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Based on recent experiments, we describe the Mott insulating, but undimerized state of $TiOCl$ using the local-density approximation combined with multi-orbital dynamical mean field theory (LDA+DMFT) for this $3d^{1}$ system.Good agreement…

Strongly Correlated Electrons · Physics 2007-05-23 L. Craco , M. S. Laad , E. Müller-Hartmann

The dynamical mean-field theory together with the non-crossing approximation is used to set up a novel scheme to study the electronic structure of strongly correlated electron systems. The non-interacting band structure is obtained from a…

Strongly Correlated Electrons · Physics 2007-05-23 M. B. Zoelfl , Th. Pruschke , J. Keller , A. I. Poteryaev , I. A. Nekrasov , V. I. Anisimov

The low-energy properties of transition metal oxides (TMOs) are governed by the electrons occupying strongly correlated $d$-orbitals that are hybridized with surrounding ligand oxygen $p$ orbitals to varying degrees. Their physics is thus…

Strongly Correlated Electrons · Physics 2025-08-05 Samuel Milner , Steven Johnston , Adrian Feiguin

We present first principles density functional calculations and downfolding studies of the electronic and magnetic properties of the layered quantum spin system TiOCl. We discuss explicitely the nature of the exchange pathes and attempt to…

Strongly Correlated Electrons · Physics 2016-08-31 T. Saha-Dasgupta , Roser Valenti , H. Rosner , Claudius Gros

The spectral weight evolution of the low-dimensional Mott insulator TiOCl upon alkali-metal dosing has been studied by photoelectron spectroscopy. We observe a spectral weight transfer between the lower Hubbard band and an additional peak…

Strongly Correlated Electrons · Physics 2015-05-13 M. Sing , S. Glawion , M. Schlachter , M. R. Scholz , K. Goss , J. Heidler , G. Berner , R. Claessen

Topological insulators have become one of the most active research areas in condensed matter physics. This article reviews progress on the topic of electronic correlations effects in the two-dimensional case, with a focus on systems with…

Strongly Correlated Electrons · Physics 2013-03-08 M. Hohenadler , F. F. Assaad

We investigate correlation effects in two dimensional topological insulators (TI). In the first part, we discuss finite size effects for interacting systems of different sizes in a ribbon geometry. For large systems, there are two pairs of…

Strongly Correlated Electrons · Physics 2015-06-04 Y. Tada , R. Peters , M. Oshikawa , A. Koga , N. Kawakami , S. Fujimoto

We investigate proximity effects in a correlated heterostructure of a two-dimensional Mott insulator (MI) and a topological insulator (TI) by employing inhomogeneous dynamical mean-field theory. We show that the edge state of the TI induces…

Strongly Correlated Electrons · Physics 2015-06-15 Suguru Ueda , Norio Kawakami , Manfred Sigrist

We present a combined density-functional theory and dynamical mean-field theory (DFT+DMFT) study of the full structural phase space of rutile-based vanadium dioxide (VO$_2$), including also the less studied M2 and T phases, using an…

Strongly Correlated Electrons · Physics 2026-03-30 Peter Mlkvik , Nicola A. Spaldin , Claude Ederer

We investigate the effect of Na intercalation in the layered Mott insulator TiOCl within the framework of density functional theory. We show that the system remains always insulating for all studied Na concentrations, and the evolution of…

Strongly Correlated Electrons · Physics 2010-04-09 Yu-Zhong Zhang , Kateryna Foyevtsova , Harald O. Jeschke , Martin U. Schmidt , Roser Valenti

On the basis of ab initio density functional theory (DFT) calculations, we derive the underlying microscopic model Hamiltonian for TiOCl, a unique system that shows two consecutive phase transitions from a Mott insulator to a spin-Peierls…

Strongly Correlated Electrons · Physics 2008-11-07 Yu-Zhong Zhang , Harald O. Jeschke , Roser Valenti

We investigate electron correlation effects in stoichiometric Titanium Nitride (TiN) using a combination of electronic structure and many-body calculations. In a first step, the Nth-order muffin tin orbital technique is used to obtain…

Strongly Correlated Electrons · Physics 2015-05-13 H. Allmaier , L. Chioncel , E. Arrigoni

Electron correlation and long-range magnetic ordering have a significant impact on the electronic structure and physical properties of solids. Here, we investigate the electronic structure of ilmenite MnTiO$_{3}$ using room temperature…

Strongly Correlated Electrons · Physics 2025-06-13 Asif Ali , R. K. Maurya , Sakshi Bansal , B. H. Reddy , Ravi Shankar Singh

We have studied the electronic structure of the two-dimensional Heisenberg antiferromagnet VOCl using photoemission spectroscopy and density functional theory including local Coulomb repulsion. From calculated exchange integrals and the…

Strongly Correlated Electrons · Physics 2009-10-16 S. Glawion , M. R. Scholz , Y. -Z. Zhang , R. Valenti , T. Saha-Dasgupta , M. Klemm , J. Hemberger , S. Horn , M. Sing , R. Claessen

We study the effects of an orbital magnetic field on the Mott metal-insulator transition in the Hubbard-Hofstadter model. We demonstrate that sufficiently large magnetic fields induce a Mott insulator-to-metal phase transition supporting…

Strongly Correlated Electrons · Physics 2025-10-28 Georg Rohringer , Anton A. Markov

We present results for the momentum-resolved single-particle spectral function of the low-dimensional system TiOCl in the insulating state, obtained by a combination of ab initio Density Functional Theory (DFT) and Variational Cluster (VCA)…

Strongly Correlated Electrons · Physics 2009-10-01 M. Aichhorn , T. Saha-Dasgupta , R. Valenti , S. Glawion , M. Sing , R. Claessen

We investigate the band structure of chromium nitride using the $N$th-order muffin-tin orbitals (NMTO) based downfolding technique. We obtain downfolded Cr $d$ bands including both $e_{g}$ and $t_{2g}$ states and the hopping integrals of…

Materials Science · Physics 2012-04-03 Xiaofeng Wang , Min Zhu , Juan Huang , Wenhui Xie

We investigate the Hubbard model on the honeycomb lattice with intrinsic spin orbit interactions as a paradigm for two-dimensional topological band insulators in the presence of interactions. Applying a combination of Hartree-Fock theory,…

Strongly Correlated Electrons · Physics 2015-03-13 Stephan Rachel , Karyn Le Hur

Electronic structure calculations on the low dimensional spin-1/2 compound TiOCl were performed at several pressures in the orthorhombic phase, finding that the structure is quasi-one-dimensional. The Ti3+ (d1) ions have one t2g orbital…

Strongly Correlated Electrons · Physics 2010-12-15 A. Piñeiro , V. Pardo , D. Baldomir , S. Blanco-Canosa , F. Rivadulla , J. E. Arias , J. Rivas

We investigate the effect of tuning the phonon energy on the correlation effects in models of electron-phonon interactions using DMFT. In the regime where itinerant electrons, instantaneous electron-phonon driven correlations and static…

Strongly Correlated Electrons · Physics 2015-05-13 J. P. Hague , N. d'Ambrumenil
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