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Understanding the formation of metal-molecule contact at the microscopic level is the key towards controlling and manipulating atomic scale devices. Employing two isomers of bipyridine, $4, 4^\prime$ bipyridine and $2, 2^\prime$ bipyridine…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Biswajit Pabi , Debayan Mondal , Priya Mahadevan , Atindra Nath Pal

In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…

Materials Science · Physics 2023-02-17 A. Martinez-Garcia , T. de Ara , L. Pastor-Amat , C. Untiedt , E. B. Lombardi , W. Dednam , C. Sabater

We carry out experiments on single-molecule junctions at low temperatures, using the mechanically controlled break junction technique. Analyzing the results received with more than ten different molecules the nature of the first peak in the…

Mesoscale and Nanoscale Physics · Physics 2012-03-21 Daniel Secker , Stefan Wagner , Stefan Ballmann , Rainer Härtle , Michael Thoss , Heiko B. Weber

Based on the matrix Green's function method combined with hybrid tight-binding / density functional theory, we calculate the conductances of a series of gold-dithiol molecule-gold junctions including benzenedithiol (BDT),…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Zhanyu Ning , Jingzhe Chen , Shimin Hou , Jiaxing Zhang , Zhenyu Liang , Jin Zhang , Rushan Han

Based on the non-equilibrium Green's function (NEGF) technique and the Landauer-B\"{u}ttiker theory, the possibility of a molecular spin-electronic device, which consists of a single C$_{60}$ molecule attached to two ferromagnetic…

Mesoscale and Nanoscale Physics · Physics 2008-12-31 Alireza Saffarzadeh

Characterization of the structural and electron transport properties of single chiral molecules provides critical insights into the interplay between their electronic structure and electrochemical environments, providing broader…

Chemical Physics · Physics 2024-09-26 Yueqing Shi , Liya Bi , Zihao Wang , Kangkai Liang , Ji-Kun Li , Xiao-Ye Wang , Wan-Lu Li , Shaowei Li

For defining the conductance of single molecule junctions with a redox functionality in an electrochemical cell, two conceptually different electron transport mechanisms, namely coherent tunnelling and vibrationally induced hopping compete…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Georg Kastlunger , Robert Stadler

Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Andrew K. Mitchell , Kim G. L. Pedersen , Per Hedegaard , Jens Paaske

Using a first principles approach, we study the electron transport properties of a new class of molecular wires containing fluorenone units, whose features open up new possibilities for controlling transport through a single molecule. We…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 C. J. Lambert , I. M. Grace , T. Papadopoulos

A single molecule break junction device serves as a tunable model system for probing the many body Kondo state. The low-energy properties of this state are commonly described in terms of a Kondo model, where the response of the system to…

Strongly Correlated Electrons · Physics 2013-06-28 Gavin D. Scott , Douglas Natelson , Stefan Kirchner , Enrique Muñoz

Electromigrated nanoscale junctions have proven very useful for studying electronic transport at the single-molecule scale. However, confirming that conduction is through precisely the molecule of interest and not some contaminant or metal…

Mesoscale and Nanoscale Physics · Physics 2008-09-04 D. R. Ward , G. D. Scott , Z. K. Keane , N. J. Halas , D. Natelson

Single-molecule junctions - nanoscale systems where a molecule is connected to metallic electrodes - offer a unique platform for studying charge, spin and energy transport in non-equilibrium many-body quantum systems, with few parallels in…

Mesoscale and Nanoscale Physics · Physics 2024-11-05 María Camarasa-Gómez , Daniel Hernangómez-Pérez , Jan Wilhelm , Alexej Bagrets , Ferdinand Evers

Scanning tunneling spectroscopy measures how a single electron with definite energy propagates between a sample surface and the tip of a scanning tunneling microscope. In the simplest description, the differential conductance measured is…

Mesoscale and Nanoscale Physics · Physics 2019-05-07 Mikko M. Ervasti , Fabian Schulz , Peter Liljeroth , Ari Harju

Molecular nanowires in which a single molecule bonds chemically to two metal electrodes and forms a stable electrically conducting bridge between them have been studied intensively for more than a decade. However the experimental…

Chemical Physics · Physics 2012-08-21 Firuz Demir , George Kirczenow

The linear conductance of the single electron transistor is determined in the high temperature limit. Electron tunneling is treated nonperturbatively by means of a path integral formulation and the conductance is obtained from Kubo's…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Georg Goeppert , Hermann Grabert

We report transport measurements through a single-molecule magnet, the Mn12 derivative [Mn12O12(O2C-C6H4-SAc)16(H2O)4], in a single-molecule transistor geometry. Thiol groups connect the molecule to gold electrodes that are fabricated by…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 H. B. Heersche , Z. de Groot , J. A. Folk , H. S. J. van der Zant , C. Romeike , M. R. Wegewijs , L. Zobbi , D. Barreca , E. Tondello , A. Cornia

We report on experimental results for the conductance of metallic single-electron transistors as a function of temperature, gate voltage and dimensionless conductance. In contrast to previous experiments our transistor layout allows for a…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 C. Wallisser , B. Limbach , P. vom Stein , R. Schaefer , C. Theis , G. Goeppert , H. Grabert

The charge flow from a single C60 molecule to another one has been probed. The conformation and electronic states of both molecules on the contacting electrodes have been characterized using a cryogenic scanning tunneling microscope. While…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Guillaume Schull , Thomas Frederiksen , Mads Brandbyge , Richard Berndt

This review presents recent results on the physics of electron transport in molecular devices. The review is organized as follows. A brief description of molecular junction (MJ) technology is first given followed by an introduction to the…

Mesoscale and Nanoscale Physics · Physics 2021-11-23 Dominique Vuillaume

Understanding and controlling heat transport in molecular junctions would provide new routes to design nanoscale coupled electronic and phononic devices. Using first principles full quantum calculations, we tune thermal conductance of a…

Mesoscale and Nanoscale Physics · Physics 2015-11-20 Qian Li , Ivan Duchemin , Shiyun Xiong , Gemma C. Solomon , Davide Donadio
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