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The effect of temperature on friction and slip at the liquid-solid interface has attracted attention over the last twenty years, both numerically and experimentally. However, the role of temperature on slip close to the glass transition has…

Soft Condensed Matter · Physics 2023-02-22 Suzanne Lafon , Alexis Chennevière , Frédéric Restagno , Samy Merabia , Laurent Joly

A recently proposed expression to describe the temperature and volume dependences of the structural (or alpha) relaxation time is discussed. This equation satisfies the scaling law for the relaxation times, tau = f(TV^g), where T is…

Soft Condensed Matter · Physics 2009-11-13 R. Casalini , C. M. Roland

The relaxation of the specific heat and the entropy to their equilibrium values is investigated numerically for the three-dimensional Coulomb glass at very low temperatures. The long time relaxation follows a stretched exponential function,…

Disordered Systems and Neural Networks · Physics 2016-08-15 A. Díaz-Sánchez , A. Pérez-Garrido

Using a general model for the equilibrium dynamics of supercooled liquids, I compute from molecular properties the emergent length and time scales that govern the nonequilibrium relaxation behavior of amorphous ice prepared by rapid…

Statistical Mechanics · Physics 2015-06-18 David T. Limmer

Relaxation processes in supercooled liquids are known to exhibit interesting as well as complex behavior. One of the hallmarks of this relaxation process observed in the measured auto correlation function is occurrence of multiple steps of…

Soft Condensed Matter · Physics 2018-08-01 Rajsekhar Das , Indrajit Tah , Smarajit Karmakar

We discuss a novel approach, the point-to-set correlation functions, that allows to determine relevant static and dynamic length scales in glass-forming liquids. We find that static length scales increase monotonically when the temperature…

Disordered Systems and Neural Networks · Physics 2013-07-04 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

The present study introduces a renormalization based approach to investigate the relaxation dynamics within supercooled liquids. By applying a numerical scale transformation to potential energies along the temporal axis, we have established…

Soft Condensed Matter · Physics 2025-04-01 B. Zhang , D. M. Zhang , D. Y. Sun , X. G. Gong

Recently a new approach to the determination of dynamic correlation lengths, {\xi}, for supercooled liquids, based on the properties of the slow (picosecond) vibrational dynamics, was carried out [L. Hong, V.N. Novikov, and A.P. Sokolov,…

Soft Condensed Matter · Physics 2015-05-30 D. Fragiadakis , R. Casalini , C. M. Roland

Molecular dynamics simulations are performed for a supercooled simple liquid with changing the system size from N=108 to $10^4$ to examine possible finite-size effects. Although almost no systematic deviation is detected in the static pair…

Soft Condensed Matter · Physics 2007-05-23 Kang Kim , Ryoichi Yamamoto

Quantum effects in material systems are often pronounced at low energies and become insignificant at high temperatures. We find that, perhaps counterintuitively, certain quantum effects may follow the opposite route and become sharp when…

Statistical Mechanics · Physics 2015-09-08 Z. Nussinov , F. Nogueira , M. Blodgett , K. F. Kelton

Using two extremely different models of glass formers in two and three dimensions we demonstrate how to encode the subtle changes in the geometric rearrangement of particles during the scenario of the glass transition. We construct a…

Statistical Mechanics · Physics 2015-05-13 Laurent Boue , Edan Lerner , Itamar Procaccia , Jacques Zylberg

We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…

Soft Condensed Matter · Physics 2022-12-16 Camille Scalliet , Benjamin Guiselin , Ludovic Berthier

We propose a dynamic structure of coupled dynamic molecular strings for supercooled small polar molecule liquids and accordingly we obtain the Hamiltonian of the rotational degrees of freedom of the system. From the Hamiltonian, the…

Disordered Systems and Neural Networks · Physics 2009-11-10 Y. N. Huang , C. J. Wang , E. Riande

The dynamics of Lennard-Jones fluid is studied through extended mode coupling theory (MCT) with the inclusion of the slow mode of defect density. Inclusion of defect density facilitates the liquid like state for temperatures much lower than…

Statistical Mechanics · Physics 2009-11-07 Sudha Srivastava , Shankar P. Das

Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. The short-time $\beta$-relaxation is generally attributed to spatially local processes involving the rattling motion of a…

Statistical Mechanics · Physics 2016-03-02 Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

Over the last decade computer simulations have had an increasing role in shedding light on difficult statistical physical phenomena and in particular on the ubiquitous problem of the glass transition. Here in a wide variety of materials the…

Statistical Mechanics · Physics 2015-06-04 Smarajit Karmakar , Itamar Procaccia

Diverse material classes exhibit practically identical behavior when made viscous upon cooling toward the glass transition, suggesting a common theoretical basis. The first-principles scaling laws that have been proposed to describe the…

When we lower the temperature of a liquid, at some point we meet a first order phase transition to the crystal. Yet, under certain conditions it is possible to keep the system in its metastable phase and to avoid crystallization. In this…

Statistical Mechanics · Physics 2009-05-12 Andrea Cavagna

We demonstrate, via numerical simulations, that the relaxation dynamics of supercooled liquids correlates well with a plastic length scale measuring a particle's response to impulsive localized perturbations and weakly to measures of local…

Soft Condensed Matter · Physics 2022-06-23 Yan-Wei Li , Yugui Yao , Massimo Pica Ciamarra

We show that a generalized fluctuation-dissipation relation applies upon instantaneously increasing the temperature of a deeply supercooled liquid. This has the same two-step shape of the relation found upon cooling the liquid, but with…

Statistical Mechanics · Physics 2013-05-30 Nicoletta Gnan , Claudio Maggi , Giorgio Parisi , Francesco Sciortino