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Apparent finite-size effects in the dynamics of supercooled liquids

Soft Condensed Matter 2007-05-23 v3

Abstract

Molecular dynamics simulations are performed for a supercooled simple liquid with changing the system size from N=108 to 10410^4 to examine possible finite-size effects. Although almost no systematic deviation is detected in the static pair correlation functions, it is demonstrated that the structural α\alpha relaxation in a small system becomes considerably slower than that in larger systems for temperatures below TcT_c at which the size of the cooperative particle motions becomes comparable to the unit cell length of the small system. The discrepancy increases with decreasing temperature.

Keywords

Cite

@article{arxiv.cond-mat/9903260,
  title  = {Apparent finite-size effects in the dynamics of supercooled liquids},
  author = {Kang Kim and Ryoichi Yamamoto},
  journal= {arXiv preprint arXiv:cond-mat/9903260},
  year   = {2007}
}

Comments

4 pages 5 figures