English

Continuous non-equilibrium transition driven by the heat flow

Statistical Mechanics 2025-02-06 v3

Abstract

We discovered an out-of-equilibrium transition in the ideal gas between two walls, divided by an inner, adiabatic, movable wall. The system is driven out-of-equilibrium by supplying energy directly into the volume of the gas. At critical heat flux, we have found a continuous transition to the state with a low-density, hot gas on one side of the movable wall and a dense, cold gas on the other side. Molecular dynamic simulations of the soft-sphere fluid confirm the existence of the transition in the interacting system. We introduce a stationary state Helmholtz-like function whose minimum determines the stable positions of the internal wall. This transition can be used as a paradigm of transitions in stationary states and the Helmholtz-like function as a paradigm of the thermodynamic description of these states.

Keywords

Cite

@article{arxiv.2103.12765,
  title  = {Continuous non-equilibrium transition driven by the heat flow},
  author = {Yirui Zhang and Marek Litniewski and Karol Makuch and Pawel J. Zuk and Anna Maciolek and Robert Holyst},
  journal= {arXiv preprint arXiv:2103.12765},
  year   = {2025}
}

Comments

8 pages, 6 figures; paragraph one rewritten; comments added regarding maxEP, and figures 4, 5 and 6 are added; references added and typos corrected

R2 v1 2026-06-24T00:29:13.856Z