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We perform computational investigations of electrolyte-mediated interactions of charged colloidal particles confined within nanochannels. We investigate the role of discrete ion effects, valence, and electrolyte strength on colloid-wall…

Soft Condensed Matter · Physics 2023-02-28 Inderbir S. Sidhu , Amalie L. Frischknecht , Paul J. Atzberger

In this paper we consider a two-dimensional model of a copolymer consisting of a random concatenation of hydrophilic and hydrophobic monomers, immersed in a micro-emulsion of random droplets of oil and water. The copolymer interacts with…

Probability · Mathematics 2012-04-06 Frank den Hollander , Nicolas Pétrélis

Polymer brushes are attractive as surface coatings for a wide range of applications, from fundamental research to everyday life, and also play important roles in biological systems. How colloids (e.g., functional nanoparticles, proteins,…

Soft Condensed Matter · Physics 2025-04-07 Mikhail Y. Laktionov , Ekaterina B. Zhulina , Leonid Klushin , Ralf P. Richter , Oleg V. Borisov

We study the interaction of small hydrophobic particles on the surface of an ultra-soft elastic gel, in which a small amount of elasticity of the medium balances the weights of the particles. The excess energy of the surface of the deformed…

Soft Condensed Matter · Physics 2014-06-09 Aditi Chakrabarti , Manoj K. Chaudhury

The depletion interaction mediated by non-adsorbing polymers promotes condensation and assembly of repulsive colloidal particles into diverse higher-order structures and materials. One example, with particularly rich emergent behaviors, is…

Soft Condensed Matter · Physics 2016-02-23 Louis Kang , Thomas Gibaud , Zvonimir Dogic , T. C. Lubensky

We study elastic interactions between colloidal particles and deformation landscapes of undulations in a cholesteric liquid crystal under an electric field applied normal to cholesteric layers. The onset of undulation instability is…

Soft Condensed Matter · Physics 2016-12-06 Michael C. M. Varney , Qiaoxuan Zhang , Bohdan Senyuk , Ivan I. Smalyukh

We report a numerical study of equilibrium phase-diagrams and interfacial properties of bulk and confined colloid-polymer mixtures using grand canonical Monte Carlo simulations. Colloidal particles are treated as hard spheres, while the…

Soft Condensed Matter · Physics 2009-11-13 Andrea Fortini , Peter G. Bolhuis , Marjolein Dijkstra

The Landau-de Gennes free energy is used to study theoretically the interaction of parallel cylindrical colloidal particles trapped at a nematic-isotropic interface. We find that the effective interaction potential is non-monotonic. The…

Soft Condensed Matter · Physics 2015-06-24 D. Andrienko , M. Tasinkevych , S. Dietrich

Control of frictional interactions among liquid-suspended particles has led to tunable, strikingly non-Newtonian rheology via the formation of strong flow constraints as particles come into close proximity under shear. Typically, these…

At sufficiently low temperatures and high densities, repulsive spherical particles in two-dimensions (2d) form close-packed structures with six-fold symmetry. By contrast, when the interparticle interaction has an attractive anisotropic…

Soft Condensed Matter · Physics 2018-09-13 T. Geigenfeind , C. S. Dias , M. M. Telo da Gama , D. de las Heras , N. A. M. Araújo

Within a general theoretical framework we study the effective, deformation-induced interaction between two colloidal particles trapped at a fluid interface in the regime of small deformations. In many studies, this interaction has been…

Soft Condensed Matter · Physics 2010-06-18 Alvaro Dominguez , Martin Oettel , Siegfried Dietrich

Phoretic colloids self-propel thanks to surface flows generated in response to surface gradients (thermal, electrical, or chemical), that are self-induced and/or generated by other particles. Here we present a scalable and versatile…

Soft Condensed Matter · Physics 2024-07-29 Blaise Delmotte , Florencio Balboa Usabiaga

We investigate bridging and aggregation of two colloidal particles in a near-critical binary mixture when the fluid far from the particles is outside the coexistence (CX) curve and is rich in the component disfavored by the colloid…

Soft Condensed Matter · Physics 2015-05-26 Shunsuke Yabunaka , Ryuichi Okamoto , Akira Onuki

Thermally induced particle flow in a charged colloidal suspension is studied in a fluid-mechanical approach. The force density acting on the charged boundary layer is derived in detail. From Stokes' equation with no-slip boundary conditions…

Soft Condensed Matter · Physics 2014-01-31 S. Fayolle , T. Bickel , A. Würger

Polymer brushes, coatings consisting of densely grafted macromolecules, experience an intrinsic lateral compressive pressure, originating from chain elasticity and excluded volume interactions. This lateral pressure complicates a proper…

Soft Condensed Matter · Physics 2023-12-07 Lars B. Veldscholte , Jacco H. Snoeijer , Wouter K. den Otter , Sissi de Beer

Understanding multibody interactions between colloidal particles out of equilibrium has a profound impact on dynamical processes such as colloidal self assembly. However, traditional colloidal interactions are effectively quasi-static on…

Soft Condensed Matter · Physics 2023-03-17 Yaxin Xu , Kyu Hwan Choi , Sachit G. Nagella , Sho C. Takatori

At the surfaces of autophoretic colloids, slip velocities arise from local chemical gradients that are many-body functions of particle configuration and activity. For rapid chemical diffusion, coupled with slip-induced hydrodynamic…

Soft Condensed Matter · Physics 2019-07-29 Rajesh Singh , R. Adhikari , M. E. Cates

We present confocal microscopy studies of novel particle-stabilized emulsions. The novelty arises because the immiscible fluids have an accessible upper critical solution temperature. The emulsions have been created by beginning with…

Soft Condensed Matter · Physics 2009-11-11 P. S. Clegg , E. M. Herzig , A. B. Schofield , T. S. Horozov , B. P. Binks , M. E. Cates , W. C. K. Poon

Effective colloid-colloid interactions can be tailored through the addition of a complex cosolute. Here we investigate the case of a cosolute made by self-assembling patchy particles. Depending on the valence, these particles can form…

Soft Condensed Matter · Physics 2019-02-08 Nicolás Ariel García , Nicoletta Gnan , Emanuela Zaccarelli

The depletion interaction between two parallel repulsive walls confining a dilute solution of long and flexible polymer chains is studied by field-theoretic methods. Special attention is paid to self-avoidance between chain monomers…

Soft Condensed Matter · Physics 2009-11-07 F. Schlesener , A. Hanke , R. Klimpel , S. Dietrich