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We investigate the work dissipated during the irreversible unfolding of single molecules by mechanical force, using the simplest model necessary to represent experimental data. The model consists of two levels (folded and unfolded states)…

Biological Physics · Physics 2012-08-27 F. Ritort , C. Bustamante , I. Tinoco,

In thermodynamically characterizing a mixture comprising a finite number of molecules, we consider two kinds of protocol for producing a mixture from a pure substance. The first is a single alchemical operation, whereas the second is a…

Statistical Mechanics · Physics 2022-03-01 Akira Yoshida , Naoko Nakagawa

The work performed on a system in a microcanonical state by changes in a control parameter is characterized in terms of its statistics. The transition probabilities between eigenstates of the system Hamiltonians at the beginning and the end…

Statistical Mechanics · Physics 2014-01-21 Peter Talkner , Manuel Morillo , Juyeon Yi , Peter Hanggi

Starting from the probability distribution of finite N-body systems, which maximises the Havrda--Charv\'at entropy, we build a Stein-type goodness-of-fit test. The Maxwell--Boltzmann distribution is exact only in the thermodynamic limit,…

Mathematical Physics · Physics 2026-02-16 Jae Wan Shim

A refinement of an argument due to Maxwell for the equipartition of kinetic energy in a mixture of ideal gases with different masses is proposed. The argument is elementary, yet it may work as an illustration of the role of symmetry and…

Classical Physics · Physics 2007-05-23 L. Peliti

Paper in honour of Freeman Dyson on the occasion of his 80th birthday. Normal N-body systems relax to equilibrium distributions in which classical kinetic energy components are 1/2 kT, but, when inter-particle forces are an inverse cubic…

Statistical Mechanics · Physics 2009-11-10 D. Lynden-Bell , R. M. Lynden-Bell

In this paper we present a self-contained macroscopic description of diffusive systems interacting with boundary reservoirs and under the action of external fields. The approach is based on simple postulates which are suggested by a wide…

Statistical Mechanics · Physics 2015-12-18 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

We discuss and qualify a previously unnoticed connection between two different phenomena in the physics of nanoscale friction, general in nature and also met in experiments including sliding emu- lations in optical lattices, and protein…

Statistical Mechanics · Physics 2019-02-27 Franco Pellegrini , Emanuele Panizon , Giuseppe Santoro , Erio Tosatti

We introduce an information free energy for thermodynamic systems driven by external time-dependent parameters. We show that the latter is a nonequilibrium state function and that it is a natural generalization of the usual equilibrium and…

Statistical Mechanics · Physics 2012-01-19 Sebastian Deffner , Eric Lutz

We propose a new thermodynamic equality and several inequalities concerning the relationship between work and information for an isothermal process with Maxwell's demon. Our approach is based on the formulation a la Jarzynski of the…

Statistical Mechanics · Physics 2007-05-23 Takahiro Sagawa , Masahito Ueda

In this communication, complex systems with a near trivial dynamics are addressed. First, under the hypothesis of equiprobability in the asymptotic equilibrium, it is shown that the (hyper) planar geometry of an $N$-dimensional multi-agent…

Adaptation and Self-Organizing Systems · Physics 2012-10-25 Ricardo Lopez-Ruiz

In this study, one-dimensional systems of masses connected by springs, i.e., spring-chain systems, are investigated numerically. The average kinetic energy of chain-end particles of these systems is larger than that of other particles,…

Chaotic Dynamics · Physics 2015-05-18 Tetsuro Konishi , Tatsuo Yanagita

The rates at which energy and particle densities move to equalize arbitrarily large temperature and chemical potential differences in an isolated quantum system have an emergent thermodynamical description whenever energy or particle…

Strongly Correlated Electrons · Physics 2015-12-31 Romain Vasseur , Christoph Karrasch , Joel E. Moore

We study at the microscopic level the dynamics of a one-dimensional gravitationally interacting sticky gas. Initially, N identical particles of mass m with uncorrelated, randomly distributed velocities fill homogeneously a finite region of…

Statistical Mechanics · Physics 2007-05-23 J. C. Bonvin , Ph. A. Martin , J. Piasecki , X. Zotos

The Kawasaki nonlinear response relation, the transient fluctuation theorem, and the Jarzynski nonequilibrium work relation are all expressions that describe the behavior of a system that has been driven from equilibrium by an external…

Statistical Mechanics · Physics 2008-11-07 Gavin E. Crooks

We consider an ordinary differential equation with a unique hyperbolic attractor at the origin, to which we add a small random perturbation. It is known that under general conditions, the solution of this stochastic differential equation…

Probability · Mathematics 2023-05-05 Gerardo Barrera , Milton Jara

In a recent paper [Int. J. Mod. Phys. B {\bf 14}, 405 (2000)] we discussed the Bose-Einstein condensation (BEC) in the framework of Tsallis's nonextensive statistical mechanics. In particular, we studied an ideal gas of bosons in a…

Statistical Mechanics · Physics 2009-11-07 Luca Salasnich

Based on the Tsallis entropy, the nonextensive thermodynamic properties are studied as a q-deformation of classical statistical results using only probabilistic methods and straightforward calculations. It is shown that the constant in the…

Statistical Mechanics · Physics 2007-05-23 Franck Jedrzejewski

We consider thermodynamics of the excluded volume particles at finite temperature and chemical potential, in the low density approximation. We assume Boltzmann statistics and study the influence of the excluded volume on an ideal gas…

High Energy Physics - Phenomenology · Physics 2016-02-17 Krzysztof Redlich , Kacper Zalewski

Fluctuation relations allow for the computation of equilibrium properties, like free energy, from an ensemble of non-equilibrium dynamics simulations. Computing them for quantum systems, however, can be difficult, as performing dynamic…

Quantum Physics · Physics 2021-09-07 Lindsay Bassman , Katherine Klymko , Diyi Liu , Norman M. Tubman , Wibe A. de Jong