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An algorithm$^{\ref{Fig1}}$ has been developed with the purpose of obtaining inverse potentials, where the Riccati-type non-linear differential equation, also called phase equation, has been kept in tandem with the Variational Monte Carlo…

Nuclear Theory · Physics 2024-04-09 Anil Khachi , Shikha Awasthi , Lalit Kumar , O. S. K. S Sastri

Broken-symmetry (BS) approaches are widely employed to evaluate Heisenberg exchange parameters, primarily in combination with DFT calculations. For many magnetic materials, BS-DFT calculations give reasonable estimations of exchange…

Chemical Physics · Physics 2025-06-02 Naoya Iwahara , Zhishuo Huang , Akseli Mansikkamäki , Liviu F. Chibotaru

The Born-Oppenheimer potential for the $^1\Sigma_g^+$ state of H$_2$ is obtained in the range of 0.1 -- 20 au, using analytic formulas and recursion relations for two-center two-electron integrals with exponential functions. For small…

Chemical Physics · Physics 2015-05-19 Krzysztof Pachucki

Refined calculations of the radial mismatch correction, $\delta_{C2}$, to superallowed $0^+\rightarrow0^+$ nuclear $\beta$ decay are performed using the shell model with realistic Woods-Saxon radial wave functions. Two important…

Nuclear Theory · Physics 2025-08-26 L. Xayavong , N. A. Smirnova , F. Nowacki

A realistic evaluation of Coulomb potential has been made for some selected nuclei using the available model-independent data for the charge density and the recent development of Coulomb energy-density functional. Within the Woods-Saxon…

Nuclear Theory · Physics 2023-03-03 L. Xayavong , Y. Lim

Background: An accurate way to incorporate long range Coulomb interaction alongside short-range nuclear interaction has been a challenge for theoretical physicists. Purpose: In this paper, we propose a methodology based on the reference…

Nuclear Theory · Physics 2023-08-23 O. S. K. S. Sastri , Arushi Sharma , Ayushi Awasthi

The quantum phase estimation algorithm stands as the primary method for determining the ground state energy of a molecular electronic Hamiltonian on a quantum computer. In this context, the ability to initialize a classically tractable…

We present an extensive review of the two-dimensional finite difference Hartree--Fock (FD HF) method, and present its implementation in the newest version of X2DHF, the FD HF program for atoms and diatomic molecules. The program was…

Computational Physics · Physics 2025-03-12 Jacek Kobus , Susi Lehtola

Separating the Coulomb potential into short-range and long-range components enables the use of different electron repulsion integral algorithms for each component. The short-range part can be efficiently computed using the analytical…

Chemical Physics · Physics 2023-09-27 Qiming Sun

A translationally invariant formulation of the Hartree-Fock (HF) $\Gamma$-point approximation is presented. This formulation is achieved through introduction of the Minimum Image Convention (MIC) at the level of primitive two-electron…

Materials Science · Physics 2016-08-16 C. J. Tymczak , Valéry T. Weber , Eric Schwegler , Matt Challacombe

We present an implementation and analysis of a stochastic high performance algorithm to calculate the correlation energy of three dimensional periodic systems in second-order M{\o}ller-Plesset perturbation theory (MP2). In particular we…

Chemical Physics · Physics 2018-02-12 Tobias Schäfer , Benjamin Ramberger , Georg Kresse

Delocalization errors, such as charge-transfer and some self-interaction errors, plague computationally-efficient and otherwise-accurate density functional approximations (DFAs). Evaluating a semi-local DFA non-self-consistently on the…

Chemical Physics · Physics 2023-01-02 Aaron D. Kaplan , Chandra Shahi , Pradeep Bhetwal , Raj K. Sah , John P. Perdew

Density-functional theory with on-site $U$ and inter-site $V$ Hubbard corrections (DFT+$U$+$V$) is a powerful and accurate method for predicting various properties of transition-metal compounds. However, its accuracy depends critically on…

Materials Science · Physics 2025-12-23 Wooil Yang , Iurii Timrov , Francesco Aquilante , Young-Woo Son

Exchange-correlation potentials vxc and energy densities exc are derived for integer and fractional electron counts using an orbital-averaged Kohn-Sham inversion procedure. The reference densities for inversion come from full configuration…

Chemical Physics · Physics 2025-04-30 Vaibhav Khanna , Bikash Kanungo , Jeffrey Hatch , Joshua Kammeraad , Paul M. Zimmerman

The need for accurate calculations on atoms and diatomic molecules is motivated by the opportunities and challenges of such studies. The most commonly-used approach for all-electron electronic structure calculations in general - the linear…

Chemical Physics · Physics 2019-08-19 Susi Lehtola

A convergent numerical method for $\alpha$-dissipative solutions of the Hunter-Saxton equation is derived. The method is based on applying a tailor-made projection operator to the initial data, and then solving exactly using the generalized…

Numerical Analysis · Mathematics 2025-05-09 Thomas Christiansen , Katrin Grunert , Anders Nordli , Susanne Solem

We present a method for constructing a scalar-relativistic pseudopotential which provides exact agreement with relativistic Dirac-Slater all-electron eigenvalues at the reference configuration. All-electron wave functions are…

Materials Science · Physics 2009-10-31 Ilya Grinberg , Nicholas J. Ramer , Andrew M. Rappe

Many-body techniques for the calculation of quasielastic nuclear matter response functions in the fully antisymmetrized random phase approximation on a Hartree-Fock basis are discussed in detail. The methods presented here allow for an…

Nuclear Theory · Physics 2009-10-31 A. De Pace

Diffusing Alpha-emitters Radiation Therapy (DaRT) is a new method for treating solid tumors using alpha particles. Unlike conventional radiotherapy, where the physical models for dose calculations are known and routinely used, for DaRT a…

Medical Physics · Physics 2021-11-09 Guy Heger , Lior Arazi

Reporting extensions of a recently developed approach to density functional theory with correct long-range be-havior (Phys. Rev. Lett. 94, 043002 (2005)). The central quantities are a splitting functional gamma[n] and a complementary…

Materials Science · Physics 2017-09-13 Ester Livshits , Roi Baer
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