English

Liquid-Gas Criticality of Hyperuniform Fluids

Statistical Mechanics 2026-04-07 v4 Soft Condensed Matter

Abstract

In statistical physics, it is well established that the liquid-gas (LG) phase transition with divergent critical fluctuations belongs to the Ising universality class. Whether non-equilibrium effects can alter this universal behavior remains a fundamental open question. In this work, we theoretically prove that non-equilibrium hyperuniform (HU) fluids with additional center-of-mass conservation exhibit LG criticality different from the Ising universality class. As a specific case, we investigate a 2D HU fluid composed of active spinners, where phase separation is driven by dissipative collisions. Strikingly, at the critical point, the 2D HU fluid displays finite density fluctuations S(q)qηS(q)\sim q^{\eta} with η=0\eta=0, while the compressibility still diverges. The critical point is thus calm yet highly susceptible, in fundamental violation of the conventional fluctuation-dissipation relation. Consistently, we observe short-range pair correlation functions coexisting with quasi-long-range response functions at the critical point. Based on a generalized Model B and renormalization-group analysis, we prove that hyperuniformity reduces the upper critical dimension dcd_c from 44 to 22. Moreover, the critical point exhibits Gaussian density fluctuations and non-divergent energy fluctuations. Furthermore, the HU fluid undergoes non-conventional spinodal decomposition. The origin of the above anomalies lies in the non-equilibrium nature of the system which obeys a generalized fluctuation-dissipation relation 2Im χ(q,ω)=ωC(q,ω)/kBTeff(q)2\mathrm{Im}~ \chi(q,\omega) ={\omega }C(q,\omega)/{k_B T_{\text{eff}}(q)} with a scale-dependent effective temperature Teff(q)q2T_{\rm eff}(q) \propto q^2. These findings establish a striking exception to conventional paradigms of critical phenomena and illustrate how non-equilibrium forces can fundamentally reshape universality classes.

Keywords

Cite

@article{arxiv.2507.06023,
  title  = {Liquid-Gas Criticality of Hyperuniform Fluids},
  author = {Shang Gao and Hao Shang and Hao Hu and Yu-Qiang Ma and Qun-Li Lei},
  journal= {arXiv preprint arXiv:2507.06023},
  year   = {2026}
}

Comments

22 pages, 6 figures