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The influence of departures from local thermodynamic equilibrium (LTE) on neutral sulfur lines is considered. A grid of corrections is proposed to take into account the influence of departures from LTE for neutral sulfur lines in the…

Solar and Stellar Astrophysics · Physics 2025-03-18 S. A. Korotin , K. O. Kiselev

The newfound ability to detect SO2 in exoplanet atmospheres presents an opportunity to measure sulfur abundances and so directly test between competing modes of planet formation. In contrast to carbon and oxygen, whose dominant molecules…

Earth and Planetary Astrophysics · Physics 2023-08-02 Ian J. M. Crossfield

Sulphur-bearing species are often used to probe the evolution of hot cores since their abundances are particularly sensitive to physical and chemical variations. However, the chemistry of sulphur is not well understood in these regions,…

Solar and Stellar Astrophysics · Physics 2017-12-01 Thomas H. G. Vidal , Valentine Wakelam

In this paper we present kinetic properties such as migration and decomposition barriers of hydrogen defects in silicon calculated by Density Functional Theory (DFT) based methods. We study the following defects: H atoms (H) and ions (H+,…

Materials Science · Physics 2011-11-29 Liviu Bilteanu , Mathias Posselt , Jean-Paul Crocombette

Sulfur-bearing species play crucial roles in atmospheric physical-chemical processes, atmosphere-surface interactions, and the geological evolution of Venus. This chapter provides a comprehensive overview of (1) instrumental data on the…

Earth and Planetary Astrophysics · Physics 2026-05-20 Mikhail Zolotov

Experimental data on the viscosity and self-diffusion coefficient of two metallic compounds in their fluid phases, i.e. potassium and thallium, are modeled using the translational elastic mode theory which has been successfully applied to…

Statistical Mechanics · Physics 2022-01-21 F. Aitken , F. Volino

Gas phase Elemental abundances in molecular CloudS (GEMS) is an IRAM 30m large program aimed at determining the elemental abundances of carbon (C), oxygen (O), nitrogen (N), and sulfur (S) in a selected set of prototypical star-forming…

High resolution UVES spectra of 40 main-sequence stars with -3.3 < [Fe/H] < -1.0 are used to derive S, Fe and Zn abundances from lines in the 400 - 950 nm region. For one star we also present novel observations of the SI triplet at 1.046…

Astrophysics · Physics 2009-11-13 P. E. Nissen , C. Akerman , M. Asplund , D. Fabbian , F. Kerber , H. U. Kaufl , M. Pettini

Recent analysis of Gemini-North/NIFS H-band (1.45 - 1.8 $\mu$m) observations of Uranus, recorded in 2010, with recently updated line data has revealed the spectral signature of hydrogen sulphide (H$_2$S) in Uranus's atmosphere (Irwin et…

Earth and Planetary Astrophysics · Physics 2018-12-14 Patrick G. J. Irwin , Daniel Toledo , Ryan Garland , Nicholas A. Teanby , Leigh N. Fletcher , Glenn S. Orton , Bruno Bézard

Ionic liquids have proved to be excellent heat transfer fluids and alternatives to common HTFs used in industries for heat exchangers and other heat transfer equipment. However, its industrial utilization depends on the cost per kg of its…

Hydrogen-rich compounds have been extensively studied both theoretically and experimentally in the quest for novel high-temperature superconductors. Reports on sulfur-hydride attaining metallicity under pressure and exhibiting…

The nonstoichiometric NaxCoO2 system exhibits extraordinary physical properties that correlate with temperature and Na concentration in its layered lattice without evident long-range structure modification when conventional crystallographic…

Strongly Correlated Electrons · Physics 2009-11-10 H. X. Yang , C. J. Nie , Y. G. Shi , H. C. Yu , S. Ding , Y. L. Liu , D. Wu , N. L. Wang , J. Q. Li

The hydroxide anion plays an essential role in many chemical and biochemical reactions. But a molecular-scale description of its hydration state, and hence also its transport, in water is currently controversial. The statistical mechanical…

Chemical Physics · Physics 2009-09-29 D. Asthagiri , Lawrence R. Pratt , J. D. Kress , Maria A. Gomez

Supercooled liquids and dense colloids exhibit anomalous behaviour known as "spatially heterogeneous dynamics" (SHD), which becomes increasingly pronounced with approach to the glass transition. Recently, SHD has been observed in confined…

Soft Condensed Matter · Physics 2010-12-23 Aaron S. Keys , Adam R. Abate , Sharon C. Glotzer , Douglas J. Durian

The recent detection of refractory molecules in massive star-forming regions provides a means of probing the innermost regions of disks around massive stars. These detections also make it possible to explore the chemical composition of…

Sulphur is a volatile alpha-element which is not locked into dust grains in the interstellar medium (ISM). Hence, its abundance does not need to be corrected for dust depletion when comparing the ISM to the stellar atmospheres. The…

Astrophysics of Galaxies · Physics 2015-05-18 Elisabetta Caffau , Luca Sbordone , Hans-Günter Ludwig , Piercarlo Bonifacio , Monique Spite

Superconductive H3S synthesized from H2S is very poorly crystallized, and has excess sulfur as impurity (3H2S -> 2H3S + S). The phase transition process undergoes in sulfur excess condition, which might cause hydrogen deficiency. The…

The recent report of superconductivity under high pressure at the record transition temperature of Tc=203K in sulfur hydride has been identified as conventional in view of the observation of an isotope effect upon deuteration. Here it is…

Superconductivity · Physics 2016-05-24 Annette Bussmann-Holder , Jurgen Kohler , M. -H. Whangbo , Antonio Bianconi , Arndt Simon

A recent version of statistical associating fluid theory (SAFT), namely SAFT2, is coupled with the van der Waals and Platteeuw theory to study the alkane hydrate phase equilibrium conditions. The model is found to provide an accurate…

Soft Condensed Matter · Physics 2017-05-22 Hao Jiang

Sulphur-bearing species play crucial roles in interstellar chemistry, yet their precise characterisation remains challenging. Here, we present laboratory experiments aimed at extending the high-resolution spectroscopy of protonated carbonyl…

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