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The accurate determination of the lowest electron attachment ($EA$) and ionization ($IP$) energies for molecules embedded in molecular junctions is important for correctly estimating, \emph{e.g.}, the magnitude of the currents ($I$) or the…

Chemical Physics · Physics 2015-09-21 Ioan Baldea

The effect of a magnetic field on the equilibrium spectral and transport properties of a single-molecule junction is studied using the numerical renormalization group method. The molecule is described by the Anderson-Holstein model in which…

Strongly Correlated Electrons · Physics 2007-05-23 P. S. Cornaglia , D. R. Grempel

On two-dimensional percolation clusters at the percolation threshold, we study $<\sigma(M_B,r)>$, the average conductance of the backbone, defined by two points separated by Euclidean distance $r$, of mass $M_B$. We find that with…

Controlling electronic transport through a single-molecule junction is crucial for molecular electronics or spintronics. In magnetic molecular devices, the spin degree-of-freedom can be used to this end since the magnetic properties of the…

At low concentrations of methanol in ethanol-methanol binary system, the molecular interactions are seen to be uniquely complex. It is observed that the ethanol aggregates are not strictly hydrogen-bonded complexes; dispersion forces also…

Chemical Physics · Physics 2016-11-21 K Nilavarasi , Thejus R Kartha , V Madhurima

The influence of an intramolecular proton transfer reaction on the conductance of a molecular junction is investigated employing a generic model, which includes the effects of the electric field of the gate and leads electrodes and the…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 Chriszandro Hofmeister , Pedro B. Coto , Michael Thoss

Coherent electronic transport in single-molecule junctions is investigated in the Coulomb blockade regime. Both the transmission phase and probability are calculated for junctions with various contact symmetries. A dramatic suppression of…

Mesoscale and Nanoscale Physics · Physics 2010-11-15 J. P. Bergfield , Ph. Jacquod , C. A. Stafford

In standard molecular junctions, a molecular structure is placed between and connected to metal leads. Understanding how mechanical tuning in such molecular junctions can change heat conductance has interesting applications in nanoscale…

Soft Condensed Matter · Physics 2022-04-20 Mohammadhasan Dinpajooh , Abraham Nitzan

Molecular electronics break-junction experiments are widely used to investigate fundamental physics and chemistry at the nanoscale. Reproducibility in these experiments relies on measuring conductance on thousands of freshly formed…

Chemical Physics · Physics 2024-01-29 Leopoldo Mejía , Pilar Cossio , Ignacio Franco

We present a systematic ab-initio study of the length dependence of the thermopower in molecular junctions. The systems under consideration are small saturated and conjugated molecular chains of varying length attached to gold electrodes…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Falco Hüser , Gemma C. Solomon

We study the conductance of an interconnect between two graphene leads formed by a single-atom carbon chain. Its dependence on the chemical potential and the number of atoms in the chain is qualitatively different from that in the case of…

Mesoscale and Nanoscale Physics · Physics 2011-09-12 Wei Chen , A. V. Andreev , G. F. Bertsch

We examine theoretically coherent electron transport through the single-molecule magnet Mn$_{12}$, bridged between Au(111) electrodes, using the non-equilibrium Green's function method and the density-functional theory. We analyze the…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Kyungwha Park , Salvador Barraza-Lopez , Victor M. Garcia-Suarez , Jaime Ferrer

The linear conductance of a molecular conductor oscillating between two metallic leads is investigated numerically both for Hubbard interacting and noninteracting electrons. The molecule-leads tunneling barriers depend on the molecule…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 K. A. Al-Hassanieh , C. A. Büsser , G. B. Martins , E. Dagotto

Molecular bridges covalently bonded to two ferromagnetic electrodes can transform ferromagnetic materials and produce intriguing spin transport characteristics. This paper discusses the impact of molecule induced strong coupling on spin…

Materials Science · Physics 2019-12-04 Pawan Tyagi , Edward Friebe

We analyze theoretically the interplay between the torsional and the rotational motion of an aligned biphenyl-like molecule. To do so, we consider a transition between two electronic states with different internal torsional potentials,…

Chemical Physics · Physics 2017-02-08 Juan J. Omiste , Lars Bojer Madsen

Conjugated polymers are observed to aggregate in solution. To account for this observation we propose a inter-chain binding mechanism based on the intermolecular tunneling of the delocalized $\pi$-electrons occurring at points where the…

Soft Condensed Matter · Physics 2013-05-29 Jeremy D. Schmit , Alex J. Levine

We calculate the conductance through double junctions of the type M(inf.)-Sn-Mm-Sn-M(inf.) and triple junctions of the type M(inf.)-Sn-Mm-Sn-Mm-Sn-M(inf.), where M(inf.) are semi-infinite metallic electrodes, Sn are 'n' layers of…

Mesoscale and Nanoscale Physics · Physics 2008-10-03 J. Peralta-Ramos , A. M. Llois

The stability of molecular junctions under transport is of the utmost importance for the field of molecular electronics. This question is often addressed within the paradigm of current-induced heating of nuclear degrees of freedom or…

Mesoscale and Nanoscale Physics · Physics 2022-12-26 André Erpenbeck , Yaling Ke , Uri Peskin , Michael Thoss

We explore the merits of neural network boosted, principal-component-projection-based, unsupervised data classification in single-molecule break junction measurements, demonstrating that this method identifies highly relevant trace classes…

Mesoscale and Nanoscale Physics · Physics 2023-03-10 Zoltán Balogh , Gréta Mezei , Nóra Tenk , András Magyarkuti , András Halbritter

Electronic transport across n-Si-alkyl monolayer/Hg junctions is, at reverse and low forward bias, independent of alkyl chain-length from 18 down to 1 or 2 carbons! This and further recent results indicate that electron transport is…