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We describe a model for the thermodynamics and dynamics of glass-forming liquids in terms of excitations from an ideal glass state to a Gaussian manifold of configurationally excited states. The quantitative fit of this three parameter…

Soft Condensed Matter · Physics 2015-06-25 Dmitry V. Matyushov , C. A. Angell

It has been demonstrated recently that supercooled liquids sharing simple structural features (e.g. pair distribution functions) may exhibit strikingly distinct dynamical behavior. Here we show that a more subtle structural feature…

Statistical Mechanics · Physics 2012-06-04 Glen M. Hocky , Thomas E. Markland , David R. Reichman

A universal dynamical crossover temperature, Tcr, in glassy liquids, associated with the {\alpha}-\b{eta} bifurcation temperature, TB, has been observed in dielectric spectroscopy and other experiments. Tcr lies significantly above the…

Soft Condensed Matter · Physics 2024-03-29 Shubham Kumar , Sarmistha Sarkar , Biman Bagchi

We describe the interaction stimulated relaxation in the ensemble of two-level systems, responsible for low temperature kinetics and thermodynamics properties of amorphous solids. This relaxation gets significant at sufficiently low…

Disordered Systems and Neural Networks · Physics 2009-11-10 A. L. Burin , I. Ya. Polishchuk

It is experimentally shown that, depending on the carrier-concentration of the system $n$, the dynamics of electron-glasses either \textit{slows down }with increasing temperature or it is \textit{independent} of it. This also correlates…

Strongly Correlated Electrons · Physics 2007-11-28 Z. Ovadyahu

An alternative scenario for the glass transition based on the cooperative nature of nucleation processes and the role of entropic effects is presented. The new ingredient is to relate the dissipation during the relaxation process to the…

Statistical Mechanics · Physics 2007-05-23 Andrea Crisanti , Felix Ritort

An analysis of the glass transition of four materials with similar chemical structures is performed: PET, PEN and two PET/PEN blends (90/10 and 70/30 w/w). During the melt processing of the blends transesterification reactions yield block…

Materials Science · Physics 2015-06-05 J. Sellares , J. A. Diego , J. C. Canadas , M. Mudarra , J. Belana , P. Colomer , F. Roman , Y. Calventus

We numerically study yielding in two-dimensional glasses which are generated with a very wide range of stabilities by swap Monte-Carlo simulations and then slowly deformed at zero temperature. We provide strong numerical evidence that…

Disordered Systems and Neural Networks · Physics 2020-05-26 Misaki Ozawa , Ludovic Berthier , Giulio Biroli , Gilles Tarjus

Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. The short-time $\beta$-relaxation is generally attributed to spatially local processes involving the rattling motion of a…

Statistical Mechanics · Physics 2016-03-02 Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

The recent experimental fabrication of ultra stable glass films via vapour deposition [Science 315, 353 (2007)] and the observation of front-like response to the annealing of these films [Phys.Rev.Lett. 102, 065503 (2009)], have raised…

Soft Condensed Matter · Physics 2011-01-20 Sébastien Léonard , Peter Harrowell

Broadband dielectric spectroscopy was used to study the molecular orientational dynamics of the glass-forming, thioether-linked cyanobiphenyl liquid crystal dimers. As was expected theoretically, two different relaxation processes that…

Soft Condensed Matter · Physics 2023-04-18 M. Czarnecka , Y. Arakawa , A. Kocot , K. Merkel

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

Statistical Mechanics · Physics 2015-06-23 Mikhail Vasin

A viscoelastic model is established to reveal the relation between alpha-beta relaxation of glass and the double-peak phenomenon in the experiments of impulse excited vibration. In the modelling, the normal mode analysis (NMA) of potential…

Disordered Systems and Neural Networks · Physics 2020-02-19 Jianbiao Wang , Xu Wang , Haihui Ruan

Using density-functional molecular dynamics simulations we analyzed the cooling-rate effects on the physical properties of GeS$_2$ chalcogenide glasses. Liquid samples were cooled linearly in time according to $T(t) = T_0 - \gamma t$ where…

Disordered Systems and Neural Networks · Physics 2007-05-23 Sebastien Le Roux , Philippe Jund

The Adam-Gibbs view of the glass transition relates the relaxation time to the configurational entropy, which goes continuously to zero at the so-called Kauzmann temperature. We examine this scenario in the context of a dimer model with an…

Statistical Mechanics · Physics 2007-05-23 Dibyendu Das , Greg Farrell , Jane' Kondev , Bulbul Chakraborty

The molecular mobility of glassy and supercooled liquid states of clotrimazole is studied using broadband dielectric spectroscopy for a wide range of temperatures and frequency. The dielectric loss data of clotrimazole below T$_{g}$, do not…

Soft Condensed Matter · Physics 2016-09-12 N S K Kumar , G Govindaraj , U Sailaja

Diverse material classes exhibit practically identical behavior when made viscous upon cooling toward the glass transition, suggesting a common theoretical basis. The first-principles scaling laws that have been proposed to describe the…

New metallic glasses containing La or Ce have been introduced that have dynamic properties bordering on extremes of conventional metallic glasses. This provides opportunity to test trends or correlations established before in molecular and…

Materials Science · Physics 2015-06-15 K. L. Ngai , Z. Wang , X. Q. Gao , H. B. Yu , W. H. Wang

Recent high precision experimental results on spin-glass films ask for a detailed understanding of the domain-growth dynamics of two-dimensional spin glasses. To achieve this goal, we numerically simulate the out-equilibrium dynamics of the…

Disordered Systems and Neural Networks · Physics 2019-05-07 L. A. Fernandez , E. Marinari , V. Martin-Mayor , G. Parisi , J. J. Ruiz-Lorenzo

We present a modified version of our "sliding model", where chain arcs, between two contacts at the surface, may move if all the barriers along the arc are weaker than a certain threshold.An important advance of the revised model is that…

Soft Condensed Matter · Physics 2007-05-23 Pierre-Gilles de Gennes