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Polaritons are usually described within single-mode cavity QED models. However, nanophotonic environments typically involve several modes that spectrally overlap and interfere, giving rise to sharp dip features such as Fano profiles in the…

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

Altering chemical reactivity and material structure in confined optical environments is on the rise, and yet, a conclusive understanding of the microscopic mechanisms remains elusive. This originates mostly from the fact that accurately…

Chemical Physics · Physics 2024-03-22 Christian Schäfer , Jakub Fojt , Eric Lindgren , Paul Erhart

The central theme of cavity quantum electrodynamics is the coupling of a single optical mode with a single matter excitation, leading to a doublet of cavity polaritons which govern the optical properties of the coupled structure. Especially…

Optomechanical crystal cavities (OMCCs) are fundamental nanostructures for a wide range of phenomena and applications. Usually, optomechanical interaction in such OMCCs is limited to a single optical mode and a unique mechanical mode. In…

Hybrid light-matter states, polaritons, are one of the central concepts in modern quantum optics and condensed matter physics. Polaritons emerge as a result of strong interaction between an optical mode and a material resonance, which is…

Understanding the quantum dynamics of strongly coupled molecule-cavity systems remains a significant challenge in molecular polaritonics. This work develops a comprehensive self-consistent model simulating electromagnetic interactions of…

Chemical Physics · Physics 2025-01-29 Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan

Nanocavities formed by ultrathin metallic gaps, such as the nanoparticle-on-mirror geometry, permit the reproducible engineering and enhancement of light-matter interaction thanks to mode volumes reaching the smallest values allowed by…

Polaritonic chemistry investigates the possible modification of chemical and photochemical reactions by means of strong light-matter coupling in optical cavities, as demonstrated in numerous experiments over the last few years. These…

Quantum Physics · Physics 2025-07-30 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

Molecular strong coupling offers exciting prospects in physics, chemistry and materials science. Whilst attention has been focused on developing realistic models for the molecular systems, the important role played by the entire photonic…

Polaritonic chemistry relies on the strong light-matter interaction phenomena for altering the chemical reaction rates inside optical cavities. To explain and to understand these processes, the development of reliable theoretical models is…

Chemical Physics · Physics 2022-09-14 Fabijan Pavošević , Angel Rubio

Linear spectra of molecular polaritons formed by $N$ molecules coupled to a microcavity photon mode are usually well described by classical linear optics, raising the question of where the expected nonlinear effects in these strongly…

Quantum Physics · Physics 2024-11-19 Arghadip Koner , Joel Yuen-Zhou

Recent years have seen significant developments in the study of strong light-matter coupling including the control of chemical reactions by altering the vibrational normal modes of molecules. In the vibrational strong coupling regime the…

Quantum Physics · Physics 2021-08-27 John Bonini , Johannes Flick

We study a hybrid system formed from an optomechanical resonator and a cavity mode strongly coupled to an excitonic transition inside a quantum well. We show that due to the mixing of cavity photon and exciton states, the emergent…

Mesoscale and Nanoscale Physics · Physics 2014-03-04 O. Kyriienko , T. C. H. Liew , I. A. Shelykh

When molecular transitions strongly couple to photon modes, they form hybrid light-matter modes called polaritons. Collective vibrational strong coupling is a promising avenue for control of chemistry, but this can be deterred by the large…

Two-dimensional semiconductors host excitons with very large oscillator strengths and binding energies due to significantly reduced carrier screening. Two-dimensional semiconductors integrated with optical cavities are emerging as a…

We theoretically investigate a single fluorescent molecule as a hybrid quantum optical device, in which multiple external laser sources exert control of the vibronic states. In the high-saturation regime, a coherent interaction is…

Vibrational polaritons are formed by strong coupling of molecular vibrations and photon modes in an optical cavity. Experiments have demonstrated that vibrational strong coupling can change molecular properties and even affect chemical…

Quantum Physics · Physics 2025-01-14 Thomas Schnappinger , Cyril Falvo , Markus Kowalewski

Polaritonic chemistry has garnered increasing attention in recent years due to pioneering experimental results, which show that site- and bond-selective chemistry at room temperature is achievable through strong collective coupling to field…

Chemical Physics · Physics 2025-06-03 Dominik Sidler , Michael Ruggenthaler , Angel Rubio

In cavity optomechanics, nanomechanical motion couples to a localized optical mode. The regime of single-photon strong coupling is reached when the optical shift induced by a single phonon becomes comparable to the cavity linewidth. We…

Mesoscale and Nanoscale Physics · Physics 2013-04-22 Max Ludwig , Amir H. Safavi-Naeini , Oskar Painter , Florian Marquardt
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