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The earlier paper of this same title demonstrated a collapse of relaxation data of fragile supercooled glass forming liquids [\textit{J. Phys. Chem. B} \textbf{113}, 5563-5567 (2009)]. For temperature $T$ below that of the onset to…

Statistical Mechanics · Physics 2014-07-31 Yael S. Elmatad , David Chandler , Juan P. Garrahan

We provide a theoretical description of dynamical heterogeneities in glass-forming liquids, based on the premise that relaxation occurs via local rearrangements coupled by elasticity. In our framework, the growth of the dynamical…

Soft Condensed Matter · Physics 2023-11-02 Ali Tahaei , Giulio Biroli , Misaki Ozawa , Marko Popović , Matthieu Wyart

Glass formers are in general classified as strong or fragile depending on whether their relaxation rates follow Arrhenius or super-Arrhenius temperature dependence. There are however notable exceptions such as water, which exhibit a…

Soft Condensed Matter · Physics 2023-01-06 Chin-Yuan Ong , Chun-Shing Lee , Xin-Yuan Gao , Qiang Zhai , Rui Shi , Hai-Yao Deng , Chi-Hang Lam

A central question concerning glass-formation has been what governs the kinetic arrest of the quenched liquid - cooling reduces the thermal energy which molecules need to surmount local potential barriers, while the accompanying volume…

Soft Condensed Matter · Physics 2007-05-23 CM Roland R Casalini

Whereas the first part of this paper dealt with the relaxation in the beta-regime, this part investigates the final (alpha) relaxation of a simulated polymer melt consisting of short non-entangled chains above the critical temperature Tc of…

Soft Condensed Matter · Physics 2007-05-23 M. Aichele , J. Baschnagel

This paper discusses the possible relation between entropy and the relaxation time of liquids, in particular glass-forming systems, providing supplementing comments to the paper entitled "A brief critique of the Adam-Gibbs entropy model" by…

Soft Condensed Matter · Physics 2014-03-12 Jeppe C. Dyre

In order to describe the slow response of a glass former we discuss some distribution of correlation times, e.g., the generalized gamma distribution (GG) and an extension thereof (GGE), the latter allowing to reproduce a simple peak…

Soft Condensed Matter · Physics 2009-11-07 T. Blochowicz , C. Tschirwitz , S. Benkhof , E. A. Rossler

We propose a dynamic structure of coupled dynamic molecular strings for supercooled small polar molecule liquids and accordingly we obtain the Hamiltonian of the rotational degrees of freedom of the system. From the Hamiltonian, the…

Disordered Systems and Neural Networks · Physics 2009-11-10 Y. N. Huang , C. J. Wang , E. Riande

The systematic identification of temperature scales in supercooled liquids that are key to understanding those liquids' underlying glass properties, and the latter's formation-history dependence, is a challenging task. Here we study the…

Soft Condensed Matter · Physics 2021-01-05 Karina González-López , Edan Lerner

We identify a link between the glass transition and percolation of mobile regions in configuration space. We find that many hallmarks of glassy dynamics, for example stretched-exponential response functions and a diverging structural…

Statistical Mechanics · Physics 2009-11-13 Gregg Lois , Jerzy Blawzdziewicz , Corey S. O'Hern

Translational dynamics of two-dimensional glass forming fluids is strongly influenced by soft, long-wavelength fluctuations first recognized by D. Mermin and H. Wagner. As a result of these fluctuations, characteristic features of glassy…

Soft Condensed Matter · Physics 2019-03-27 Elijah Flenner , Grzegorz Szamel

We propose a simple dynamical model of the glass transition based on the results from a non-randomly frustrated spin model which is known to form a glassy state below a characteristic quench temperature. The model is characterized by a…

Statistical Mechanics · Physics 2008-02-03 Michael Ignatiev , Lei Gu , Bulbul Chakraborty

Below the onset temperature $T_\text{o}$, the equilibrium relaxation time of most glass-forming liquids exhibits glassy dynamics characterized by super-Arrhenius temperature dependence. In this supercooled regime, the relaxation dynamics…

Statistical Mechanics · Physics 2023-05-03 Dimitrios Fraggedakis , Muhammad R. Hasyim , Kranthi K. Mandadapu

We theoretically investigate glass transition behaviors of the glassy graphene in a wide range of temperature, where this amorphous graphene is described as a hard-sphere fluid. The dynamic arrest of a particle is assumingly caused by…

Soft Condensed Matter · Physics 2020-03-11 Tran Dinh Cuong , Anh D. Phan , Katsunori Wakabayashi , Pham Thanh Huy

A model glass is considered with one type of fast ($\beta$-type) of processes, and one type of slow processes ($\alpha$-type). On time-scales where the fast ones are in equilibrium, the slow ones have a dynamics that resembles the one of…

Statistical Mechanics · Physics 2009-11-07 Luca Leuzzi , Theo M. Nieuwenhuizen

The diverging relaxation time in approaching hypothetical ideal glass transition is a subject of hot debate. In the current paper we demonstrate, how diverging relaxation time and turning excess entropy to zero (which is an essence of…

Soft Condensed Matter · Physics 2024-10-25 M. V. Kondrin , Y. B. Lebed , A. A. Pronin , V. V. Brazhkin

Hierarchical dynamics in glass-forming systems span multiple timescales, from fast vibrations to slow structural rearrangements, appearing in both supercooled fluids and glassy states. Understanding how these diverse processes interact…

Soft Condensed Matter · Physics 2025-05-28 Wensi Sun , Yanshuang Chen , Wencheng Ji , Yi Zhou , Hua Tong , Ke Chen , Xiaosong Chen , Hajime Tanaka , Peng Tan

Despite decades of studies on the grand problem of the glass transition the question of well-defined universal patterns, including the key problem of the previtreous behavior of the primary (structural) relaxation time, remains elusive.…

Soft Condensed Matter · Physics 2018-09-18 Aleksandra Drozd-Rzoska

The dielectric relaxation of water in glassy aqueous binary mixtures exhibits an Arrhenius behaviour with a nearly universal activation energy. We here demonstrate that its characteristic relaxation time follows a remarkably general…

We investigate a general scenario for ``glassy'' or ``jammed'' systems driven by an external, non-conservative force, analogous to a shear force in a fluid. In this scenario, the drive results in the suppression of the usual aging process,…

Soft Condensed Matter · Physics 2009-10-31 Ludovic Berthier , Jean-Louis Barrat , Jorge Kurchan