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We study the gap closure with pressure of crystalline molecular hydrogen. The gaps are obtained from grand-canonical Quantum Monte Carlo methods properly extended to quantum and thermal crystals, simulated by Coupled Electron Ion Monte…

Materials Science · Physics 2020-03-25 Vitaly Gorelov , Markus Holzmann , David M. Ceperley , Carlo Pierleoni

We construct the integral transform passing from the space representation to the momentum representation for the Hydrogen atom using polar spherical coordinates. The resulting radial wave functions are explicitly given in terms of complex…

Quantum Physics · Physics 2023-03-15 M. Kirchbach , J. A. Vallejo

Supercooled water is expected to exhibit a liquid--liquid phase transition between low- and high-density liquid states, possibly terminating in a liquid--liquid critical point in the experimentally difficult no man's land. Because the…

Chemical Physics · Physics 2026-05-20 Michael Beerbaum , Julian Heske , Jure Gujt , Thomas D. Kühne

For rovibronic states corresponding to the $B$ and $B'\ ^1\Sigma_\text{u}^+$ electronic states of the hydrogen molecule, the pre-Born--Oppenheimer (four-particle) non-relativistic energy is converged to a 1-3 parts-per-billion relative…

Chemical Physics · Physics 2023-01-10 Eszter Saly , Dávid Ferenc , Edit Mátyus

Establishing the phase diagram of hydrogen is a major challenge for experimental and theoretical physics. Experiment alone cannot establish the atomic structure of solid hydrogen at high pressure, because hydrogen scatters X-rays only…

Atomic hydrogen energy levels calculated to high precision are required to assist experimental researchers working on spectroscopy in the pursuit of testing quantum electrodynamics (QED) and probing for physics beyond the Standard Model.…

Atomic Physics · Physics 2023-09-12 David M. Jacobs , Marko Horbatsch

Hydrogen is the most abundant element in the universe. It is also the lightest and as such the most quantum of the elements, in the sense that quantum tunnelling, quantum delocalisation, and zero-point motion can be important. For practical…

Chemical Physics · Physics 2019-01-18 Wei Fang , Ji Chen , Yexin Feng , Xin-Zheng Li , Angelos Michaelides

Analytical approximations are constructed for binding energies, quantum-mechanical sizes and oscillator strengths of main radiative transitions of hydrogen atoms arbitrarily moving in magnetic fields 10^{12}-10^{13} G. Examples of using the…

Atomic Physics · Physics 2009-10-30 A. Y. Potekhin

It is believed that one of the first useful applications for a quantum computer will be the preparation of groundstates of molecular Hamiltonians. A crucial task involving state preparation and readout is obtaining physical observables of…

We study the Hydrogen atom as a quantum mechanical system with a Coulomb like potential, with a semiclassical approach based on an effective description of quantum mechanics. This treatment allows us to describe the quantum state of the…

Quantum Physics · Physics 2012-03-23 Guillermo Chacón-Acosta , Héctor H. Hernández

With recent developments in simulating nonadiabatic systems to high accuracy, it has become possible to determine how much energy is attributed to nuclear quantum effects beyond zero-point energy. In this work we calculate the…

Chemical Physics · Physics 2016-08-23 Yubo Yang , Ilkka Kylanpaa , Norm Tubman , Jaron Krogel , Sharon Hammes-Schiffer , David Ceperley

Nuclear-structure effects often provide an irreducible theory error that prevents using precision atomic measurements to test fundamental theory. We apply newly developed effective field theory tools to Hydrogen atoms, and use them to show…

High Energy Physics - Phenomenology · Physics 2021-02-03 C. P. Burgess , P. Hayman , Markus Rummel , László Zalavári

In Part one of this Paper a hypothesis is forwarded of the electron charge in an atom existing in a distributed form. To check it by methods of electrodynamics and mechanics (without invoking the formalism of quantum mechanics and the…

General Physics · Physics 2013-05-29 Andrey Vasilyev

Nuclear quantum effects are essential for correctly describing hydrogen-rich materials at high pressures. Superconducting hydrides and ice are prime examples of such systems, requiring the inclusion of lattice anharmonicity and nuclear…

Taking into account results of WKB-approximation, we derive exact quantum energies and wave functions of even and odd states in the one-dimensional Coulomb potential

Quantum Physics · Physics 2019-02-07 A. M. Ishkhanyan , V. P. Krainov

Precise solutions of the Hartree-Fock equations for the ground state of the hydrogen molecule are obtained for a wide range of internuclear distances R by means of a two-dimensional fully numerical mesh computational method. The spatial…

Atomic Physics · Physics 2007-05-23 Mikhail V. Ivanov

We construct wave packets for the hydrogen atom labelled by the classical action-angle variables with the following properties. i) The time evolution is exactly given by classical evolution of the angle variables. (The angle variable…

Quantum Physics · Physics 2009-10-30 Pushan Majumdar , H. S. Sharatchandra

A new model of quantum mechanics, Classical Quantum Mechanics, is based on the (nearly heretical) postulate that electrons are physical objects that obey classical physical laws. Indeed, ionization energies, excitation energies etc. are…

Plasma Physics · Physics 2008-10-30 Jonathan Phillips

Neutron Compton Scattering measurements presented here of the momentum distribution of hydrogen in $KH_2PO_4$ (KDP) just above and well below the ferroelectric transition temperature show clearly that the proton is coherent over both sites…

Statistical Mechanics · Physics 2009-11-07 G. F. Reiter , J. Mayers , P. Platzman

Different kinds of averaging of the wavefunctions/densities of the two-electron atomic systems are investigated. Using the Pekeris-like method, the ground state wave functions $\Psi$ of the helium-like atoms with nucleus charge $1\leq…

Atomic Physics · Physics 2020-04-22 Evgeny Liverts , Rajmund Krivec
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