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We derive a Debye-H\"uckel-like model of the electric ion-ion interaction for non-constant dielectric susceptibility, which does not depend on any kind of charging process due to its foundation in the general framework of non-equilibrium…

Chemical Physics · Physics 2025-02-24 Wolfgang Dreyer , Rüdiger Müller

Ion transport measurements are widely used as an indirect probe for various properties of confined electrolytes. It is generally assumed that the ion concentration in a nanoscale channel is equal to the ion concentration in the macroscopic…

Soft Condensed Matter · Physics 2023-04-05 Paul Robin , Adrien Delahais , Lydéric Bocquet , Nikita Kavokine

We describe a simulation method for the accurate study of the equilibrium freezing properties of polydisperse fluids under the experimentally relevant condition of fixed polydispersity. The approach is based on the phase switch Monte Carlo…

Soft Condensed Matter · Physics 2009-11-13 Nigel B. Wilding

We present an implementation in a linear-scaling density-functional theory code of an electronic enthalpy method, which has been found to be natural and efficient for the ab initio calculation of finite systems under hydrostatic pressure.…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Niccolò R. C. Corsini , Andrea Greco , Nicholas D. M. Hine , Carla Molteni , Peter D. Haynes

Grand canonical Monte Carlo simulation results are reported for an electric double layer modelled by a planar charged hard wall, anisotropic shape cations, and spherical anions at different electrolyte concentrations and asymmetric…

Soft Condensed Matter · Physics 2016-03-09 M. Kaja , S. Lamperski , W. Silvestre-Alcantara , L. B. Bhuiyan , D. Henderson

Ionic microgel particles are intriguing systems in which the properties of thermo-responsive polymeric colloids are enriched by the presence of charged groups. In order to rationalize their properties and predict the behaviour of microgel…

Soft Condensed Matter · Physics 2021-01-28 G. Del Monte , F. Camerin , A. Ninarello , N. Gnan , L. Rovigatti , E. Zaccarelli

The dynamical structure factor of a Coulomb crystal of ions is calculated at arbitrary temperature below the melting point taking into account multi-phonon processes in the harmonic approximation. In a strongly coupled Coulomb ion liquid,…

Plasma Physics · Physics 2007-05-23 D. A. Baiko , A. D. Kaminker , A. Y. Potekhin , D. G. Yakovlev

We study the effective interaction mediated by strongly coupled Coulomb fluids between dielectric surfaces carrying quenched, random monopolar charges with equal mean and variance, both when the Coulomb fluid consists only of mobile…

Soft Condensed Matter · Physics 2020-10-01 Malihe Ghodrat , Ali Naji , Haniyeh Komaie-Moghaddam , Rudolf Podgornik

Bounded potentials are good models to represent the effective two-body interaction in some colloidal systems, such as dilute solutions of polymer chains in good solvents. The simplest bounded potential is that of penetrable spheres, which…

Statistical Mechanics · Physics 2007-05-23 Alexandr Malijevsky , Andres Santos

We determine exactly the short-distance leading behavior of the density correlation functions of a two-dimensional two-component charge-symmetric Coulomb gas composed of point particles, in the whole regime of stability where the coulombic…

Statistical Mechanics · Physics 2007-05-23 Gabriel Tellez

A quasi-two-dimensional (Q2D) electron liquid (EL) is formed at the interface of a semiconductor heterojunction. For an accurate characterization of the Q2D EL, many-body effects need to be taken into account beyond the random phase…

Condensed Matter · Physics 2009-10-28 C. Bulutay , M. Tomak

We study the thermodynamic and dynamic phase transitions in two-dimensional polydisperse hard disks using Monte Carlo methods. A conventional local Monte Carlo algorithm allows us to observe a dynamic liquid-glass transition at a density,…

Statistical Mechanics · Physics 2007-05-23 Ludger Santen , Werner Krauth

A classical coulombic correlation functional in one-loop (1L) and local-density-approximation (LDA) is derived for electrolyte solutions, starting from a first-principles many-body partition function. The 1L-LDA functional captures…

Chemical Physics · Physics 2026-02-17 Nils Bruch , Tobias Binninger , Jun Huang , Michael Eikerling

A recently proposed local second contact value theorem [Henderson D., Boda D., J. Electroanal. Chem., 2005, 582, 16] for the charge profile of an electric double layer is used in conjunction with the existing Monte Carlo data from the…

Soft Condensed Matter · Physics 2012-07-16 L. B. Bhuiyan , D. Henderson , S. Sokołowski

A theory of a confined two dimensional electrolyte is presented. The positive and negative ions, interacting by a $1/r$ potential, are constrained to move on an interface separating two solvents with dielectric constants $\epsilon_1$ and…

Statistical Mechanics · Physics 2009-11-07 J. E. Flores-Mena , Marcia C. Barbosa , Yan Levin

We present a quantized hydrodynamic theory and its applications of one-dimensional hard-core bosons in a harmonic trap. Quantizing the Hamiltonian of a trapped hard-core bosons and diagonalize it in terms of the phase and density…

Soft Condensed Matter · Physics 2007-05-23 Tarun Kanti Ghosh

In this short review, we discuss recent advances in exact solutions of models based on a one- dimensional (1D) Coulomb gas by means of field-theoretic functional integral methods. The exact solutions can be used to assess the accuracy of…

Statistical Mechanics · Physics 2012-09-18 Ronald R. Horgan , David S. Dean , Vincent Démery , Thomas C. Hammant , Ali Naji , Rudolf Podgornik

We explore quantitative descriptors that herald when a many-particle system in $d$-dimensional Euclidean space $\mathbb{R}^d$ approaches a hyperuniform state as a function of the relevant control parameter. We establish quantitative…

Soft Condensed Matter · Physics 2021-05-26 Salvatore Torquato

A variational approach is used to calculate free energy and conformational properties in polyelectrolytes. The true bond and Coulomb potentials are approximated by a trial isotropic harmonic energy containing monomer-monomer force constants…

High Energy Physics - Lattice · Physics 2009-09-25 B. Jönsson , C. Peterson , B. Söderberg

Two-dimensional mixtures of dipolar colloidal particles with different dipole moments exhibit extremely rich self-assembly behaviour and are relevant to a wide range of experimental systems, including charged and super-paramagnetic colloids…

Soft Condensed Matter · Physics 2019-04-16 W. R. C. Somerville , J. L. Stokes , A. M. Adawi , T. S. Horozov , A. J. Archer , D. M. A. Buzza