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Studies of the behaviour of solids at ultra-high pressures, those beyond 200 GPa, contribute to our fundamental understanding of materials properties and allow an insight into the processes happening at such extreme conditions relevant for…

Metallic hydrogen is capable of showing room temperature superconductivity, but its experimental syntheses are extremely hard. Therefore, it is desirable to reduce the synthesis pressure of metallic hydrogen by adding other chemical…

Superconductivity · Physics 2022-11-23 Zhongyu Wan , Ruiqin Zhang

The high pressure phase diagram of CsC8 graphite intercalated compound has been investigated at ambient temperature up to 32 GPa. Combining X-ray and neutron diffraction, Raman and X- ray absorption spectroscopies, we report for the first…

Recent high-pressure studies found that superconductivity can be achieved under very low pressure in the parent iron arsenide compound CaFe2As2, although details of the sharpness and temperature of transitions vary between liquid medium and…

Superconductivity · Physics 2009-11-13 W. Yu , A. A. Aczel , T. J. Williams , S. L. Bud'ko , N. Ni , P. C. Canfield , G. M. Luke

Uranium manganese germanide, UMn2Ge2, crystallizes in body-centered tetragonal ThCr2Si2 structure with space group I4/mmm, a = 3.993A and c = 10.809A under ambient conditions. Energy dispersive X-ray diffraction was used to study the…

Materials Science · Physics 2009-11-10 Vasudeva Siruguri , S. K. Paranjpe , P. Raj , A. Sathyamoorthy , Jean Paul Itie , Alain Polian

A new route to the sintering of MgB2 has been identified, based on a reactive infiltration of liquid Mg on a powdered B preform. The technique allows to obtain large bulk manufacts in an inexpensive way, without the need of high pressure…

Superconductivity · Physics 2009-11-07 Giovanni Giunchi

Motivated by recent experimental work, we use first-principles density functional theory methods to conduct an extensive search for low enthalpy structures of C$_6$Ca under pressure. As well as a range of buckled structures, which are…

Superconductivity · Physics 2007-05-23 Gabor Csanyi , Chris J. Pickard , B. D. Simons , R. J. Needs

We introduce a novel method that combines the accuracy of Quantum Monte Carlo simulations with ab-initio Molecular Dynamics, in the spirit of Car-Parrinello. This method is then used for investigating the structure of a two-dimensional…

Computational Physics · Physics 2017-05-16 Francesco Calcavecchia , Thomas D. Kühne , Markus Holzmann

Nanoporous metals are a class of nanostructured materials finding extensive applications in multiple fields thanks to their unique properties attributed to their high surface area and interconnected nanoscale ligaments. They can be…

The crystal structure of solid oxygen at low temperatures and at pressures up to 7 GPa is studied by theoretical calculations. In the calculations, the adiabatic potential of the crystal is approximated by a superposition of pair-potentials…

Materials Science · Physics 2009-11-13 Kazuki Nozawa , Nobuyuki Shima , Kenji Makoshi

We report a novel high pressure structural sequence for the functionally graded thermoelectric, narrow band gap semiconductor AgSbTe$_{2}$, using angle dispersive x-ray diffraction in a diamond anvil cell with synchrotron radiation at room…

In this article, a brief introduction is first given on infrared studies of materials at high pressures using a diamond anvil cell. Then, our recent results of high-pressure infrared studies are described for Mg$_2$Si, InAs, and InSb. For…

Superconducting MgB2 was synthesized in a stainless steel tube which compressed by pulsed magnetic field. The temperature dependence of diamagnetic moment m(T) was investigated and the pinning potential was determined

Superconductivity · Physics 2007-05-23 S. P. Ananev , V. A. Grinenko , V. A. Keilin , E. P. Krasnoperov , P. A. Levit , V. A. Stoliarov

In this study, we conducted experiments on CaC6 for elucidating the Na-catalyzed formation mechanism and achieving rapid mass synthesis of graphite intercalation compounds (GICs). Rapidly synthesized CaC6 was characterized by analysis of…

The appropriateness of including Hg among the transition metals has been debated for a long time. Although the synthesis of HgF$_{4}$ molecules in gas phase was reported before, the molecules show strong instabilities and dissociate.…

Materials Science · Physics 2012-06-14 Xiaoli Wang , Haiqing Lin , Yanming Ma , Mao-Sheng Miao

LaNiGa2 is a time-reversal symmetry breaking superconductor with symmetry protected band crossings, making it an ideal platform for investigating the interplay between unconventional superconductivity and electronic structure topology. Here…

Among the family of TMDs, ReS2 takes a special position, which crystalizes in a unique distorted low-symmetry structure at ambient conditions. The interlayer interaction in ReS2 is rather weak, thus its bulk properties are similar to that…

The rise of nanotechnology has been propelled by low dimensional metals. Albeit the long perceived importance, synthesis of freestanding metallic nanomembranes, or the so-called 2D metals, however has been restricted to simple metals with a…

Applied Physics · Physics 2019-12-17 Tianyu Wang , Quanfeng He , Jingyang Zhang , Zhaoyi Ding , Fucheng Li , Yong Yang

Gold selenide (AuSe) is a multilayer compound yet to be thoroughly studied. The colloidal synthesis and characterization of gold selenide nanoparticles are described, emphasizing the effect of different gold-to-selenium precursor ratios and…

Materials Science · Physics 2023-04-05 Aditya Kumar Sahu , Satyabrata Raj

High-entropy intermetallic compounds (HEICs) were fabricated by mechanical alloying and spark plasma sintering to fill a knowledge gap between the traditional high-entropy alloys (HEAs) and emerging high-entropy ceramics (HECs). Notably,…

Materials Science · Physics 2019-02-28 Naixie Zhou , Sicong Jiang , Timothy Huang , Mingde Qin , Tao Hu , Jian Luo