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Related papers: Optimizing Flux Method Growth of Rutile GeO2 Cryst…

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Rutile Germanium Dioxide (r-GeO$_2$) has been identified as an ultrawide bandgap (UWBG) semiconductor recently, featuring a bandgap of 4.68 eV, comparable to Ga$_2$O$_3$ but offering bipolar dopability, higher electron mobility, higher…

Applied Physics · Physics 2024-07-04 Imteaz Rahaman , Bobby Duersch , Hunter D. Ellis , Michael A. Scarpulla , Kai Fu

Rutile Germanium Dioxide (GeO2) has been recently theoretically identified as an ultrawide bandgap (UWBG) semiconductor with bandgap 4.68 eV similar to Ga2O3 but having bipolar dopability and ~2x higher electron mobility, Baliga figure of…

Materials Science · Physics 2024-05-14 Imteaz Rahaman , Hunter D. Ellis , Kathy Anderson , Michael A. Scarpulla , Kai Fu

Rutile germanium dioxide (r-GeO2) is an ultra-wide bandgap semiconductor with potential for ambipolar doping, making it a promising candidate for next-generation power electronics and optoelectronics. Growth of phase-pure r-GeO2 films by…

Materials Science · Physics 2025-07-31 Imteaz Rahaman , Botong Li , Hunter D. Ellis , Kathy Anderson , Feng Liu , Michael A. Scarpulla , Kai Fu

Germanium dioxide (r-GeO2) is an emerging new ultrawide bandgap (UWBG) semiconductor with significant potential for power electronics, thanks to its large-size substrate compatibility and ambipolar doping capability. However, phase…

Materials Science · Physics 2025-06-12 Imteaz Rahaman , Botong Li , Bobby Duersch , Hunter D. Ellis , Kai Fu

Rutile germanium dioxide (r-GeO$_2$) is a promising ultra-wide bandgap (UWBG) semiconductor, offering a high theoretical Baliga figure of merit, potential for p-type doping, and favorable thermal and electrical properties. In this work, we…

Materials Science · Physics 2025-08-05 Imteaz Rahaman , Anthony Bolda , Botong Li , Hunter D. Ellis , Kai Fu

Ultrawide bandgap (UWBG) semiconductors are promising for next-generation power electronics, largely attributed to their substantial bandgap and exceptional breakdown electric field. Rutile GeO2 (r-GeO2) emerges as a promising alternative,…

Materials Science · Physics 2024-10-18 Imteaz Rahaman , Botong Li , Hunter D. Ellis , Brian Roy Van Devener , Randy C Polson , Kai Fu

Rutile germanium dioxide (r-GeO2) has recently emerged as a promising ultrawide-bandgap (UWBG) semiconductor owing to its wide bandgap (~4.4-5.1 eV), ambipolar doping potential, and high theoretical thermal conductivity. However,…

Strain engineering vanadium dioxide thin films is one way to alter this material's characteristic first order transition from semiconductor to metal. In this study we extend the exploitable strain regime by utilizing the very large lattice…

Materials Science · Physics 2020-03-06 Simon Fischer , Jon-Olaf Krisponeit , Michael Foerster , Lucia Aballe , Jens Falta , Jan Ingo Flege

Rutile GeO2 has been predicted to be an ultra-wide bandgap semiconductor suitable for future power electronics devices while quartz-like GeO2 shows piezoelectric properties. To explore these crystalline phases for application and…

We have selectively grown thin epitaxial GaAs films on Ge substrates with the aid of a 200 nm thin SiO2 mask layer. The selectively grown structures have lateral sizes ranging from 1 um width up to large areas of 1 by 1 mm2. The growth is…

Materials Science · Physics 2007-05-23 G. Brammertz , M. Caymax , Y. Mols , S. Degroote , M. Leys , J. Van Steenbergen , G. Winderickx , G. Borghs , M. Meuris

This work aimed first at growing high quality bulk $\alpha$-GeO$_2$ crystals in their Quartz iso-structural form ($\alpha$-SiO$_2$), using a high temperature flux method. By optimizing the flux composition and the geometry and orientation…

Optics · Physics 2025-01-23 Alexandra Pena , Corinne Felix , Bertrand Menaert , Benoit Boulanger

Metal-insulator transitions and superconductivity in rutile-structured oxides hold promise for advanced electronic applications, yet their thin film synthesis is severely hindered by limited substrate options. Here, we present three single-…

Ultrawide-bandgap (UWBG) semiconductors, such as GeO$_2$, are gaining significant attention for their potential in high-performance applications, particularly in piezoelectric devices. Despite extensive research, a comprehensive…

Materials Science · Physics 2025-06-12 Botong Li , Imteaz Rahaman , Hunter Ellis , Bobby G. Duersch , Kathy Anderson , Kai Fu

GeO$_2$ has an $\alpha$-quartz-type crystal structure with a very wide fundamental band gap of 6.6 eV and is a good insulator. Here we find that the stable rutile-GeO$_2$ polymorph with a 4.6 eV band gap has a surprisingly low $\sim$6.8 eV…

Materials Science · Physics 2020-11-19 Christian A. Niedermeier , Keisuke Ide , Takayoshi Katase , Hideo Hosono , Toshio Kamiya

We explore the U-Ge phase diagram using thin film growth by co-deposition of U and Ge via d.c. magnetron sputtering. Using three different single crystal substrates - MgO, CaF$_2$ and SrTiO$_3$ - we have stabilised mixed phase films of…

Broadening the variety of two-dimensional (2D) materials and improving the synthesis of ultrathin films are crucial to the development of the semiconductor industry. As a state-of-the-art 2D material, Ga2Se2 has attractive optoelectronic…

Materials Science · Physics 2023-10-18 Mingyu Yu , Lottie Murray , Matthew Doty , Stephanie Law

We report the details of the growth of ultra-clean single crystals for RuO2, a candidate material for altermagnetism. By using a crystal-growth tube with a necking structure and precisely controlling the conditions of the sublimation…

Strongly Correlated Electrons · Physics 2026-05-05 Shubhankar Paul , Giordano Mattoni , Hisakazu Matsuki , Thomas Johnson , Chanchal Sow , Shingo Yonezawa , Yoshiteru Maeno

We report on the growth of epitaxial Sr2RuO4 films using a hybrid molecular beam epitaxy approach in which a volatile precursor containing RuO4 is used to supply ruthenium and oxygen. The use of the precursor overcomes a number of issues…

Materials Science · Physics 2017-10-05 Patrick B. Marshall , Honggyu Kim , Kaveh Ahadi , Susanne Stemmer

Two-dimensional crystals are an important class of materials for novel physics, chemistry, and engineering. Germanane (GeH), the germanium-based analogue of graphane (CH), is of particular interest due to its direct band gap and spin-orbit…

Germanium-based oxides such as rutile GeO2 are garnering attention owing to their wide band gaps and the prospects for ambipolar doping for application in high-power devices. Here, we present the use of germanium tetraisopropoxide (GTIP)…

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