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We have investigated electrical transport through the molecular model systems benzenedithiol, benzenediamine, hexanedithiol and hexanediamine. Conductance histograms under different experimental conditions indicate that measurements using…

Mesoscale and Nanoscale Physics · Physics 2008-07-01 C. A. Martin , D. Ding , H. S. J. van der Zant , J. M. van Ruitenbeek

We study the dc conductance of organic single-molecule contacts in the presence of external electromagnetic radiation (photoconductance). In agreement with previous predictions, we find that the radiation can lead to large enhancements of…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 J. K. Viljas , F. Pauly , J. C. Cuevas

A conducting bridge of a single hydrogen molecule between Pt electrodes is formed in a break junction experiment. It has a conductance near the quantum unit, G_0 = 2e^2/h, carried by a single channel. Using point contact spectroscopy three…

Mesoscale and Nanoscale Physics · Physics 2017-12-11 D. Djukic , K. S. Thygesen , C. Untiedt , R. H. M. Smit , K. W. Jacobsen , J. M. van Ruitenbeek

Many types of molecular motors have been proposed and synthesized in recent years, displaying different kinds of motion, and fueled by different driving forces such as light, heat, or chemical reactions. We propose a new type of molecular…

Mesoscale and Nanoscale Physics · Physics 2010-11-24 Johannes S. Seldenthuis , Ferry Prins , Joseph M. Thijssen , Herre S. J. van der Zant

Single-molecule break junction measurements deliver a huge number of conductance vs.\ electrode separation traces. Along such measurements the target molecules may bind to the electrodes in different geometries, and the evolution and…

Mesoscale and Nanoscale Physics · Physics 2020-06-04 A. Magyarkuti , N. Balogh , Z. Balogh , L. Venkataraman , A. Halbritter

Controlling electronic transport through a single-molecule junction is crucial for molecular electronics or spintronics. In magnetic molecular devices, the spin degree-of-freedom can be used to this end since the magnetic properties of the…

We study theoretically the length dependence of both conductance and thermopower in metal-molecule-metal junctions made up of dithiolated oligophenylenes contacted to gold electrodes. We find that while the conductance decays exponentially…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 F. Pauly , J. K. Viljas , J. C. Cuevas

Using benzene-diamine and benzene-dithiol molecular junctions as benchmarks, we investigate the widespread analysis of the quantum transport conductance $\mathcal{G}(\epsilon)$ in terms of the projected density of states (PDOS) onto…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Tonatiuh Rangel , Gian-Marco Rignanese , Valerio Olevano

Tunneling of electrons through rotor-stator anthracene aldehyde molecular interfaces is studied with a combined ab initio and model approach. Molecular electronic structure calculated from first principles is utilized to model different…

Chemical Physics · Physics 2016-05-27 Irina Petreska , Vladimir Ohanesjan , Ljupco Pejov , Ljupco Kocarev

It is understood that molecular conjugation plays an important role in charge transport through single-molecule junctions. Here, we investigate electron transport through an anthraquinone based single-molecule three-terminal device. With…

Mesoscale and Nanoscale Physics · Physics 2016-05-19 M. Koole , J. M. Thijssen , H. Valkenier , J. C. Hummelen , H. S. J. van der Zant

Molecular-scale components are expected to be central to nanoscale electronic devices. While molecular-scale switching has been reported in atomic quantum point contacts, single-molecule junctions provide the additional flexibility of…

The single-molecule conductance of a 3-ring, conjugated azomethine was studied using the mechanically controlled breakjunction technique. Charge transport properties are found to be comparable to vinyl-based analogues; findings are…

Mesoscale and Nanoscale Physics · Physics 2016-08-18 Max Koole , Riccardo Frisenda , Michiel L. Petrus , Mickael L. Perrin , Herre S. J. van der Zant , Theo J. Dingemans

The conductance through a molecular device including electron-electron and electron-phonon interactions is calculated using the Numerical Renormalization Group method. At low temperatures and weak electron-phonon coupling the properties of…

Strongly Correlated Electrons · Physics 2007-05-23 P. S. Cornaglia , H. Ness , D. R. Grempel

Vibrationally inelastic electron transport through a flexible molecular junction is investigated. The study is based on a mechanistic model for a biphenyl molecule between two metal electrodes. Employing methods from electron-molecule…

Mesoscale and Nanoscale Physics · Physics 2023-07-26 Martin Cizek , Michael Thoss , Wolfgang Domcke

Inspired by recent measurements of forces and conductances of bipyridine nano-junctions, we have performed density functional theory calculations of structure and electron transport in a bipyridine molecule attached between gold electrodes…

Materials Science · Physics 2009-11-11 R. Stadler , K. S. Thygesen , K. W. Jacobsen

We consider several fundamental optical phenomena involving single molecules in biased metal-molecule-metal junctions. The molecule is represented by its highest occupied and lowest unoccupied molecular orbitals, and the analysis involves…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

The linear conductance of a molecular conductor oscillating between two metallic leads is investigated numerically both for Hubbard interacting and noninteracting electrons. The molecule-leads tunneling barriers depend on the molecule…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 K. A. Al-Hassanieh , C. A. Büsser , G. B. Martins , E. Dagotto

Thermopower measurements of molecular junctions have recently gained interest as a characterization technique that supplements the more traditional conductance measurements. Here we investigate the electronic conductance and thermopower of…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Troels Markussen , Chengjun Jin , Kristian S. Thygesen

Recent experiments demonstrate a temperature control of the electric conduction through a ferrocene-based molecular junction. Here we examine the results in view of determining means to distinguish between transport through single-particle…

Mesoscale and Nanoscale Physics · Physics 2018-02-23 Miguel A. Sierra , David Sánchez , Alvar R. Garrigues , Enrique del Barco , Lejia Wang , Christian A. Nijhuis

The electrical conductivity is calculated for regular inhomogeneous two component isotropic medium in which droplets of one phase with conductivity sigma_2 are embedded in another, with conductivity sigma_1. An expression is formulated…

Statistical Mechanics · Physics 2007-05-23 V. V. Kabanov , K. Zagar , D. Mihailovic