Related papers: Solvation force for long ranged wall-fluid potenti…
In this Letter we consider a liquid mixture confined between two thermally conducting walls subjected to a stationary temperature gradient. While in a one-component liquid non-equilibrium fluctuation forces appear inside the liquid layer…
The growing correlation length observed in supercooled liquids as their temperature is lowered has been studied with the aid of a single occupancy cell model. This model becomes more accurate as the density of the system is increased. One…
We simulate a hard-sphere liquid in confined geometry where the separation of the two parallel, hard walls is smaller than two particle diameters. By systematically reducing the wall separation we analyze the behavior of structural and…
Liquid slip flow with a Knudsen number Kn = 0.001-0.1 plays a dominant role in confined flow channels. Its physical origin can be attributed to the intermolecular fluid-solid (F-S) interaction force. To this end, we propose herein…
The phase behavior of fluids near weakly attractive substrates is studied by computer simulations of the coexistence curve of a Lennard-Jones (LJ) fluid confined in a slitlike pore. The temperature dependence of the density profiles of the…
We investigate phase separation of near-critical binary mixtures between parallel symmetric walls in the strong adsorption regime. We take into account the renormalization effect due to the critical fluctuations using the recent local…
The dynamical properties of a three dimensional model glass, the frustrated Ising lattice gas (FILG) are studied by Monte Carlo simulations. We present results of compression experiments, where the chemical potential is either slowly or…
In a recent article, we showed how the properties of the density-density correlation function and its integral, the local structure factor, in the fluid interfacial region, in systems with short-ranged forces, can be understood…
Structural and thermodynamic properties of ionic fluids are related to those of a simpler ``mimic'' system with short ranged intermolecular interactions in a spatially varying effective field by use of Local Molecular Field (LMF) theory,…
Some time ago, Fisher and de Gennes pointed out that long-ranged correlations in a fluid close to its critical point Tc cause distinct forces between immersed colloidal particles which can even lead to flocculation [C. R. Acad. Sc. Paris B…
Using density functional theory we calculate the density profiles of a binary solvent adsorbed around a pair of big solute particles. All species interact via repulsive Gaussian potentials. The solvent exhibits fluid-fluid phase separation…
Effective Casimir forces induced by thermal fluctuations in the vicinity of bulk critical points are studied by means of Monte Carlo simulations in three-dimensional systems for film geometries and within the experimentally relevant Ising…
In statistical physics, it is well established that the liquid-gas (LG) phase transition with divergent critical fluctuations belongs to the Ising universality class. Whether non-equilibrium effects can alter this universal behavior remains…
A density functional for the lattice gas (Ising model) from fundamental measure theory is applied to the problem of droplet states in three-dimensional, finite systems. Similar to previous simulation studies, the sequence of droplets…
We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of…
We calculate the effective force between two oppositely charged and similarly charged ions fixed in water as a function of separation distance R. At short separations, R less than 1 nm, the effective force is vastly different from the…
Using concepts from classical density functional theory (DFT) we investigate the freezing of a two-dimensional (2D) system of ultra-soft particles in a one-dimensional (1D) external potential; a phenomenon often called laser-induced…
The article is devoted to the mathematical analysis of a fluid-structure interaction system where the fluid is compressible and heat conducting and where the structure is deformable and located on a part of the boundary of the fluid domain.…
It is theoretically shown that the excess liquid-liquid interfacial tension between two electrolyte solutions as a function of the ionic strength I behaves asymptotically as O(- I^0.5) for small I and as O(+- I) for large I. The former…
Extended de Gennes-Fisher (EdGF) local-functional method has been applied to the thermodynamic Casimir effect {\it away} from the critical point for systems in the Ising universality class confined between parallel plane plates with…