Forces and pressures in adsorbing partially directed walks
Abstract
Polymers in confined spaces lose conformational entropy. This induces a net repulsive entropic force on the walls of the confining space. A model for this phenomenon is a lattice walk between confining walls, and in this paper a model of an adsorbing partially directed walk is used. The walk is placed in a half square lattice with boundary , and confined between two vertical parallel walls, which are vertical lines in the lattice, a distance apart. The free energy of the walk is determined, as a function of , for walks with endpoints in the confining walls and adsorbing in . This gives the entropic force on the confining walls as a function of . It is shown that there are zero force points in this model and the locations of these points are determined, in some cases exactly, and in other cases asymptotically.
Keywords
Cite
@article{arxiv.1509.07165,
title = {Forces and pressures in adsorbing partially directed walks},
author = {E. J. Janse van Rensburg and T. Prellberg},
journal= {arXiv preprint arXiv:1509.07165},
year = {2016}
}