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The absorption energy of atomic hydrogen at rotated graphene bilayers is studied using ab initio methods based on the density functional theory including van der Waals interactions. We find that, due to the surface corrugation induced by…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Ivan Brihuega , Felix Yndurain

Methane is typically thought to be formed in the solid state on the surface of cold interstellar icy grain mantles via the successive atomic hydrogenation of a carbon atom. In the current work we investigate the potential role of molecular…

Astrophysics of Galaxies · Physics 2022-04-06 Thanja Lamberts , Gleb Fedoseev , Marc van Hemert , Danna Qasim , Ko-Ju Chuang , Julia C. Santos , Harold Linnartz

Effects of graphene oxide nanomaterials addition and oxidation level on ignition delay and burning rate of ethanol droplets are experimentally investigated. Three graphene oxide samples are synthesized and characterized. Separate high-speed…

Electronically-induced desorption from solid Ar pre-irradiated by a low-energy electron beam was investigated by activation spectroscopy methods - photon-stimulated exoelectron emission and photon-stimulated luminescence in combination with…

In this article, we report rather long time emission ($\sim$ 250 $\mu s$) from aluminum neutrals (Al I) in ns laser produced plasma in the presence of ambient argon. The study is carried out with varying laser power density, background…

Plasma Physics · Physics 2022-03-24 Garima Arora , Jinto Thomas , Hem Chandra Joshi

Metal heteroatoms dispersed in nitrogen-doped graphene display promising catalytic activity for fuel cell reactions such as the hydrogen evolution reaction (HER). Here we explore the effects of dopant concentration on the synergistic…

The role of charged centers in radiation-induced phenomena occurring in solid nitrogen irradiated with an electron beam was studied. The experiments were performed employing luminescence method and activation spectroscopy techniques -…

We investigate the dynamics of Na clusters embedded in Ar matrices. We use a hierarchical approach, accounting microscopically for the cluster's degrees of freedom and more coarsely for the matrix. The dynamical polarizability of the Ar…

Other Condensed Matter · Physics 2009-11-13 M. Baer , G. Bousquet , P. M. Dinh , F. Fehrer , P. -G. Reinhard , E. Suraud

The formation of ordered phases of dimethyl-disulfide on the Au(111) surface has been investigated by means of Low-Energy Electron Diffraction (LEED), X-ray Photoemission Spectroscopy (XPS), and state-of-the-art Density Functional Theory…

Condensed Matter · Physics 2007-05-23 V. De Renzi , D. Marchetto , R. Biagi , U. del Pennino , R. Di Felice , A. Selloni

The dynamics of polarized fluorescence in NADH at 460 nm under two-photon excitation at 720 nm by femtosecond laser pulses in water-methanol solutions has been studied experimentally and theoretically as a function of methanol…

Pillared Graphene Frameworks are a novel class of microporous materials made by graphene sheets separated by organic spacers. One of their main features is that the pillar type and density can be chosen to tune the material properties. In…

Materials Science · Physics 2017-07-04 Andrea Pedrielli , Simone Taioli , Giovanni Garberoglio , Nicola Maria Pugno

Enabled by the addition of a TOF detector system in 2010, the first phase of the Beam Energy Scan (BES-I) at RHIC allows STAR to conduct an unprecedented energy-dependent study of dielectron production within a homogeneous experimental…

Nuclear Experiment · Physics 2017-04-24 Patrick Huck

This experimental study addresses the re-initiation mechanism of detonation waves following the Mach reflection of a shock-flame complex. The detonation diffraction around a cylinder is used to reproducibly generate the shock-flame complex…

We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…

Astrophysics · Physics 2007-05-23 B. Parise , A. Castets , E. Herbst , E. Caux , C. Ceccarelli , I. Mukhopadhyay , A. G. G. M. Tielens

For thermonuclear flashes to occur on neutron-star surfaces, fuel must have been accreted from a donor star. However, sometimes flashes are seen from transient binary systems when they are thought to be in their quiescent phase, during…

Astrophysics · Physics 2015-05-13 E. Kuulkers , J. J. M. in 't Zand , J. -P. Lasota

Absorption and emission lines originating from the nu3 C-H stretching manifold of gas phase CH4 were discovered in the high resolution (R=25,000) infrared L band spectrum along the line of sight toward NGC 7538 : IRS9. These observations…

Astrophysics · Physics 2016-08-30 A. C. A. Boogert , G. A. Blake , K. Oberg

Aims. Excitation of far-infrared and submillimetric molecular lines may originate from nonreactive collisions, chemical formation, or far infrared, near-infrared, and optical fluorescences. As a template, we investigate the impact of each…

Astrophysics of Galaxies · Physics 2015-06-12 Benjamin Godard , José Cernicharo

The dynamics of desorption from a submonolayer of adsorbed atoms or ions are significantly influenced by the absence or presence of lateral diffusion of the adsorbed particles. When diffusion is present, the adsorbate configuration is…

Chemical Physics · Physics 2013-10-18 Tjipto Juwono , Per Arne Rikvold

Methane (CH4) pyrolysis is a promising route to co-produce hydrogen (H2) and carbon black (CB) while avoiding emissions associated with steam-methane reforming and furnace black processes. Model development of pyrolytic CB synthesis…

The isotope effect in the scattering of methane is studied by wavepacket simulations of oriented CH4 and CD4 molecules from a flat surface including all nine internal vibrations. At a translational energy up to 96 kJ/mol we find that the…

Chemical Physics · Physics 2009-11-06 R. Milot , A. P. J. Jansen