Related papers: Interstellar triply deuterated ammonia
Deuterium and lithium are light elements of high cosmological and astrophysical importance. In this work we report the first detection of deuterated molecules and a search for lithium hydride, 7LiH, at redshift z=0.89 in the spiral galaxy…
NH3 and CH3OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH3CN and HCOOCH3. Despite a number of recent studies, little is known about their abundances in the…
Aims. We measure the deuterium fraction, RD, and the CO-depletion factor, fd, toward a number of starless and protostellar cores in the L1688 region of the Ophiuchus molecular cloud complex and search for variations based upon environmental…
Context. The number of identified complex organic molecules (COMs) in inter- and circumstellar gas-phase environments is steadily increasing. Recent laboratory studies show that many such species form on icy dust grains. At present only…
Nitrogen-bearing molecules display variable isotopic fractionation levels in different astronomical environments such as in the interstellar medium or in the Solar System. Models of interstellar chemistry are unable to induce nitrogen…
The crystals of potassium hydrogen carbonate (KHCO3) and the KDCO3 analogue are isomorphous. They are composed of hydrogen or deuterium bonded centrosymmetric dimers (HCO3-)(2) or (DCO3-)(2). The space group symmetry of KHpD1-pCO3 (p…
We present Very Large Array observations of NH3 (1,1) and (2,2) in a sample of six infrared-dark clouds (IRDCs) with distances from 2 to 5 kpc. We find that ammonia serves as an excellent tracer of dense gas in IRDCs, showing no evidence of…
We discuss the measurements of deuterium abundances in high redshift quasar absorbers, in the solar system and in the interstellar medium. We present new results that indicate spatial variations of the deuterium abundance in the…
Many chemical models of dense interstellar clouds predict that the majority of gas-phase elemental nitrogen should be present as N2, with an abundance approximately five orders of magnitude less than that of hydrogen. As a homonuclear…
We present high angular resolution observations of the NH$_3$(1,1), (2,2) and (3,3) inversion transitions from the Egg Nebula, the archetypical proto-planetary nebula. The spatial distribution and kinematics of the emission in all three…
We present 12 mm Mopra observations of the dense (>10^3 cm^-3 ) molecular gas towards the north-east (NE) of the W28 supernova remnant (SNR). This cloud is spatially well-matched to the TeV gamma-ray source HESS J1801-233 and is known to be…
We observed 42 molecular condensations within previously identified bright-rimmed clouds in the ammonia rotational inversion lines NH3 (1,1), (2,2), (3,3) and (4,4) using the Green Bank Telescope in Green Bank, West Virginia. Using the…
Inferences of molecular compositions of exoplanetary atmospheres have generally focused on C, H, and O-bearing molecules. Recently, additional absorption in HST WFC3 transmission spectra around 1.55$\mu$m has been attributed to…
We present a comprehensive examination of interstellar P and Cl abundances based on an analysis of archival spectra acquired with the Space Telescope Imaging Spectrograph of the Hubble Space Telescope and the Far Ultraviolet Spectroscopic…
H$_{\rm I}$ 21-cm and $^{12}$CO 2.6-mm line emissions respectively trace the atomic and molecular gas phases, but they miss most of the opaque H$_{\rm I}$ and diffuse H$_2$ present in the Dark Neutral Medium (DNM) at the transition between…
The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation…
It is a fact that interstellar formation processes are thermodynamically affected. Based on this, the seven heterocycles; imidazole, pyridine, pyrimidine, pyrrole, quinoline, isoquinoline and furan that have been searched for from different…
Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply…
We investigate 35 pre-stellar cores and 36 proto-stellar cores in the Perseus molecular cloud. We find a very tight correlation between the physical parameters describing the N2H+ and NH3 gas. Both the velocity centroids and the line widths…
Despite the detection of numerous interstellar complex organic molecules (iCOMs) for decades, it is still a matter of debate whether they are synthesized in the gas-phase or on the icy surface of interstellar grains. In the past, molecular…