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Conjugated molecules are materials which are widely studied and developed for molecular electronic technologies focusing on single molecule devices. In this paper we observed the molecular conductance of single molecule based on n phenyl…

Materials Science · Physics 2015-10-15 Setianto , B. Aradi , Th. Niehaus

Recent experiments by Venkatamaran {\em et al.} [Nature (London) {\bf 442}, 904 (2006)] on a series of molecular wires with varying chemical compositions, revealed a linear dependence of the conductance on $\mathrm{cos}^2\theta$, where…

We investigate the formation and evolution of Au-CO single-molecule break junctions. The conductance histogram exhibits two distinct molecular configurations, which are further investigated by a combined statistical analysis. According to…

Mesoscale and Nanoscale Physics · Physics 2016-01-11 Zoltán Balogh , Péter Makk , András Halbritter

The anchoring of the molecule to an electrode is known to be a key factor in single-molecule spintronics experiments. Likewise, a relaxation down to the most stable geometry is a critical step in theoretical simulations of transport through…

Mesoscale and Nanoscale Physics · Physics 2019-06-18 Silvia Giménez-Santamarina , Salvador Cardona-Serra , Alejandro Gaita-Ariño

The effect of vibrational motion on resonant charge transport through single molecule junctions is investigated. The study is based on a combination of first-principles electronic structure calculations to characterize the system and…

Other Condensed Matter · Physics 2007-12-24 Claudia Benesch , Martin Cizek , Jiri Klimes , Michael Thoss , Wolfgang Domcke

Achieving highly transmitting molecular junctions through resonant transport at low bias is key to the next-generation low-power molecular devices. Although, resonant transport in molecular junctions was observed by connecting a molecule…

Mesoscale and Nanoscale Physics · Physics 2023-08-09 Biswajit Pabi , Štepán Marek , Adwitiya Pal , Puja Kumari , Soumya Jyoti Ray , Arunabha Thakur , Richard Korytár , Atindra Nath Pal

Helicenes are inherently chiral polyaromatic molecules composed of all-ortho fused benzene rings possessing a spring-like structure. Here, using a combination of density functional theory and tight-binding calculations, it is demonstrated…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Jaroslav Vacek , Jana Vacek Chocholousová , Irena G. Stará , Ivo Starý , Yonatan Dubi

We present electronic transport measurements through thiolated C$_{60}$ molecules in liquid environment. The molecules were placed within a mechanically controllable break junction using a single anchoring group per molecule. When varying…

Single molecule manipulation techniques reveal that the mechanical resistance of a protein depends on the direction of the applied force. Using a lattice model of polymers, we show that changing the pulling direction leads to different…

Statistical Mechanics · Physics 2009-11-13 Sanjay Kumar , Debaprasad Giri

We report a method using scanning tunnelling microscope single molecular break junction to simultaneously measure and correlate the single-molecule thermopower and electrical conductance. In contrast to previously reported approaches, it…

Mesoscale and Nanoscale Physics · Physics 2021-09-24 Joseph M. Hamill , Christopher Weaver , Tim Albrecht

Using photoemission spectroscopy, we determine the relationship between electronic energy level alignment at a metal-molecule interface and single-molecule junction transport data. We measure the position of the highest occupied molecular…

Mesoscale and Nanoscale Physics · Physics 2010-06-28 M. Dell'Angela , G. Kladnik , A. Cossaro , A. Verdini , M. Kamenetska , I. Tamblyn , S. Y. Quek , J. B. Neaton , D. Cvetko , A. Morgante , L. Venkataraman

We present a simple model of electrical transport through a metal-molecule-metal nanojunction that includes charging effects as well as aspects of the electronic structure of the molecule. The interplay of a large charging energy and an…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Matthias H. Hettler , Herbert Schoeller , Wolfgang Wenzel

We present periodic Density Functional Theory calculations of the electronic properties of molecular junctions formed by amine-, and thiol-terminated alkane chains attached to two metal (Au, Ag) electrodes. Based on extensive analysis that…

Mesoscale and Nanoscale Physics · Physics 2008-07-02 Jian-guo Wang , Emil Prodan , Roberto Car , Annabella Selloni

Conductance measurements of a molecular wire, contacted between an epitaxial molecule-metal bond and the tip of a scanning tunneling microscope, are reported. Controlled retraction of the tip gradually de-hybridizes the molecule from the…

Strongly Correlated Electrons · Physics 2024-02-05 R. Temirov , A. C. Lassise , F. Anders , F. S. Tautz

We characterize molecular magnet heterojunctions in which sublimated CoPc films as thin as 5 nm are sandwiched between transparent conducting bottom-layer indium tin oxide and top-layer soft-landing eutectic GaIn (EGaIn) electrodes. The…

We report the thermal conductances of molecular junctions made of self-assembled monolayers of benzo-bis(imidazole) molecules, without side groups or functionalized with two phenylamine side groups. In the two cases, when the molecules are…

Mesoscale and Nanoscale Physics · Physics 2026-03-31 Sergio Gonzalez-Casal , Simon Pascal , Olivier Siri , Dominique Vuillaume

It is often intriguing experimentally to take stock of how conformational changes in the device configuration may impact the overall charge transport behavior of single-molecule junctions. Based on the allied approach of density functional…

Mesoscale and Nanoscale Physics · Physics 2020-02-06 Talem Rebeda Roy , Arijit Sen

We investigate the molecular sensing properties of carbon nanotube-boron nitride-carbon nanotube (CNT-BN-CNT) junctions. We demonstrate that the electrical conductance of such a junction changes in response to the binding of an analyte…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 Laith Algharagholy , Thomas Pope , Qusiy Al-Galiby , Hatef Sadeghi , Steve W. D. Bailey , Colin J. Lambert

We consider several fundamental optical phenomena involving single molecules in biased metal-molecule-metal junctions. The molecule is represented by its highest occupied and lowest unoccupied molecular orbitals, and the analysis involves…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

The finite-frequency transport properties of a large-spin molecule attached to ferromagnetic contacts are studied theoretically in the Kondo regime. The focus is on the behavior of the dynamical conductance in the linear response regime,…

Mesoscale and Nanoscale Physics · Physics 2017-05-03 Anna Płomińska , Maciej Misiorny , Ireneusz Weymann
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