. Araújo , C. S. Dias , M. M. Telo da Gama

We propose the use of topographic modulation of surfaces to select and localize particles in nematic colloids. By considering convex and concave deformations of one of the confining surfaces we show that the colloid-flat surface repulsion…

Soft Condensed Matter · Physics 2014-10-15 Z. Eskandari , N. M. Silvestre , M. M. Telo da Gama , M. R. Ejtehadi

We investigate the non-equilibrium fluid structure mediated forces between two colloids driven through a suspension of mutually non-interacting Brownian particles as well as between a colloid and a wall in stationary situations. We solve…

Soft Condensed Matter · Physics 2009-11-13 Matthias Krüger , Markus Rauscher

The interaction of amphiphilic polymers with small colloids, capable to reversibly stick onto the chains, is studied. Adhesive small colloids in solution are able to dynamically bind two polymer segments. This association leads to…

Soft Condensed Matter · Physics 2010-11-10 Vladimir A. Baulin , Albert Johner , Josep Bonet Avalos

We study the structure of clusters in a model colloidal system with competing interactions using Brownian dynamics simulations. A short-ranged attraction drives clustering, while a weak, long-ranged repulsion is used to model electrostatic…

Soft Condensed Matter · Physics 2010-10-05 Alex Malins , Stephen R. Williams , Jens Eggers , Hajime Tanaka , C. Patrick Royall

Hydrophobic PMMA colloidal particles, when dispersed in oil with a relatively high dielectric constant, can become highly charged. In the presence of an interface with a conducting aqueous phase, image charge effects lead to strong binding…

We report on the formation of colloidal complexes resulting from the electrostatic self-assembly of polyelectrolyte-neutral block copolymers and oppositely charged surfactants. The copolymers investigated are asymmetric and characterized by…

Soft Condensed Matter · Physics 2007-05-23 Jean-Francois Berret , Pascal Herve , Isabelle Grillo

Particles bound to an interface interact because they deform its shape. The stresses that result are fully encoded in the geometry and described by a divergence-free surface stress tensor. This stress tensor can be used to express the force…

Soft Condensed Matter · Physics 2007-05-23 Martin Michael Mueller , Markus Deserno , Jemal Guven

Self-assembly of colloidal particles is a promising avenue to control the shape and dynamics of larger aggregates. However, achieving the necessary fine control over the dynamics and specificity of the bonds between such particles remains a…

Soft Condensed Matter · Physics 2024-09-26 Muraleedharapai Mayarani , Justine Laurent , Martin Lenz , Olivia du Roure , Julien Heuvingh

We show theoretically that near a fluid-fluid interface a single active colloidal particle generating, e.g., chemicals or a temperature gradient experiences an effective force of hydrodynamic origin. This force is due to the fluid flow…

Soft Condensed Matter · Physics 2016-03-16 Alvaro Domínguez , Paolo Malgaretti , Mihail N. Popescu , Siegfried Dietrich

In this work, we study the acoustically mediated interaction forces among multiple well-separated spherical particles trapped in the same node or antinode plane of a standing wave. An analytical expression of the acoustic interaction force…

Soft Condensed Matter · Physics 2016-12-21 Shenwei Zhang , Chunyin Qiu , Mudi Wang , Manzhu Ke , Zhengyou Liu

Scattering or tunneling of an electron at a potential barrier is a fundamental quantum effect. Electron-electron interactions often affect the scattering, and understanding of the interaction effect is crucial in detection of various…

Mesoscale and Nanoscale Physics · Physics 2022-11-10 Sungguen Ryu , H. -S. Sim

Creating materials with structure that is independently controllable at a range of scales requires breaking naturally occurring hierarchies. Breaking these hierarchies can be achieved via the decoupling of building block attributes from…

Soft Condensed Matter · Physics 2022-07-04 Lucia Baldauf , Erin G. Teich , Peter Schall , Greg van Anders , Laura Rossi
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