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The metal-insulator transition of VO$_2$, which in equilibrium is associated with a structural phase transition, has been intensively studied for decades. In particular, it is challenging to disentangle the role of Mott physics from…

Strongly Correlated Electrons · Physics 2025-05-16 Jiyu Chen , Francesco Petocchi , Viktor Christiansson , Philipp Werner

The electrodynamics near the metal-to-insulator transitions (MIT) induced, in V3O5 single crystals, by both temperature (T) and pressure (P) has been studied by infrared spectroscopy. The T- and P-dependence of the optical conductivity may…

Strongly Correlated Electrons · Physics 2009-11-13 L. Baldassarre , A. Perucchi , E. Arcangeletti , D. Nicoletti , D. Di Castro , P. Postorino , V. A. Sidorov , S. Lupi

The metal insulator transition of nano-scaled $VO_2$ devices is drastically different from the smooth transport curves generally reported. The temperature driven transition occurs through a series of resistance jumps ranging over 2 decades…

Mesoscale and Nanoscale Physics · Physics 2008-10-31 Amos Sharoni , Juan Gabriel Ramírez , Ivan K. Schuller

Methane (CH_4) gas sensing properties of novel vanadium dioxide (VO_2) nanostructured films is reported for the first time. The single phase nanostructures are synthesized by pulsed dc-magnetron sputtering of V target followed by oxidation…

Materials Science · Physics 2015-09-02 A. K. Prasad , S. Amirthapandian , S. Dhara , S. Dash , N. Murali , A. K. Tyagi

Vanadium sesquioxide (V2O3) is an archetypal Mott insulator in which the atomic positions and electron correlations change as temperature, pressure or doping are varied giving rise to different structural, magnetic or electronic phase…

Strongly Correlated Electrons · Physics 2024-06-12 P. Homm , M. Menghini , J. W. Seo , S. Peters , J. -P. Locquet

We present a combined density-functional theory and single-site dynamical mean-field theory (DMFT) study of vanadium dioxide (VO$_2$) using an unconventional set of bond-centered orbitals as the basis of the correlated subspace. VO$_2$ is a…

Strongly Correlated Electrons · Physics 2025-04-15 Peter Mlkvik , Maximilian E. Merkel , Nicola A. Spaldin , Claude Ederer

The insulator-to-metal transition in Mott insulators is the key mechanism for a novel class of electronic devices, belonging to the Mottronics family. Intense research efforts are currently devoted to the development of specific control…

To compare the metal-insulator transitions (MITs) of VO2 and V2O3 we analyze the relations between the structural and electronic properties of the vanadium Magneli phases. These materials set up the homologous series VnO(2n-1) (3 <= n <= 9)…

Strongly Correlated Electrons · Physics 2009-11-10 Udo Schwingenschloegl , Volker Eyert

Unveiling the physics that governs the intertwining between the nanoscale self-organization and the dynamics of insulator-to-metal transitions (\textit{IMT}) is key for controlling on demand the ultrafast switching in strongly correlated…

Researchers pursuing advanced photoelectric devices have discovered near room-temperature metal-insulator transitions (MIT) in non-volatile VO2. Despite theoretical investigations suggesting that polaron dynamics mediate the MIT, direct…

We have made a detailed temperature-dependent photoemission study of VO_2/TiO_2(001) thin films, which show a metal-insulator transition at \sim 300 K. Clean surfaces were obtained by annealing the films in an oxygen atmosphere. Spectral…

Strongly Correlated Electrons · Physics 2009-11-10 K. Okazaki , H. Wadati , A. Fujimori , M. Onoda , Y. Muraoka , Z. Hiroi

We analyze the effects on the structural and electronic properties of vanadium dioxide (VO$_2$) of adding an empirical inter-atomic potential within the density-functional theory$+V$ (DFT$+V$) framework. We use the DFT$+V$ machinery founded…

Materials Science · Physics 2025-04-15 Lea Haas , Peter Mlkvik , Nicola A. Spaldin , Claude Ederer

Neuromorphic functionalities in memristive devices are commonly associated with the ability to electrically create local conductive pathways by resistive switching. The archetypal correlated material, VO2, has been intensively studied for…

Controlling the insulator-metal transition (IMT) in correlated oxide system through oxygen vacancy ordering opens up a new paradigm for exploring exotic structural transformation and physical functionality. Oxygen vacancy serves as a…

Materials Science · Physics 2025-12-19 Xuanchi Zhou , Xiaohui Yao , Xiaomei Qiao , Jiahui Ji , Guowei Zhou , Huihui Ji , Xiaohong Xu

From thermodynamic analysis we demonstrate that during metal-insulator transitions in pure matters, a nonequilibrium homogeneous state may be unstable against charge density modulations with certain wavelengths, and thus evolves to the…

Strongly Correlated Electrons · Physics 2020-11-06 Yin Shi , Long-Qing Chen

Spatial phase inhomogeneity at the nano- to microscale is widely observed in strongly-correlated electron materials. The underlying mechanism and possibility of artificially controlling the phase inhomogeneity are still open questions of…

Strongly Correlated Electrons · Physics 2015-05-13 J. Cao , E. Ertekin , V. Srinivasan , W. Fan , S. Huang , H. Zheng , J. W. L. Yim , D. R. Khanal , D. F. Ogletree , J. C. Grossman , J. Wu

We study the photo-induced metallization process in niobium dioxide NbO$_2$. This compound undergoes the thermal insulator-to-metal transition at the remarkably high temperature of 1080 K. Our optical pump - terahertz probe measurements…

Strongly Correlated Electrons · Physics 2019-01-09 Rakesh Rana , J. Michael Klopf , Jörg Grenzer , Harald Schneider , Manfred Helm , Alexej Pashkin

Experimental insight in the nanoscale dynamics underlying switching in novel memristive devices is limited owing to the scarcity of techniques that can probe the electronic structure of these devices. Scattering scanning near-field optical…

Strongly Correlated Electrons · Physics 2023-03-14 Sergio Salvía Fernández , Xing Gao , Silvia Cassanelli , Stephan Bron , Hans Hilgenkamp , Erik van Heumen

Achieving ultrafast all-optical switching in a silicon waveguide geometry is a key milestone on the way to an integrated platform capable of handling the increasing demands for higher speed and higher capacity for information transfer.…

Phase transitions driven by ultrashort laser pulses have attracted interest both for understanding the fundamental physics of phase transitions and for potential new data storage or device applications. In many cases these transitions…