Related papers: How chiral vibrations drive molecular rotation
The behavior of the collective rotor in the chiral motion of triaxially deformed nuclei is investigated using the particle rotor model by transforming the wave functions from the $K$-representation to the $R$-representation. After examining…
Correlation among particles in finite quantum systems leads to complex behaviour and novel states of matter. One remarkable example is predicted to occur in a semiconductor quantum dot (QD) where at vanishing density the Coulomb correlation…
Exploring the limits of the microscopic reversibility principle, we investigated the interplay between thermal and electron tunneling excitations for the unidirectional rotation of a molecule-rotor on the Au(111) surface. We identified a…
Chiral phonons have been proposed to be involved in various physical phenomena, yet the chirality of molecular normal modes has not been well defined mathematically. Here we examine two approaches for assigning and quantifying the chirality…
Light's orbital angular momentum (OAM) is an unbounded degree of freedom emerging in helical beams that appears very advantageous technologically. Using a chiral microlaser, i.e. an integrated device that allows generating an emission…
We analyze theoretically the interplay between the torsional and the rotational motion of an aligned biphenyl-like molecule. To do so, we consider a transition between two electronic states with different internal torsional potentials,…
Chiral active materials are those that break both time-reversal symmetry and parity microscopically, which results in average rotation of the material's complex molecules around their center-of-mass (CM). These materials are far from…
We introduce a theory of chemical equilibrium in optical microcavities, which allows us to relate equilibrium reaction quotients in different electromagnetic environments. Our theory shows that in planar microcavities under strong coupling…
The rapidly rotational motion of C$_{60}$ molecules provides us with an ingenious way to test Mashhoon's spin-rotation coupling. The spin-rotation coupling of electrons in the rotating C$_{60}$ molecule is considered in the present letter.…
We study a simple model consisting of an atomic ion and a polar molecule trapped in a single setup, taking into consideration their electrostatic interaction. We determine analytically their collective modes of excitation as a function of…
We report a molecular Wankel motor, the dual-ring structure B13+, driven by circularly-polarized infrared electromagnetic radiation, under which a guided uni-directional rotation of the outer ring is achieved with rotational frequency of…
Intermolecular correlations in liquid acetonitrile (CH3CN) have been revisited by calculating orientational correlation functions. In the present approach, hydrogen atoms are included, so that a concept applicable for molecules of (nearly)…
We provide a way of generating and observing molecular quantum gyroscopic motion that resembles gyroscopic motion of classical rotors. After producing a nonspreading rotational wavepacket called a cogwheel state, one can generate a…
The rotational excitation of the three asymmetric-top molecular ion isotopologues H$_2$O$^+$, HDO$^+$, and D$_2$O$^+$ is studied theoretically using a combined framework of electron-molecule R-matrix scattering theory, multichannel…
Recently, it was predicted theoretically and verified experimentally that a pair of delayed and cross-polarized short laser pulses can create molecular ensembles with a well defined sense of rotation (clockwise or counterclockwise). Here we…
We propose a scheme to realize a pseudospin-$1/2$ model of the $^{1}\Sigma(v=0)$ bialkali polar molecules with the spin states corresponding to two sublevels of the first excited rotational level. We show that the effective dipole-dipole…
Vibrational polaritons are formed by strong coupling of molecular vibrations and photon modes in an optical cavity. Experiments have demonstrated that vibrational strong coupling can change molecular properties and even affect chemical…
In this study, we apply the monitoring master equation describing decoherence of internal states to an optically active molecule prepared in a coherent superposition of nondegenerate internal states interacting with thermal photons at low…
We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…
Magnetic phenomena are in chemistry and condensed matter physics considered to be associated with low temperatures. That a magnetic state, or order, is stable below a critical temperature as well as becoming stronger the lower the…