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Related papers: Investigating solid-state CH3OH formation with che…

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Explaining the formation pathways of amides on ice-grain mantels is crucial to understanding the prebiotic chemistry in an interstellar medium. In this computational study, we explore different radical-neutral formation pathways for some of…

Astrophysics of Galaxies · Physics 2024-07-10 Gabriela Silva-Vera , Giulia M. Bovolenta , Namrata Rani , Sebastian Vera , Stefan Vogt-Geisse

Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…

Earth and Planetary Astrophysics · Physics 2016-03-31 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Nadia Balucani

We present the observational result of a glycine precursor, methylamine (CH$_3$NH$_2$), together with methanol (CH$_3$OH) and methanimine (CH$_2$NH) towards high-mass star-forming regions, NGC6334I, G10.47+0.03, G31.41+0.3, and W51~e1/e2…

Solar and Stellar Astrophysics · Physics 2019-09-04 Taiki Suzuki , Liton Majumdar , Kazuki Tokuda , Harumi Minamoto , Masatoshi Ohishi , Masao Saito , Tomoya Hirota , Hideko Nomura , Yoko Oya

The study of cyclic hydrocarbons is of utmost relevance in current astrochemical research, as they are considered to be among the most significant reservoirs of carbon in the interstellar medium. However, while unsaturated cyclic…

Astrophysics of Galaxies · Physics 2025-05-07 Mario Largo , Miguel Sanz-Novo , Pilar Redondo

We used several data sets from the Plateau de Bure Interferometer to map the dimethyl ether emission in Orion-KL with different arcsec spatial resolutions and different energy levels to compare with our previous methyl formate maps. Our…

Astrophysics of Galaxies · Physics 2015-06-12 N. Brouillet , D. Despois , A. Baudry , T. -C. Peng , C. Favre , A. Wootten , A. J. Remijan , T. L. Wilson , F. Combes , G. Wlodarczak

We present the results of James Webb Space Telescope observations of the protostar ST6 in the Large Magellanic Cloud (LMC) with the Medium Resolution Spectrograph of the Mid-Infrared Instrument (4.9-27.9 $\mu$m). Characterized by one-third…

Quantifying the composition of the material in protoplanetary disks is paramount to determining the potential for exoplanetary systems to produce and support habitable environments. A key complex organic molecule (COM) to detect is methanol…

Formic acid (HCOOH) and carbon dioxide (CO2) are simple species that have been detected in the interstellar medium. The solid-state formation pathways of these species under experimental conditions relevant to prestellar cores are primarily…

Solar and Stellar Astrophysics · Physics 2019-06-26 D. Qasim , T. Lamberts , J. He , K. -J. Chuang , G. Fedoseev , S. Ioppolo , A. C. A. Boogert , H. Linnartz

The Central Molecular Zone (CMZ) contains a substantial reservoir of dense molecular gas, where numerous young stellar objects (YSOs) and dense cloud cores have been identified. However, the large distance and severe foreground extinction…

Astrophysics of Galaxies · Physics 2026-03-04 Yewon Kang , Deokkeun An , Jiwon Han , Sang-Il Han , Dayoung Pyo , A. C. Adwin Boogert , Kee-Tae Kim , Do-Young Byun

We present the first astrophysical detection of methanol (CH3OH) in the torsional band near 25 um. Using high resolution mid-infrared (MIR) spectroscopy, we identified over seventy gas-phase CH3OH absorption lines between 20 and 28 um…

Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the freeze-out of molecules onto grains. The processing is caused by…

Astrophysics of Galaxies · Physics 2013-06-14 Juris Kalvāns , Ivar Shmeld

A previous analysis of methanol and formaldehyde towards the Orion Bar concluded that the two molecular species may trace different physical components, methanol the clumpy material, and formaldehyde the interclump medium. To verify this…

Astrophysics of Galaxies · Physics 2015-05-14 S. Leurini , B. Parise , P. Schilke , J. Pety , R. Rolffs

Cyclopentadiene (c-C5H6) is considered a key molecule in the formation of polycyclic aromatic hydrocarbons (PAHs) in the interstellar medium (ISM). The synthesis of PAHs from simpler precursors is known as the "bottom-up" theory, which, so…

Astrophysics of Galaxies · Physics 2026-01-14 María Mallo , Marcelino Agúndez , Carlos Cabezas , Octavio Roncero , José Cernicharo , Germán Molpeceres

AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…

Astrophysics · Physics 2009-11-13 Q. Chang , H. M. Cuppen , E. Herbst

Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…

Astrophysics of Galaxies · Physics 2023-12-20 W. Riedel , O. Sipilä , E. Redaelli , P. Caselli , A. I. Vasyunin , F. Dulieu , N. Watanabe

Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…

NH3 and CH3OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH3CN and HCOOCH3. Despite a number of recent studies, little is known about their abundances in the…

Context: Dimethyl sulfide (DMS; CH$_3$SCH$_3$) is an organosulfur compound that has been suggested as a potential biosignature in exoplanetary atmospheres. In addition to its tentative detections toward the sub-Neptune planet K2-18b, DMS…

Astrophysics of Galaxies · Physics 2026-01-14 Gabriella Di Genova , Nadia Balucani , Luca Mancini , Marzio Rosi , Dimitrios Skouteris , Cecilia Ceccarelli

Reactions involving atomic carbon in its ground electronic state, C(3P), play an important role in astrochemistry due to high C-atom abundance levels. Here we performed a kinetic investigation of the reaction between C(3P) and acetaldehyde,…

Astrophysics of Galaxies · Physics 2025-06-06 Kevin M. Hickson , Jean-Christophe Loison , Valentine Wakelam
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