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Fundamental bounds on quadratic electromagnetic metrics are formulated and solved via convex optimization. Both dual formulation and method-of-moments formulation of the electric field integral equation are used as key ingredients. The…

Computational Physics · Physics 2021-12-02 Jakub Liska , Lukas Jelinek , Miloslav Capek

The description of weakly bound electronic states is especially difficult with atomic orbital basis sets. The diffuse atomic basis functions that are necessary to describe the extended electronic state generate significant linear…

Chemical Physics · Physics 2019-12-30 Susi Lehtola

By using the plane-wave expansion for the electromagnetic-field vector potential, transition matrix elements between the relativistic bound and unbound states of hydrogenic atoms were expressed explicitly in terms of finite series made of…

Quantum Physics · Physics 2014-12-17 J. Seke , A. V. Soldatov , M. Polak , G. Adam

We present equations of motion (EOMs) for general time-dependent wave functions with exponentially parametrized biorthogonal basis sets. The equations are fully bivariational in the sense of the time-dependent bivariational principle…

Chemical Physics · Physics 2023-05-08 Mads Greisen Højlund , Alberto Zoccante , Ove Christiansen

The thermodynamic entropy of coarse-grained (CG) models stands as one of the most important properties for quantifying the missing information during the CG process and for establishing transferable (or extendible) CG interactions. However,…

Chemical Physics · Physics 2024-04-10 Jaehyeok Jin , David R. Reichman

Ensemble Density Functional Theory (EDFT) is a promising extension to Density Functional Theory (DFT) for calculating excited states. While Kohn-Sham eigenvalue differences underestimate gaps, EDFT has been shown to provide more accurate…

Materials Science · Physics 2026-02-10 Gregory G. V. Kenning , Remi J. Leano , David A. Strubbe

We extend previous work applying elementary matrix mechanics to one-dimensional periodic arrays (to generate energy bands) to two-dimensional arrays. We generate band structures for the square lattice "2D Kronig-Penney model" (square…

Mesoscale and Nanoscale Physics · Physics 2018-01-09 R. L. Pavelich , F. Marsiglio

We use a simple system, the electron configuration in a Hydrogen-like atom, to demonstrate the importance of using a complete basis set to provide a proper quantum mechanical description. We first start with what might be considered a…

Atomic Physics · Physics 2015-11-17 Lindsay Forestell , Frank Marsiglio

The moir\'e superlattice system provides an excellent platform for exploring various novel quantum phenomena. To theoretically tackle the diverse correlated and topological states emerging from moir\'e superlattices, one usually adopts an…

Mesoscale and Nanoscale Physics · Physics 2025-09-16 Bo Xie , Jianqi Huang , Jianpeng Liu

Understanding the structure of our universe and the distribution of matter is an area of active research. As cosmological surveys grow in complexity, the development of emulators to efficiently and effectively predict matter power spectra…

Applications · Statistics 2025-07-28 Stephen A. Walsh , Annie S. Booth , David Higdon , Jared Clark , Kelly R. Moran , Katrin Heitmann

This article presents a general approach akin to domain-decomposition methods to solve a single linear PDE, but where each subdomain of a partitioned domain is associated to a distinct variational formulation coming from a mutually…

Numerical Analysis · Mathematics 2017-09-26 Federico Fuentes , Brendan Keith , Leszek Demkowicz , Patrick Le Tallec

A simple and completely general representation of the exact exchange-correlation functional of density-functional theory is derived from the universal Lieb-Oxford bound, which holds for any Coulomb-interacting system. This representation…

Materials Science · Physics 2015-05-13 Mariana M. Odashima , K. Capelle

Multicomponent methods are a conceptually simple way to include nuclear quantum effects into quantum chemistry calculations. In multicomponent methods, the electronic molecular orbitals are described using the linear combination of atomic…

Chemical Physics · Physics 2022-12-02 Irina Samsonova , Gabrielle B. Tucker , Naresh Alaal , Kurt R. Brorsen

Electromagnetic (EM) composites have stimulated tremendous fundamental and practical interests owing to their flexible electromagnetic properties and extensive potential engineering applications. Hence, it is necessary to systematically…

Optics · Physics 2022-09-21 Faxiang Qin , Mengyue Peng , Diana Estevez , Christian Brosseau

We present a concise, but systematic, review of the ergodicity issue in strongly correlated systems. After giving a brief historical overview, we analyze the issue within the Green's function formalism by means of the equations of motion…

Strongly Correlated Electrons · Physics 2007-07-27 Adolfo Avella , Ferdinando Mancini , Evgeny Plekhanov

Nonuniform background electromagnetic fields, once implemented in lattice quantum chromodynamics calculations of hadronic systems, provide a means to constrain a large class of electromagnetic properties of hadrons and nuclei, from their…

High Energy Physics - Lattice · Physics 2015-10-27 Zohreh Davoudi , William Detmold

We propose theoretical approach based on combination of graph theory and generalized Ising model (GIM), which enables systematic determination of extremal structures for crystalline solids without any information about interactions or…

Disordered Systems and Neural Networks · Physics 2017-01-13 Koretaka Yuge

The direct transition-matrix approach to the description of the electric polarization of the quantum bound system of particles is used to determine the electric multipole polarizabilities of the hydrogen-like atoms. It is shown that in the…

Atomic Physics · Physics 2014-10-30 V. F. Kharchenko

In these lecture notes I give an elementary introduction to elliptic hypergeometric functions. I focus on motivating the main ideas and constructions, rather than giving a comprehensive survey. The lectures include a brief explanation of…

Classical Analysis and ODEs · Mathematics 2017-06-21 Hjalmar Rosengren

Strongly correlated electron systems require the development of new theoretical schemes in order to describe their unusual and unexpected properties. The usual perturbation schemes are inadequate and new concepts must be introduced. In our…

Strongly Correlated Electrons · Physics 2016-08-31 F. Mancini , A. Avella