Related papers: Harnessing multi-mode optical structure for chemic…
The coupling of resonant light and surface plasmons in metal layer coated optical microcavities results in the formation of hybrid photon-plasmon modes. Here, we comprehensively investigate the hybridization mechanism of photon-plasmon…
Catalyzing reactions effectively by vacuum fluctuations of electromagnetic fields is a significant challenge within the realm of chemistry. Different from most studies based on vibrational strong coupling, we introduce an innovative…
Recent experiments have suggested that ground state chemical kinetics can be suppressed or enhanced by coupling the vibrational degrees of freedom of a molecular system with a radiation mode inside an optical cavity. Experiments show that…
Vibrational strong coupling (VSC) provides a novel means to modify chemical reactions and energy transfer pathways. To efficiently model chemical dynamics under VSC in the collective regime, herein a hybrid quantum mechanical/molecular…
Proton transfer is ubiquitous in many fundamental chemical and biological processes, and the ability to modulate and control the proton transfer rate would have a major impact on numerous quantum technological advances. One possibility to…
Recent experiments showed that the chemical reaction rate is modified, either increased or decreased, by strongly coupling a nuclear vibration mode to the single mode of an optical cavity. Herein we investigate how the rate of an…
Optical cavities are an enabling technology of modern quantum science: from their essential role in the operation of lasers, to applications as fly-wheels in atomic clocks and interaction-enhancing components in quantum optics experiments,…
Photonic molecules, named by analogy with chemical molecules, are clusters of closely located electromagnetically interacting microcavities or "photonic atoms". As two or several microcavities are brought close together, their optical modes…
We use the polarized Fock states to describe the coupled molecule-cavity hybrid system in quantum electrodynamics. The molecular permanent dipoles polarize the photon field by displacing its vector potential, leading to non-orthogonality…
The photon blockade (PB) effect in emitter-cavity systems depends on the anharmonicity of the ladder of dressed energy eigenstates. The recent developments in color center photonics are leading toward experimental demonstrations of…
This study investigates the dynamic behavior of polaritons in an optical cavity containing one million molecules, emphasizing the influence of molecular rotation and level disorder on the coupling between molecules and photons. Through…
In this article we explore the dynamics of many-body atomic systems symmetrically coupled to a single Lorentzian photonic cavity. Our study reveals interesting dynamical characteristics including non-zero steady states, superradiant decay,…
Multistability -- the emergence of multiple stable states under identical conditions -- is a hallmark of nonlinear complexity and an enabling mechanism for multilevel optical memory and photonic computing. Its realization in a compact…
Polaritonic chemistry is an interdisciplinary emerging field that presents several challenges and opportunities in chemistry, physics, and engineering. A systematic review of polaritonic response theory is presented, following a chemical…
Plasmonic nanocavities are a promising platform for strong light-matter coupling and enhanced spectroscopies at the single-molecule level. These nanoscale environments are challenging to model due to their strongly multimodal character and…
We investigate the multiphoton quantum dynamics of a leaking single-mode quantized cavity field coupled with a resonantly driven two-level system possessing permanent dipoles. The frequencies of the interacting subsystems are being…
Molecular cavity optomechanical systems, featuring ultrahigh vibrational frequencies and strong light-matter interactions, hold significant promise for advancing applications in quantum science and technology. Specifically, by introducing…
The synchronization of the motion of microresonators has attracted considerable attention. Here we present theoretical methods to synchronize the chaotic motion of two optical cavity modes in an optomechanical system, in which one of the…
Few-photon transport via waveguide-coupled local quantum systems has attracted extensive theoretical and experimental studies. Most of the study has focused on atomic or atomic-like local quantum systems due to their strong light-matter…
The increased decay rate of a two-level system weakly coupled to an optical cavity, known as the Purcell effect, is a cornerstone of cavity QED. However, the effect of cavity coupling is not well understood if the two-level system is…