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An accurate description of a columnar liquid crystal of hard disks at high packing fractions is presented using an improved free-volume theory. It is shown that the orientational entropy of the disks in the one-dimensional fluid direction…

Statistical Mechanics · Physics 2012-07-17 H. H. Wensink

Interparticle interactions in charge-stabilized colloidal suspensions, of arbitrary salt concentration, are described at the level of effective interactions in an equivalent one-component system. Integrating out from the partition function…

Soft Condensed Matter · Physics 2009-10-31 A. R. Denton

Fluids made of two-dimensional hard particles with polygonal shapes may stabilize symmetries which do not result directly from the particle shape. This is due to the formation of clusters in the fluid. Entropy alone can drive these effects,…

Soft Condensed Matter · Physics 2024-02-05 Yuri Martinez-Raton , Enrique Velasco

Motivated by recent experimental reports, we carry out a Fermi liquid many-body calculation of the interaction induced renormalization of the spin susceptibility and effective mass in realistic two dimensional (2D) electron systems as a…

Strongly Correlated Electrons · Physics 2007-05-23 Ying Zhang , S. Das Sarma

The gas of the interacted electrons is usually described within Kohn-Sham approximation by the set of Poisson and Schr\"{o}dinger equations with an effective potential for the single-particle wave functions. The solution of these equations…

Materials Science · Physics 2007-05-23 A. Ya. Shul'man , D. V. Posvyanskii

We propose a microscopic, first-principles description of the ionic conduction in crystals. This formalism allows us to gain new insights into the ideal characteristics of general ionic conducting materials and, in particular, solid…

Materials Science · Physics 2021-11-05 Aleksandr Rodin , Keian Noori , Alexandra Carvalho , Antonio Helio Castro Neto

Interplay of Coulomb interaction energy, free ion entropy, and conformational elasticity is a fascinating aspect in polyelectrolytes (PEs). We develop a theory for complexation of two oppositely charged PEs, a process known to be the…

Soft Condensed Matter · Physics 2022-09-15 Soumik Mitra , Arindam Kundagrami

The Keldysh theory of photoionization for solids is generalized to atomically thin two-dimensional semiconductors. We derive a closed-form formula and its asymptotic forms for a two-band model with a Kane dispersion. These formulas exhibit…

Optics · Physics 2024-08-06 Tsing-Hua Her , Che-Hao Chang , Kenan Darden , Tsun-Hsu Chang , Hsin-Yu Yao

We develop a theory of Coulomb drag in ultraclean double layers with strongly correlated carriers. In the regime where the equilibration length of the electron liquid is shorter than the interlayer spacing the main contribution to the…

Strongly Correlated Electrons · Physics 2015-06-18 S. S. Apostolov , A. Levchenko , A. V. Andreev

In a counter-ion only charged fluid, Coulomb coupling is quantified by a single dimensionless parameter. Yet, the theoretical treatment of moderately to strongly coupled charged fluids is a difficult task, central to the understanding of a…

Soft Condensed Matter · Physics 2016-11-03 L. Samaj , A. P. dos Santos , Y. Levin , E. Trizac

Poisson-Boltzmann (PB) theory is the classic approach to soft matter electrostatics which has been applied to numerous problems of physical chemistry and biophysics. Its essential limitations are the neglect of correlation effects and of…

Soft Condensed Matter · Physics 2016-08-03 Sahin Buyukdagli , Ralf Blossey

Transport properties of high-energy-density plasmas are influenced by the ion collision rate. Traditionally, this rate involves the Coulomb logarithm, $\ln\Lambda$. Typical values of $\ln\Lambda$ are $\approx 10~\mbox{to}~20$ in kinetic…

We present a multiscale atomistic-to-continuum method for ionic crystals with defects. Defects often play a central role in ionic and electronic solids, not only to limit reliability, but more importantly to enable the functionalities that…

Mesoscale and Nanoscale Physics · Physics 2013-10-11 Jason Marshall , Kaushik Dayal

Non-local electrostatic interactions associated with the finite solvent size and ion polarizability are investigated within the mean-field linear response theory. To this end, we introduce a field theoretic model of a polar liquid composed…

Soft Condensed Matter · Physics 2015-06-15 Sahin Buyukdagli , Tapio Ala-Nissila

The correlation functions of an ionic fluid with charge and size asymmetry are studied within the framework of the random phase approximation. The results obtained for the charge-charge correlation function demonstrate that the…

Statistical Mechanics · Physics 2016-08-31 Oksana Patsahan , Ihor Mryglod , Jean-Michel Caillol

The solvation structures and ion dynamics of CaCl$_2$ aqueous electrolytes have been investigated using ab initio molecular dynamics simulations and molecular dynamics simulations with deep learning potentials. We found multiple solvation…

Chemical Physics · Physics 2023-07-20 Zhou Yu , Lei Cheng

A mesoscopic theory for water-in-salt electrolytes combining density functional and field-theoretic methods is developed in order to explain the unexpectedly large period of the oscillatory decay of the disjoining pressure observed in…

Soft Condensed Matter · Physics 2021-09-29 Oksana Patsahan , Alina Ciach

We consider a set of identical mobile point-like charges (counter-ions) confined to a domain with curved hard walls carrying a uniform fixed surface charge density, the system as a whole being electroneutral. Three domain geometries are…

Soft Condensed Matter · Physics 2016-03-24 Ladislav Samaj , E. Trizac

We develop a strong-coupling theory of Bose-Einstein condensate-mediated superconductivity in a hybrid system, which consists of a two-dimensional electron gas with either (i) parabolic spectrum or (ii) relativistic Dirac spectrum in the…

Superconductivity · Physics 2021-08-25 Meng Sun , A. V. Parafilo , V. M. Kovalev , I. G. Savenko

In this work we have applied the recently formulated self-compressed inhomogeneous stabilized jellium model [M. Payami and T. Mahmoodi, Can. J. Phys. {\bf 89}, 967 (2011)] to describe the equilibrium electronic and geometric properties of…

Materials Science · Physics 2017-09-22 M. Payami , T. Mahmoodi