English

Critical scaling of lattice polymers confined to a box without endpoint restriction

Statistical Mechanics 2022-07-22 v2

Abstract

We study self-avoiding walks on the square lattice restricted to a square box of side LL weighted by a length fugacity without restriction of their end points. This models a confined polymer in dilute solution. The model admits a phase transition between an `empty' phase, where the average length of walks are finite and the density inside large boxes goes to zero, to a `dense' phase, where there is a finite positive density. We prove various bounds on the free energy and develop a scaling theory for the phase transition based on the standard theory for unconstrained polymers. We compare this model to unrestricted walks and walks that whose endpoints are fixed at the opposite corners of a box, as well as Hamiltonian walks. We use Monte Carlo simulations to verify predicted values for three key exponents: the density exponent α=1/2\alpha=1/2, the finite size crossover exponent 1/ν=4/31/\nu=4/3 and the critical partition function exponent 2η=43/242-\eta=43/24. This implies that the theoretical framework relating them to the unconstrained SAW problem is valid.

Keywords

Cite

@article{arxiv.2111.10993,
  title  = {Critical scaling of lattice polymers confined to a box without endpoint restriction},
  author = {C. J. Bradly and A. L. Owczarek},
  journal= {arXiv preprint arXiv:2111.10993},
  year   = {2022}
}

Comments

17 pages, 7 figures