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A generalized class of ultra-long-range Rydberg molecules is proposed which consist of a multichannel Rydberg atom whose outermost electron creates a chemical bond with a distant ground state atom. Such multichannel Rydberg molecules…

Atomic Physics · Physics 2015-11-11 Matthew T. Eiles , Chris H. Greene

Quantum reflection is a pure wave phenomena that predicts reflection of a particle at a changing potential for cases where complete transmission occurs classically. For a chemical bond, we find that this effect can lead to non-classical…

Quantum sensing has attracted significant attention due to its ability to measure physical quantities with extremely high accuracy. Rydberg atoms - typically alkali atoms with a highly excited valence electron that is far from the nucleus -…

Information Theory · Computer Science 2025-10-03 Javane Rostampoor , Raviraj Adve

Rydberg atoms, with their giant electronic orbitals, exhibit dipole-dipole interaction reaching the GHz range at a distance of a micron, making them a prominent contender for realizing quantum operations well within their coherence time.…

The lifetimes of the lower-lying vibrational states of ultralong-range strontium Rydberg molecules comprising one ground-state 5s2 1S0 atom and one Rydberg atom in the 5s38s 3S1 state are reported. The molecules are created in an ultracold…

Rydberg Matter (RM) theory is previously shown to give good agreement with the unidentified infrared bands (UIR, UIB) that are observed in emission from many objects in space. From stimulated emission studies in RM, a slightly simpler…

Astrophysics · Physics 2007-10-18 Leif Holmlid

We explore the energy spectrum and eigenstates of two-component atomic Fermi superfluids with tunable pairing interactions in the presence of spin-dependent ultra long-range Rydberg molecule (ULRM) potentials, within the Bogoliubov-de…

Quantum Gases · Physics 2025-05-15 Chih-Chun Chien , Seth T. Rittenhouse , S. I. Mistakidis , H. R. Sadeghpour

Recent developments in the study of ultracold Rydberg gases demand an advanced level of experimental sophistication, in which high atomic and optical densities must be combined with excellent control of external fields and sensitive Rydberg…

Resonant electric dipole-dipole interactions between cold Rydberg atoms were observed using microwave spectroscopy. Laser-cooled Rb atoms in a magneto-optical trap were optically excited to 45d Rydberg states using a pulsed laser. A…

Atomic Physics · Physics 2007-05-23 K. Afrousheh , P. Z. Bohlouli , D. Vagale , A. Mugford , M. Fedorov , J. D. D. Martin

We investigate the fine and spin structure of ultralong-range Rydberg molecules exposed to a homogeneous magnetic field. Each molecule consists of a $^{87}$Rb Rydberg atom whose outer electron interacts via spin-dependent $s$- and p-wave…

Atomic Physics · Physics 2018-05-02 Frederic Hummel , Christian Fey , Peter Schmelcher

Rydberg molecules, often exemplified by long-range "trilobite" molecules, are a subject of much recent interest at high principal quantum number $n$. States that use the same bonding mechanism can exist at much lower $n$ and less-extreme…

Atomic Physics · Physics 2017-05-01 R. A. Carollo , J. L. Carini , E. E. Eyler , P. L. Gould , W. C. Stwalley

We observe a magnetic Feshbach resonance in a collision between the ground and metastable states of two-electron atoms of ytterbium (Yb). We measure the on-site interaction of doubly-occupied sites of an atomic Mott insulator state in a…

Quantum Gases · Physics 2013-05-01 Shinya Kato , Seiji Sugawa , Kosuke Shibata , Ryuta Yamamoto , Yoshiro Takahashi

The formation of ultralong-range Rydberg molecules is a result of the attractive interaction between Rydberg electron and polarizable ground state atom in an ultracold gas. In the nondegenerate case the backaction of the polarizable atom on…

Atomic Physics · Physics 2015-07-10 A. Gaj , A. T. Krupp , P. Ilzhöfer , R. Löw , S. Hofferberth , T. Pfau

Quantum entanglement is crucial for simulating and understanding exotic physics of strongly correlated many-body systems, such as high--temperature superconductors, or fractional quantum Hall states. The entanglement of non-identical…

Quantum Physics · Physics 2017-10-25 Y. Zeng , P. Xu , X. D. He , Y. Y. Liu , M. Liu , J. Wang , D. J. Papoular , G. V. Shlyapnikov , M. S. Zhan

In order to study ultracold charge-transfer processes in hybrid atom-ion traps, we have mapped out the potential energy curves and molecular parameters for several low lying states of the Rb, Yb$^+$ system. We employ both a multi-reference…

Atomic Physics · Physics 2013-05-30 H. D. L. Lamb , J. F. McCann , B. M. McLaughlin , J. Goold , N. Wells , I. Lane

Recognition of multifrequency microwave (MW) electric fields is challenging because of the complex interference of multifrequency fields in practical applications. Rydberg atom-based measurements for multifrequency MW electric fields is…

Quantum Physics · Physics 2022-04-18 Zong-Kai Liu , Li-Hua Zhang , Bang Liu , Zheng-Yuan Zhang , Guang-Can Guo , Dong-Sheng Ding , Bao-Sen Shi

We present experimental evidence for spin-orbit interaction of an electron as it scatters from a neutral atom. The scattering process takes place within a Rb$_2$ ultralong-range Rydberg molecule, consisting of a Rydberg atomic core, a…

We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…

Atomic Physics · Physics 2026-03-17 Felix Giering , Rohan Srikumar , Peter Schmelcher

We study the impact of Rydberg molecule formation on the storage and retrieval of Rydberg polaritons in an ultracold atomic medium. We observe coherent revivals appearing in the retrieval efficiency of stored photons that originate from…

Atom-based radio frequency electromagnetic field sensing using atomic Rydberg states is a promising technique that has recently attracted significant interest. Its unique advantages, such as extraordinary bandwidth, self-calibration and…

Atomic Physics · Physics 2022-09-07 Katelyn Dixon , Kent Nickerson , Donald W. Booth , James P. Shaffer