Related papers: How chiral vibrations drive molecular rotation
Chirality is a pervasive form of symmetry that is intimately connected to the physical properties of solids, as well as the chemical and biological activity of molecular systems. However, its control with light is challenging, because…
In the present work we theoretically analyze electroluminescence occurring in a biased single-molecule junction with a chiral bridge imitated by a helical chain. We show that optical transitions between electron states of the chiral linker…
Semiclassical oscillation of the electron through the nucleus of the H atom yields both the exact energy and the correct orbital angular momentum for l=0 quantum states. Similarly, electron oscillation through the nuclei of H2+ accounts for…
Molecular chirality and electron spin are intricately intertwined via the fascinating phenomenon of chiral-induced spin selectivity (CISS), which has garnered considerable attention due to its extensive potential applications. A recent…
We consider optical properties of a gas of molecules that are brought to fast unidirectional spinning by a pulsed laser field. It is shown that a circularly polarized probe light passing through the medium inverts its polarization…
Active hydrodynamic theories are a powerful tool to study the emergent ordered phases of internally driven particles such as bird flocks, bacterial suspension and their artificial analogues. While theories of orientationally ordered phases…
Planar chiral structures possess a two dimensional handedness that is associated with broken mirror symmetry. Such motifs span vast length scales; examples include certain pinwheel molecules, nautilus shells, cyclone wind patterns and…
Polar molecules in selected quantum states can be guided, decelerated, and trapped using electric fields created by microstructured electrodes on a chip. Here we explore how transitions between two of these quantum states can be induced…
Chiral active matter is a variant of active matter systems in which the motion of the constituent particles violates mirror symmetry. In this letter, we simulate two-dimensional chiral Active Brownian Particles, the simplest chiral model in…
To a phenomenological core described by the Generalized Coherent State Model a set of interacting particles are coupled. Among the particle-core states one identifies a finite set which have the property that the angular momenta carried by…
Nonadiabatic phenomena are investigated in the rovibrational motion of molecules confined in an infrared cavity. Conical intersections (CIs) between vibrational polaritons, similar to CIs between electronic polaritonic surfaces, are found.…
We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately-designed…
Chirality arises from the asymmetry of matters, where two counterparts are the mirror image of each other. The interaction between circular-polarization light and quantum materials is enhanced in chiral space groups due to the structural…
Controlling the polarization state of electromagnetic radiation enables the investigation of fundamental symmetry properties of matter through chiroptical processes. Many strategies have been developed to reveal structural or dynamical…
Chiral light-matter interactions can enable polarization to control the direction of light emission in a photonic device. Most realizations of chiral light-matter interactions require external magnetic fields to break time-reversal symmetry…
A theoretical framework is presented for the computation of rovibrational polaritonic states of a molecule in a lossless infrared (IR) microcavity. In the proposed approach the quantum treatment of the rotational and vibrational motion of…
A misconception that non-chiral molecules have no optical activity at all is widespread. However, at molecular level even non-chiral molecules have optical activity. Optical activity of a non-chiral molecule is canceled out by that of…
In this paper, we discuss microscopic models for chiral active particles, i.e., rotating active units that exhibit circular or spinning motion. While non-chiral active particles are typically governed by self-propulsion and conservative…
Drawing inspiration from a remarkable chiral force found in nature, we show that a static electric field combined with an optical lin$\perp$lin polarization standing wave can exert a chiral optical force on a small chiral molecule that is…
The interaction of a diatomic molecule with photons carrying well-defined angular momentum and parity is investigated to determine whether photon absorption can induce molecular rotational transitions between states having angular momentum…