Related papers: Quantifying sulfur speciation in magmatic-hydrothe…
We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and…
The sulfur abundance is poorly known in most environments. Yet, deriving the sulfur abundance is key to understanding the evolution of the chemistry from molecular clouds to planetary atmospheres. We present observations of H$_2$S 110-101…
Potassium sulfate single crystals that are grown from aqueous solutions lose upon the first heating up to 1% of mass that is assumed to be water. This mass loss occurs in the vicinity of the PT from orthorhombic to hexagonal K2SO4. Only in…
We present results of \textit{ab initio} molecular dynamics study of a structural transformation occurring in hot liquid sulfur under high pressure, which corresponds to the chain-breakage phenomenon recently observed experimentally by Liu…
The high cosmic abundance and the intermediate volatility and chemical properties of sulfur allow the use of sulfur-bearing species as a tracer of the chemical processes in the atmospheres of hot Jupiter exoplanets. Nevertheless, despite…
We study the content in S-bearing molecules of protoplanetary disks around low-mass stars. We used the new IRAM 30-m receiver EMIR to perform simultaneous observations of the $1_{10}-1_{01}$ line of H$_2$S at 168.8 GHz and $2_{23}-1_{12}$…
This work aims to study the unexplained sulfur depletion observed toward dense clouds and protostars. We made simulation experiments of the UV-photoprocessing and sublimation of H2S and H2S:H2O ice in dense clouds and circumstellar regions,…
To date, gas phase observations of sulphur in dense interstellar environments have only constrained the molecular carriers of 1% of its predicted cosmic abundance. An additional 5% is known to be locked up in molecular solids in dense…
Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…
Sulfur appears to be depleted by an order of magnitude or more from its elemental abundance in star-forming regions. In the last few years, numerous observations and experiments have been performed in order to to understand the reasons…
Grain-surface chemistry plays a crucial role in the formation of molecules of astrobiological interest, including H$_{2}$S and complex organic molecules (COMs). They are commonly observed in the gas phase toward star-forming regions, but…
We study several molecules that could help in the solution of the missing sulfur problem in dense clouds and circumstellar regions, as well as in the clarification of the sulfur chemistry in comets. These sulfur molecules are: the trimer…
JWST has revealed sulfur chemistry in giant exoplanet atmospheres, where molecules such as SO2 trace photochemistry, metallicity, and formation and migration. To ascertain the conditions that determine whether (or how much) SO2, H2S, and…
Here we report the polarization dependent non-resonant second harmonic generation (SHG) measurement of the interfacial water molecules at the aqueous solution of the following salts: NaF, NaCl, NaBr, KF, KCl, and KBr. Through quantitative…
Recent discovery of high-temperature superconductivity (Tc = 190 K) in sulfur hydrides at megabar pressures breaks the traditional belief on the Tc limit of 40 K for conventional superconductors, and open up the doors in searching new…
We report ISO SWS infrared spectroscopy of the H II region Hubble V in NGC 6822 and the blue compact dwarf galaxy I Zw 36. Observations of Br alpha, [S III] at 18.7 and 33.5 microns, and [S IV] at 10.5 microns are used to determine ionic…
(Abridged) Sulfur chemistry is poorly understood in the process of low-mass star and planet formation, where the main carriers of sulfur are still unknown. Despite the fact that simple S-bearing molecules are usually detected toward…
Sulfur-water chemistry plays an important role in the middle atmosphere of Venus. Ground based observations have found that simultaneously observed SO2 and H2O at ~64 km vary with time and are temporally anti-correlated. To understand these…
Hf substitution stabilizes the metastable body-centered cubic (bcc) $\alpha$-UH$3$ phase in uranium hydrides, enabling systematic measurements of its magnetic, thermodynamic, and transport properties. (UH$3$)${1-x}$Hf$x$ hydrides ($x =…
Sulphur is an element which is formed in the alpha-process and is easily measured in the gaseous phase in external galaxies. Since it does not form dust, it is the preferred indicator for alpha-elements, rather than Si or Mg, for which dust…