English

Possible Universal Relation Between Short time $\beta$-relaxation and Long time $\alpha$-relaxation in Glass-forming Liquids

Soft Condensed Matter 2018-08-01 v2 Disordered Systems and Neural Networks Statistical Mechanics

Abstract

Relaxation processes in supercooled liquids are known to exhibit interesting as well as complex behavior. One of the hallmarks of this relaxation process observed in the measured auto correlation function is occurrence of multiple steps of relaxation. The shorter time relaxation is known as the β\beta-relaxation which is believed to be due to the motion of particles in the cage formed by their neighbors. One the other hand longer time relaxation, the α\alpha-relaxation is believed to be the main relaxation process in the liquids. The timescales of these two relaxations processes dramatically separate out with supercooling. In spite of decades of researches, it is still not clearly known how these relaxation processes are related to each other. In this work we show that, there is a possible universal relation between short time β\beta-relaxation and the long time α\alpha-relaxation. This relation is found to be quite robust across many different model systems. Finally we show that length scale obtained from the finite size scaling analysis of β\beta timescale is same as that of length scale associated with the dynamic heterogeneity in both two and three dimensions.

Keywords

Cite

@article{arxiv.1712.08033,
  title  = {Possible Universal Relation Between Short time $\beta$-relaxation and Long time $\alpha$-relaxation in Glass-forming Liquids},
  author = {Rajsekhar Das and Indrajit Tah and Smarajit Karmakar},
  journal= {arXiv preprint arXiv:1712.08033},
  year   = {2018}
}

Comments

8 pages and 8 figures with supplementary information