Related papers: Interstellar triply deuterated ammonia
Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS…
Observations of chemical species can provide an insight into the physical conditions of the emitting gas but it is important to understand how their abundances and excitation vary within different heating environments. C$_2$H is a molecule…
We have observed the deuterated gas in the high-mass star formation region IRAS 05345+3157 at high-angular resolution, in order to determine the morphology and the nature of such gas. We have mapped the N2H+ (1-0) line with the Plateau de…
We study deuterium fractionation in two massive starless/early-stage cores C1-N and C1-S in Infrared Dark Cloud (IRDC) G028.37+00.07, first identified by Tan et al. (2013) with ALMA. Line emission from multiple transitions of $\rm N_2H^+$…
Deuterium was primarily created during the Big Bang Nucleosynthesis (BBN). This fact, alongside its fractionation reactions resulting in enhanced abundances of deuterated molecules, means that these abundances can be used to better…
To investigate whether distinctions exist between low and high-luminosity Class II 6.7-GHz methanol masers, we have undertaken multi-line mapping observations of various molecular lines, including the NH3(1,1), (2,2), (3,3), (4,4) and…
In this work we present the first attempt of modelling the deuterium chemistry in the massive young protostellar core NGC 2264 CMM3. We investigated the sensitivity of this chemistry to the physical conditions in its surrounding…
We present new models of the deuterium chemistry in protoplanetary disks, including, for the first time, multiply deuterated species. We use these models to explore whether observations in combination with models can give us clues as to…
In the past decade, much progress has been made in characterising the processes leading to the enhanced deuterium fractionation observed in the ISM and in particular in the cold, dense parts of star forming regions such as protostellar…
While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds…
We present N2D+ 3-2 (IRAM) and H2D+ 1_11 - 1_10 and N2H+ 4-3 (JCMT) maps of the small cluster-forming Ophiuchus B2 core in the nearby Ophiuchus molecular cloud. In conjunction with previously published N2H+ 1-0 observations, the N2D+ data…
We report extensive theoretical calculations on the rotation-inversion excitation of interstellar ammonia (NH3) due to collisions with atomic and molecular hydrogen (both para- and ortho-H2). Close-coupling calculations are performed for…
Although the deuterium fraction is known to be a powerful evolutionary tracer, its variation within individual molecular cloud cores is still poorly understood. The northern $\int$-shaped filament and 20 individual starless cores in the…
The abundance of deuterated molecules in a star-forming region is sensitive to the environment in which they are formed. Deuteration fractions therefore provide a powerful tool for studying the physical and chemical evolution of a…
Observations with the Short Wavelength Spectrometer (SWS) onboard the {\it Infrared Space Observatory} (ISO) have led to the first detection of the methyl radical ${\rm CH_3}$ in the interstellar medium. The $\nu_2$ $Q-$branch at 16.5…
To measure interstellar atomic deuterium abundances, we used the Interstellar Medium Absorption Profile Spectrograph (IMAPS) to obtain spectra of gamma2 Vel and zeta Pup over the wavelength interval 930-1150 A at a resolving power of…
Context : Despite the low cosmic abundance of deuterium (D/H ~ 1e-5), large degrees of deuterium fractionation in molecules are observed in star forming regions with enhancements that can reach 13 orders of magnitude, which current models…
Using the Green Bank Telescope (GBT), we have obtained accurate measurements of the $^{14}$N/$^{15}$N isotopic ratio in ammonia in two nearby cold, dense molecular clouds, Barnard~1 and NGC 1333. The $^{14}$N/$^{15}$N ratio in Barnard~1,…
We present an extensive analysis of the gas-phase abundances and depletion behaviors of neutron-capture elements in the interstellar medium (ISM). Column densities (or upper limits to the column densities) of Ga II, Ge II, As II, Kr I, Cd…
At the low temperatures ($\sim$10 K) and high densities ($\sim$100,000 H$_2$ molecules per cc) of molecular cloud cores and protostellar envelopes, a large amount of molecular species (in particular those containing C and O) freeze-out onto…