Specific yet transient bonds between anisotropic colloids
Abstract
Self-assembly of colloidal particles is a promising avenue to control the shape and dynamics of larger aggregates. However, achieving the necessary fine control over the dynamics and specificity of the bonds between such particles remains a challenge. Here we demonstrate such control in bonds mediated by depletion interactions between anisotropic colloids that we 3D-print in the shape of half disks with sub-micron resolution. When brought together by diffusion, the particles interact in different configurations but the interaction through the flat faces is by far the longest-lasting. All bonds are flexible and transient, and we demonstrate control over their life time through the depletant concentration in quantitative agreement with a simple physical model. This basic design could be extended to manufacture particles with multiple binding sites to engineer directional assembly with multiple particles.
Cite
@article{arxiv.2408.11569,
title = {Specific yet transient bonds between anisotropic colloids},
author = {Muraleedharapai Mayarani and Justine Laurent and Martin Lenz and Olivia du Roure and Julien Heuvingh},
journal= {arXiv preprint arXiv:2408.11569},
year = {2024}
}
Comments
Total submission: 23 pages (Article: 15 pages followed by Supporting Information: 8 pages )