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The lead-halide perovskites, including CH$_{3}$NH$_{3}$PbBr$_{3}$, are components in cost effective, highly efficient photovoltaics, where the interactions of the molecular cations with the inorganic framework are suggested to influence the…

Materials Science · Physics 2015-10-14 I. P. Swainson , C. Stock , S. F. Parker , L. Van Eijck , M. Russina , J. W. Taylor

Synchrotron x-ray powder diffraction measurements have been performed on unpoled ceramic samples of (1-x)PbMg(1/3)Nb(2/3)O3-xPbTiO3 (PMN-xPT) with 30%<= x<= 39% as a function of temperature around the morphotropic phase boundary (MPB),…

Materials Science · Physics 2009-11-07 B. Noheda , D. E. Cox , G. Shirane , Z. -G. Ye , J. Gao

The phase diagram of the Pb(Mg1/3Nb2/3)O3 and PbTiO3 solid solution (PMN-xPT) indicates a rhombohedral ground state for x < 0.32. X-ray powder measurements by Dkhil et al. show a rhombohedrally split (222) Bragg peak for PMN-10%PT at 80 K.…

Materials Science · Physics 2009-11-10 P. M. Gehring , W. Chen , Z. -G. Ye , G. Shirane

We review some of the current research on two of the ultra-high piezoelectric relaxors Pb(Mg1/3Nb2/3)O3 (PMN) and Pb(Zn1/3Nb2/3)O3 (PZN). The discovery of a monoclinic phase in Pb(Zr1-xTix)O3 (PZT) in 1999 by Noheda et al. forced a…

Materials Science · Physics 2007-05-23 G. Shirane , P. M. Gehring

Pb_1.83Mg_0.29Nb_1.71O_6.39 (PMN) crystallizing in a cubic pyrochlore structure exhibits, as the first dielectrics with pyrochlore structure, typical feature of quantum paraelectrics - its permittivity continuously increases on cooling and…

Materials Science · Physics 2007-09-25 S. Kamba , D. Nuzhnyy , S. Denisov , S. Veljko , V. Bovtun , M. Savinov , J. Petzelt , M. Kalnberga , A. Sternberg

The nature of the cubic-like state in the lead-free piezoelectric ceramics 0.5K0.5Na0.5NbO3-0.5Na0.5Bi0.5TiO3 (KNN-50BNT) has been examined in detail by synchrotron x-ray diffraction (SD), selected area electron diffraction (SAED), neutron…

The results of diffuse neutron scattering experiment on PbMg1/3Nb2/3O3 single crystal above the Burns temperature are reported. It is shown that the high temperature elastic diffuse component is highly anisotropic in low-symmetry Brillouin…

Materials Science · Physics 2015-03-17 R. G. Burkovsky , S. B. Vakhrushev , K. Hirota , M. Matsuura

We report the spontaneous decay of a soft, optical phonon in a solid. Using neutron spectroscopy, we find that specific phonon lifetimes in the relaxor PbMg$_{1/3}$Nb$_{2/3}$O$_{3}$ are anomalously short within well-defined ranges of energy…

Materials Science · Physics 2018-07-19 C. Stock , P. M. Gehring , R. A. Ewings , G. Xu , J. Li , D. Viehland , H. Luo

Relaxor ferroelectrics are difficult to study and understand. The experiment shows that at low energy scattering there is an acoustic mode, an optic mode, dynamic quasi-elastic scattering and strictly elastic scattering as well as Bragg…

Materials Science · Physics 2008-08-29 R. A. Cowley , S. N. Gvasaliya , B. Roessli

We have examined the local structure of PMN-PT and PZN-PT solid solutions using density functional theory. We find that the directions and magnitudes of cation displacement can be explained by an interplay of cation-oxygen bonding,…

Materials Science · Physics 2009-11-10 Ilya Grinberg , Andrew M. Rappe

We report first principles calculations of the phonon dispersions of PbTe both for its observed structure and under compression. At the experimental lattice parameter we find a near instability of the optic branch at the zone center, in…

Materials Science · Physics 2008-10-27 Jiming An , Alaska Subedi , David J. Singh

Short-range polar orders in the relaxor ferroelectric material PbMg$_{1/3}$Nb$_{2/3}$O$_3$-$28\%$PbTiO$_3$ (PMN-28PT) have been studied using neutron diffuse scattering. An external electric field along [110] direction can affect the…

Materials Science · Physics 2019-08-07 Zhijun Xu , Fei Li , Shujun Zhang , Christopher Stock , Jun Luo , Peter M. Gehring , Guangyong Xu

We report a neutron scattering study of a ferroelectric phase transition in Sr$_{0.61}$Ba$_{0.39}$Nb$_2$O$_6$ (SBN-61). The ferroelectric polarization is along the crystallographic $c$-axis but the transverse acoustic branch propagating…

Materials Science · Physics 2014-02-10 S. N. Gvasaliya , R. A. Cowley , L. I. Ivleva , S. G. Lushnikov , B. Roessli , A. Zheludev

We report measurements of the phonon dispersion relations in non-superconducting, oxygen-deficient PrBa2Cu3O6+x (x ~ 0.2) by inelastic neutron scattering. The data are compared with a model of the lattice dynamics based on a common…

Inelastic neutron scattering measurements on the molecular dimer-Mott insulator $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Cl reveal a phonon anomaly in a wide temperature range. Starting from $T_{\rm ins}\sim50$-$60$ K where the charge gap…

The 93Nb and 45Sc NMR spectra in PbSc_1/2Nb_1/2O_3 (PSN) and PbMg_1/3Nb_2/3O_3 (PMN) disordered relaxor ferroelectrics at the temperature T > T_0 (T_0 is the temperature of the dielectric susceptibility maximum) have been studied. Spectra…

Materials Science · Physics 2007-05-23 V. V. Laguta , M. D. Glinchuk , I. P. Bykov , R. Blinc , A. Gregorovic , B. Zalar

High energy resolution neutron spin-echo spectroscopy has been used to measure intrinsic width of diffuse scattering discovered earlier in relaxor ferroelectric crystals. The anisotropic and transverse components of the scattering have been…

Materials Science · Physics 2017-09-13 Sergey Vakhrushev , Alexandre Ivanov , Jiri Kulda

Ferroelectric soft mode in Pb(Mg1/3Nb2/3)O3 (PMN) has been clearly resolved by precision Raman scattering measurements for the first time. A polarization direction of the incident laser was chosen along [110] in cubic configuration in order…

Materials Science · Physics 2009-09-23 Hiroki Taniguchi , Masanori Oishi , Desheng Fu , Mitsuru Itoh

We present an \emph{ab-initio} study that identifies the main electron-phonon scattering channels in $n$-type PbTe. We develop an electronic transport model based on the Boltzmann transport equation within the transport relaxation time…

Mesoscale and Nanoscale Physics · Physics 2018-11-14 Jiang Cao , Jose D. Querales-Flores , Aoife R. Murphy , Stephen Fahy , Ivana Savić

We investigate the elastic $\pi N$ scattering for the $I=3/2$ channel dominated by the $\Delta(1232)$ resonance at finite baryon density $\rho_B$ for the symmetric nuclear matter, employing the effective Lagrangian approach at the…

Nuclear Theory · Physics 2023-02-22 Hyeon-dong Han , Parada T. P. Hutauruk , Seung-il Nam