Related papers: How chiral vibrations drive molecular rotation
The dynamics of non-polar diatomic molecules interacting with a far-detuned narrow-band laser field, that only may drive rotational transitions, is studied. The rotation of the molecule is considered both classically and quantum…
We introduce chiral rotational spectroscopy: a new technique that enables the determination of the orientated optical activity pseudotensor components $B_{XX}$, $B_{YY}$ and $B_{ZZ}$ of chiral molecules, in a manner that reveals the…
We discuss the electronic transport through molecules in the Kondo regime. We concentrate here on the influence of molecular vibrations. Two types of vibrations are investigated: (i) the breathing internal molecular modes, where the…
We explore a pure optical method for enantioselective orientation of chiral molecules by means of laser fields with twisted polarization. Several field implementations are considered, including a pair of delayed cross-polarized laser…
We theoretically explore the dynamics of a chiral active Ornstein Uhlenbeck particle confined in a two-dimensional anisotropic harmonic trap. The particle is driven by chirality and is coupled to two orthogonal heat baths, potentially at…
We present a detailed analysis of the molecular kinetics of CHCl$_3$ in a range of temperatures covering the solid and liquid phases. Using nuclear quadrupolar resonance we determine the relaxation times for the molecular rotations in solid…
Right- and left-handed circularly polarized light interact differently with electronic charges in chiral materials. This asymmetry generates the natural circular dichroism and gyrotropy, also known as the optical activity. Here we…
Despite generally lacking ferromagnetic properties or strong spin-orbit coupling, electrons in chiral molecules exhibit unique spin-dependent transport behavior, known as chiral-induced spin selectivity (CISS). This phenomenon implies a…
The rotation of polarization occurs for light interacting with chiral materials. It requires the light states with opposite chiralities interact differently with the materials. We demonstrate analogous rotation of polarization also exists…
Polar active particles constitute a wide class of synthetic colloids that are able to propel along a preferential direction, given by their polar axis. Here, we demonstrate a generic self-phoretic mechanism that leads to their spontaneous…
We consider bosonic dipolar molecules in an optical lattice prepared in a mixture of different rotational states. The 1/r^3 interaction between molecules for this system is produced by exchanging a quantum of angular momentum between two…
We show that combined electrostatic and radiative fields can greatly amplify the directional properties, such as axis orientation and alignment, of symmetric top molecules. In our computational study, we consider all four symmetry…
Vibrational polaritons, hybrid light-matter states formed between molecular vibrations and infrared (IR) cavity modes, provide a novel approach for modifying chemical reaction pathways and energy transfer processes. For vibrational…
We examine the dynamics of chiral states of chiral molecules with high tunneling rates in dilute and condensed phases in the context of time-dependent perturbation theory. The chiral molecule is effectively described by an asymmetric…
Charge and spin dynamics is addressed in chiral molecules immediately after the instantaneous coupling to an external metallic reservoir. It is shown how a spin-polarization is induced in the chiral structure as a response to the charge…
The dynamics of chiral nuclei is investigated for the first time with the time-dependent and tilted axis cranking covariant density functional theories on a three-dimensional space lattice in a microscopic and self-consistent way. The…
We revisit the chiral properties of nucleon interpolating currents, and show that of the two leading order currents $j_1$ and $j_2$, only two linear combinations $j_1\pm j_2$ transform covariantly under the anomalous $U(1)_A$ symmetry. As a…
Chiral molecules form a number of non-chiral structures, the simplest being an isotropic fluid phase. In a mesophase of achiral molecules the fluctuations will on average be achiral as well: left-handed twists and right-handed twists will…
We show that a nonchiral atom can act as an antenna to induce a photoelectron circular dichroism in a nearby chiral molecule in a three-step process: The donor atom (antenna) is initially resonantly excited by circularly polarized…
Chirality is a recurrent theme in the study of biological systems, in which active processes are driven by the internal conversion of chemical energy into work. Bacterial flagella, acto-myosin filaments and microtubule bundles are active…