Averaged electron densities of the helium-like atoms
Abstract
Different kinds of averaging of the wavefunctions/densities of the two-electron atomic systems are investigated. Using the Pekeris-like method, the ground state wave functions of the helium-like atoms with nucleus charge are calculated in a few coordinate systems including the hyperspherical coordinates . The wave functions of the hyperspherical radius are calculated numerically by averaging over the hyperspherical angles and . The exact analytic representations for the relative derivatives and are derived. Analytic approximations very close to the actual are obtained. Using actual wave functions , the one-electron densities are calculated as functions of the electron-nucleus distance . The relevant derivatives and characterizing the behavior of near the nucleus are calculated numerically. Very accurate analytical approximations, representing the actual one-electron density both near the nucleus and far away from it, are derived. All the analytical and numerical results are supplemented with tables and graphs.
Keywords
Cite
@article{arxiv.1908.00843,
title = {Averaged electron densities of the helium-like atoms},
author = {Evgeny Liverts and Rajmund Krivec},
journal= {arXiv preprint arXiv:1908.00843},
year = {2020}
}
Comments
29 pages, 7 figures, 3 tables