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The electronic structure of the vanadium dioxide VO_2 in the tetragonal R and two monocinic M_1 and M_2 structural modifications was calculated in frames of the local-density functional (LDA) approach and the LSDA + U formalism of…

Strongly Correlated Electrons · Physics 2007-05-23 M. A. Korotin , N. A. Skorikov , V. I. Anisimov

Strongly confined NaVO$^+$ segregation and its thermo-responsive functionality at the interface between simple sputter-deposited amorphous vanadium oxide thin films and soda-lime glass was substantiated in the present study by in-situ…

With remarkable electrical and optical switching properties induced at low power and near room temperature (68C), vanadium dioxide (VO2) has sparked rising interest in unconventional computing among the phase-change materials research…

We present a density-functional theory (DFT) study of the structural, electronic, and chemical bonding behaviour in germanium (Ge)-doped vanadium dioxide (VO$_2$). Our motivation is to explain the reported increase of the metal-insulator…

Materials Science · Physics 2023-02-03 Peter Mlkvik , Claude Ederer , Nicola A. Spaldin

The temperature dependence of the local structure of V_2O_3 in the vicinity of the metal to insulator transition (MIT) has been investigated using hard X-ray absorption spectroscopy. It is shown that the vanadium pair distance along the…

Strongly Correlated Electrons · Physics 2009-11-11 P. Pfalzer , G. Obermeier , M. Klemm , S. Horn , M. L. denBoer

Vanadium is a transition metal with multiple oxidation states and V2O5 is the most stable form among them. Besides catalysis, chemical sensing and photo-chromatic applications, V2O5 is also reported to exhibit a semiconductor to metal…

Materials Science · Physics 2018-01-03 Raktima Basu , Sandip Dhara

The optical properties of a V4O7 single crystal have been investigated from the high temperature metallic phase down to the low temperature antiferromagnetic insulating one. The temperature dependent behavior of the optical conductivity…

Strongly Correlated Electrons · Physics 2015-06-22 I. Lo Vecchio , M. Autore , F. D'Apuzzo , F. Giorgianni , A. Perucchi , U. Schade , V. N. Andreev , V. A. Klimov , S. Lupi

Hydrogen intercalation in solids is common, complicated, and very difficult to monitor. In a new approach to the problem, we have studied the profile of hydrogen diffusion in single-crystal nanobeams and plates of VO2, exploiting the fact…

Strongly Correlated Electrons · Physics 2016-08-24 T. Serkan Kasırga , Jim M. Coy , Jae H. Park , David H. Cobden

We investigated optical absorption coefficient spectra of an epitaxial VO2 film in wide photon energy (0.5 - 5.0 eV) and temperature (100 - 380 K) regions. In its insulating phase, we observed two d-d transition peaks around 1.3 eV and 2.7…

Strongly Correlated Electrons · Physics 2007-05-23 C. H. Koo , J. S. Lee , M. W. Kim , Y. J. Chang , T. W. Noh , J. H. Jung B. G. Chae , H. -T. Kim

Although vanadium dioxide (VO2) exhibits the most abrupt metal to insulator transition (MIT) properties near room-temperature, the present regulation of their MIT functionalities is insufficient owing to the high complexity and susception…

Materials Science · Physics 2023-01-03 Xuanchi Zhou , Yuchen Cui , Yanlong Shang , Haifan Li , Jiaou Wang , Ye Meng , Xiaoguang Xu , Yong Jiang , Nuofu Chen , Jikun Chen

Using an \textit{ab initio} approach based on the GW approximation which includes strong local \textbf{k}-space correlations, the Metal-Insulator Transition of M$_2$ vanadium dioxide is broken down into its component parts and investigated.…

Strongly Correlated Electrons · Physics 2017-09-15 Jamie M. Booth , Daniel W. Drumm , Phil S. Casey , Suresh K. Bhargava , Jackson S. Smith , Salvy P. Russo

Photoinduced phase transition (PIPT) is always treated as a coherent process, but ultrafast disordering in PIPT is observed in recent experiments. Utilizing the real-time time-dependent density functional theory (rt-TDDFT) method, here, we…

Materials Science · Physics 2022-07-08 Hao-Wen Liu , Wen-Hao Liu , Zhao-Jun Suo , Zhi Wang , Jun-Wei Luo , Shu-Shen Li , Lin-Wang Wang

We study the interplay of the structural phase transition, flat electronic band dispersion, and metal-to-insulator transition (MIT) in the parent compounds of the Ru-pnictide superconductors by using first-principles calculations. Our…

Materials Science · Physics 2024-01-30 Niraj Aryal , Emil S. Bozin , Weiguo Yin

Recently, metalenses which consist of metasurface arrays, have attracted attention due to their more condensed size in comparison with conventional lenses. In this paper, we propose a reconfigurable coding metasurface hybridized with…

Optics · Physics 2019-10-09 Roya Kargar , Kasra Rouhi , Ali Abdolali

Metallization of initially insulating VO2 via ionic liquid electrolytes (electrolyte gating) has recently been a topic of much interest. It is clear that the metallization takes place electrochemically and there has previously been…

Strongly Correlated Electrons · Physics 2018-12-06 Michael A. Hope , Kent J. Griffith , Bin Cui , Fang Gao , Siân E. Dutton , Stuart S. P. Parkin , Clare P. Grey

Recent development of ultrashort laser pulses allows for optical control of structural and electronic properties of complex quantum materials. The layered transition metal dichalcogenide MoTe2, which can crystalize into several different…

Materials Science · Physics 2019-05-29 M. Y. Zhang , Z. X. Wang , Y. N. Li , L. Y. Shi , D. Wu , T. Lin , S. J. Zhang , Y. Q. Liu , C. N. Wang , Q. M. Liu , J. Wang , T. Dong , N. L. Wang

In this work, we report the design of a wavelength-tunable infrared metamaterial by exciting magnetic resonance with phase transition of vanadium dioxide (VO2). Numerical simulation shows a broad absorption peak at the wavelength of 10.9 um…

Optics · Physics 2014-12-19 Hao Wang , Yue Yang , Liping Wang

Dynamic radiative cooling with variable emissive power is experimentally demonstrated in this study by a wavelength-selective tunable metafilm emitter, which consists of an opaque aluminum film, a sputtered silicon spacer, and a…

We report the growth of ultrathin VO$_{2}$ films on rutile TiO$_{2}$ (001) substrates via reactive molecular-beam epitaxy. The films were formed by the cyclical deposition of amorphous vanadium and its subsequent oxidation and…

We have grown VO2 thin films by laser ablation for electronic device applications. In obtaining the thin films of the pure VO2 phase, oxygen partial pressure is a critical parameter because vanadium oxides have several phases with the…

Materials Science · Physics 2007-05-23 B. G. Chae , D. H. Youn , H. T. Kim , S. Y. Maeng , K. Y. Kang
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