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The paper moves a step towards the full integration of statistical mechanics and information theory. Starting from the assumption that the thermodynamical system is composed by particles whose quantized energies can be modelled as…

Statistical Mechanics · Physics 2023-02-01 Arnaldo Spalvieri

In the framework of statistical mechanics the properties of macroscopic systems are deduced starting from the laws of their microscopic dynamics. One of the key assumptions in this procedure is the ergodic property, namely the equivalence…

Statistical Mechanics · Physics 2024-01-09 Marco Baldovin , Raffaele Marino , Angelo Vulpiani

We consider the paradigm of an overdamped Brownian particle in a potential well, which is modulated through an external protocol, in the presence of stochastic resetting. Thus, in addition to the short range diffusive motion, the particle…

Statistical Mechanics · Physics 2020-03-25 Deepak Gupta , Carlos A. Plata , Arnab Pal

We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…

Statistical Mechanics · Physics 2015-03-19 Yuki Sughiyama , Masayuki Ohzeki

A central endeavor of thermodynamics is the measurement of free energy changes. Regrettably, although we can measure the free energy of a system in thermodynamic equilibrium, typically all we can say about the free energy of a…

Statistical Mechanics · Physics 2012-04-10 David A. Sivak , Gavin E. Crooks

In this paper, we study Jarzynski's equality and fluctuation theorems for diffusion processes. While some of the results considered in the current work are known in the (mainly physics) literature, we review and generalize these…

Mathematical Physics · Physics 2019-04-09 Carsten Hartmann , Christof Schuette , Wei Zhang

We describe some solvable models which illustrate the Jarzynski theorem and related fluctuation theorems. We consider a charged particle in the presence of magnetic field in a two dimensional harmonic well. In the first case the centre of…

Statistical Mechanics · Physics 2015-06-25 A. M. Jayannavar , Mamata Sahoo

The received wisdom in statistical mechanics is that isolated systems, when left to themselves, approach equilibrium. But under what circumstances does an equilibrium state exist and an approach to equilibrium take place? In this paper we…

Statistical Mechanics · Physics 2016-06-06 Charlotte Werndl , Roman Frigg

A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

Statistical Mechanics · Physics 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

We discovered an out-of-equilibrium transition in the ideal gas between two walls, divided by an inner, adiabatic, movable wall. The system is driven out-of-equilibrium by supplying energy directly into the volume of the gas. At critical…

Statistical Mechanics · Physics 2025-02-06 Yirui Zhang , Marek Litniewski , Karol Makuch , Pawel J. Zuk , Anna Maciolek , Robert Holyst

The Jarzynski estimator is a powerful tool that uses nonequilibrium statistical physics to numerically obtain partition functions of probability distributions. The estimator reconstructs partition functions with trajectories of the…

Statistical Mechanics · Physics 2022-05-17 Nobumasa Ishida , Yoshihiko Hasegawa

We have investigated the non-equilibrium nature of a lattice gas system consisting of a regular lattice of charged particles driven by an external electric field. For a big system, an exact solution cannot be obtained using a master…

Statistical Mechanics · Physics 2007-05-23 Wannapong Triampo , I Ming Tang , Jirasak Wong-Ekkabut

We compute the average work done by an external agent, driving a piston at constant speed, over a single particle gas going through an adiabatic compression and expansion process. To do so, we get the analytical expression relating the…

Classical Physics · Physics 2019-10-10 Carlos E. Álvarez , Nicolás Afanador , Gabriel Téllez

Jarzynski equality [Phys. Rev. E {\bf 56}, 5018 (1997)] is found to be valid with slight modefication for the transitions between nonequilibrium stationary states, as well as the one between equilibrium states. Also numerical results…

Statistical Mechanics · Physics 2007-05-23 Takahiro Hatano

We explore thermodynamic relations in non-equilibrium steady states with numerical experiments on a driven lattice gas. After operationally defining the pressure and chemical potential in the driven lattice gas, we confirm numerically the…

Statistical Mechanics · Physics 2009-11-07 Kumiko Hayashi , Shin-ichi Sasa

Most natural and engineered processes, such as biomolecular reactions, protein folding, and population dynamics, occur far from equilibrium and, therefore, cannot be treated within the framework of classical equilibrium thermodynamics. The…

Soft Condensed Matter · Physics 2016-01-07 Aykut Argun , Ali-Reza Moradi , Erçağ Pince , Gokhan Baris Bagci , Giovanni Volpe

We consider the statistical mechanics of a classical particle in a one-dimensional box subjected to a random potential which constitutes a Wiener process on the coordinate axis. The distribution of the free energy and all correlation…

Condensed Matter · Physics 2009-10-28 Kurt Broderix , Reiner Kree

Jarzynski's nonequilibrium work relation can be understood as the realization of the (hidden) time-generator reciprocal symmetry satisfied for the conditional probability function. To show this, we introduce the reciprocal process where the…

Statistical Mechanics · Physics 2018-02-09 T. Koide

This thesis is dedictaed to the study of fluctuation and correlation observables of hadronic equilibrium systems. The statistical hadronization model of high energy physics, in its ideal, i.e. non-interacting, gas approximation will be…

Nuclear Theory · Physics 2010-08-13 Michael Hauer

We introduce a straightforward, single-ensemble, path sampling approach to calculate free energy differences based on Jarzynski's relation. For a two-dimensional ``toy'' test system, the new (minimally optimized) method performs roughly one…

Computational Physics · Physics 2009-11-10 F. Marty Ytreberg , Daniel M. Zuckerman