Related papers: Interstellar triply deuterated ammonia
We aimed to study the chemistry of the circumnuclear molecular gas of NGC1068, and to compare it with those of the starburst galaxies M82 and NGC253. Using the IRAM-30m telescope, we observed the inner 2 kpc of NGC1068 between 86.2 GHz and…
The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…
Context. Massive star-formation leads to enrichment with heavy elements of the interstellar medium. On the other hand, the abundance of heavy elements is a key parameter to study the star-formation history of galaxies. Furthermore, the…
We have carried out the NH$_3$ $(J,K)=(1,1),(2,2),$ and $(3,3)$ mapping observations toward the Galactic infrared bubble N49 (G28.83-0.25) using the Nobeyama 45 m telescope. Three NH$_3$ clumps (A, B, and C) were discovered along the…
Deuterium enrichment of interstellar methanol is reproduced experimentally for the first time via grain-surface H-D substitution in solid methanol at an atomic D/H ratio of 0.1. Although previous gas-grain models successfully reproduce the…
Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…
A new interstellar molecule, CH$_3$NCO (methyl isocyanate), has been detected using the 12 m telescope of the Arizona Radio Observatory (ARO). CH$_3$NCO was identified in spectra covering 48 GHz (68-116 GHz) in the 3 mm segment of a…
We report the detection of D2CO in a sample of starless dense cores, in which we previously measured the degree of CO depletion. The deuterium fractionation is found extremely high, [D2CO]/[H2CO] ~ 1-10 %, similar to that reported in…
We present a study of the abundances and physical conditions in the interstellar gas toward the heavily reddened star HD 192639 [E_(B-V) = 0.64], based on analysis of FUSE and HST/STIS spectra covering the range from 912 to 1361 A. This…
(Abridged) Aims. In the present part of our survey we search for ammonia emitters in the Aquila rift complex which trace the densest regions of molecular clouds. Methods. From a CO survey carried out with the Delingha 14-m telescope we…
We report the detection of the (J,K) = (1,1), (2,2), and (3,3) inversion lines of ammonia (NH3) towards the south--western molecular lobe in M82. The relative intensities of the ammonia lines are characterized by a rotational temperature of…
Theory predicts, and observations confirm, that the column density ratio of a molecule containing D to its counterpart containing H can be used as an evolutionary tracer in the low-mass star formation process. Since it remains unclear if…
Hydrocarbons are ubiquitous in the interstellar medium, observed in diverse environments ranging from diffuse to molecular dark clouds and strong photon-dominated regions near HII regions. Recently, two broad diffuse interstellar bands…
Methyl acetate (CH_3COOCH_3) has been recently observed by IRAM 30 m radio telescope in Orion though the presence of its deuterated isotopomers is yet to be confirmed. We therefore study the properties of various forms of methyl acetate,…
The quantity of NH3 produced on grain surfaces in the prestellar core is thought to be one of the determining factors regarding the chemical complexity achievable at later stages of stellar birth. In order to investigate how this quantity…
The deuterium abundances inferred from observations of the interstellar medium within 1-2 kpc of the Sun range over a factor of three and the corresponding oxygen abundances show an even larger dispersion. While the lower D (and O)…
The (J,K) = (1,1), (2,2), (3,3), and (4,4) inversion lines of ammonia (NH3) have been detected toward the nuclear 40'' sized bar of the nearby spiral galaxy Maffei 2. The relative intensities of the ammonia lines are characterized by a…
Odin has successfully observed the molecular core rho Oph A in the 572.5 GHz rotational ground state line of ammonia, NH3 (J,K = 1,0 - 0,0). The interpretation of this result makes use of complementary molecular line data obtained from the…
The impact of the vapor pressure difference between deuterated and nondeuterated condensing molecules in planetary atmospheres is quantitatively assessed. This difference results in a loss of deuterium in the vapor phase above the…
Context. Multi-wavelength studies of galaxies and galactic nuclei allow us to build a relatively more complete picture of the interstellar medium (ISM), especially in the dusty regions of starburst galaxies. An understanding of the physical…