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We consider self-avoiding walks terminally attached to a surface at which they can adsorb. A force is applied, normal to the surface, to desorb the walk and we investigate how the behaviour depends on the vertex of the walk at which the…

Statistical Mechanics · Physics 2019-08-01 C J Bradly , EJ Janse van Rensburg , A L Owczarek , S G Whittington

We investigate polymers pulled away from an interacting surface, where the force is applied to the untethered endpoint and at an angle $\theta$ to the surface. We use the canonical self-avoiding walk model of polymers and obtain the phase…

Soft Condensed Matter · Physics 2026-03-03 C J Bradly , N R Beaton , A L Owczarek

A linear polymer grafted to a hard wall and underneath an AFM tip can be modelled in a lattice as a grafted lattice polymer (or self-avoiding walk) compressed underneath a piston approaching the wall. As the piston approaches the wall the…

Soft Condensed Matter · Physics 2023-08-16 EJ Janse van Rensburg

We consider a self-avoiding walk model of polymer adsorption where the adsorbed polymer can be desorbed by the application of a force. In this paper the force is applied normal to the surface at the last vertex of the walk. We prove that…

Mathematical Physics · Physics 2015-06-16 E. J. Janse van Rensburg , S. G. Whittington

We study various self-avoiding walks (SAWs) which are constrained to lie in the upper half-plane and are subjected to a compressive force. This force is applied to the vertex or vertices of the walk located at the maximum distance above the…

Mathematical Physics · Physics 2021-12-20 Nicholas R. Beaton , Anthony J. Guttmann , Iwan Jensen , Gregory F. Lawler

We consider a self-avoiding walk model of polymer adsorption where the adsorbed polymer can be desorbed by the application of a force, concentrating on the case of the square lattice. Using series analysis methods we investigate the…

Statistical Mechanics · Physics 2015-06-17 Anthony J. Guttmann , Iwan Jensen , Stu G. Whittington

The present paper is dedicated to the 2-dimensional Interacting Partially Directed Self Avoiding Walk constrained to remain in the upper-half plan and interacting with the horizontal axis. The model has been introduced in \cite{F90} to…

Probability · Mathematics 2020-09-22 Alexandre Legrand , Nicolas Pétrélis

We consider the phase diagram of self-avoiding walks (SAW) on the simple cubic lattice subject to surface and bulk interactions, modeling an adsorbing surface and variable solvent quality for a polymer in dilute solution, respectively. We…

Statistical Mechanics · Physics 2019-06-19 C J Bradly , A L Owczarek , T Prellberg

We investigate the phase diagram of a self-avoiding walk model of a 3-star polymer in two dimensions, adsorbing at a surface and being desorbed by the action of a force. We show rigorously that there are four phases: a free phase, a…

Statistical Mechanics · Physics 2019-05-14 C J Bradly , E J Janse van Rensburg , A L Owczarek , S G Whittington

In order to study long chain polymers many lattice models accommodate a pulling force applied to a particular part of the chain, often a free endpoint. This is in addition to well-studied features such as energetic interaction between the…

Statistical Mechanics · Physics 2023-07-19 C. J. Bradly , A. L. Owczarek

We consider a simple cubic lattice self-avoiding walk model of 3-star polymers adsorbed at a surface and then desorbed by pulling with an externally applied force. We determine rigorously the free energy of the model in terms of properties…

Statistical Mechanics · Physics 2018-05-09 EJ Janse van Rensburg , S G Whittington

Single three dimensional polymers confined to a slab, i.e. to the region between two parallel plane walls, are studied by Monte Carlo simulations. They are described by $N$-step walks on a simple cubic lattice confined to the region $1 \le…

Soft Condensed Matter · Physics 2009-11-10 Hsiao-Ping Hsu , Peter Grassberger

We study via Monte Carlo simulation a generalisation of the so-called vertex interacting self-avoiding walk (VISAW) model on the square lattice. The configurations are actually not self-avoiding walks but rather restricted self-avoiding…

Statistical Mechanics · Physics 2016-10-27 A Bedini , A L Owczarek , T Prellberg

Polymers in confined spaces lose conformational entropy. This induces a net repulsive entropic force on the walls of the confining space. A model for this phenomenon is a lattice walk between confining walls, and in this paper a model of an…

Statistical Mechanics · Physics 2016-05-04 E. J. Janse van Rensburg , T. Prellberg

We study self-avoiding walks on the square lattice restricted to a square box of side $L$ weighted by a length fugacity without restriction of their end points. This models a confined polymer in dilute solution. The model admits a phase…

Statistical Mechanics · Physics 2022-07-22 C. J. Bradly , A. L. Owczarek

The phase structure of self-avoiding polymerized membranes is studied by extensive Hybrid Monte Carlo simulations. Several folding transitions from the flat to a collapsed state are found. Using a suitable order parameter and finite size…

Condensed Matter · Physics 2009-10-28 Christian Münkel , Dieter W. Heermann

Stretched polymers with attractive interaction are studied in two and three dimensions. They are described by biased self-avoiding random walks with nearest neighbour attraction. The bias corresponds to opposite forces applied to the first…

Statistical Mechanics · Physics 2009-11-07 Peter Grassberger , Hsiao-Ping Hsu

In the present paper, we consider the interacting partially-directed self-avoiding walk (IPDSAW) attracted by a vertical wall. The IPDSAW was introduced by Zwanzig and Lauritzen (J. Chem. Phys., 1968) as a manner of investigating the…

Probability · Mathematics 2025-02-07 Elric Angot , Nicolas Pétrélis , Julien Poisat

Self-avoiding walks are a simple and well-known model of long, flexible polymers in a good solvent. Polymers being pulled away from a surface by an external agent can be modelled with self-avoiding walks in a half-space, with a Boltzmann…

Statistical Mechanics · Physics 2015-06-22 Nicholas R. Beaton

In this paper, we investigate a model for a $1+1$ dimensional self-interacting and partially directed self-avoiding walk, usually referred to by the acronym IPDSAW. The interaction intensity and the free energy of the system are denoted by…

Probability · Mathematics 2015-07-29 P. Carmona , G. B. Nguyen , N. Pétrélis
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