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The nanoscopic characterization of ferroelectric thin films is crucial from their device application point of view. Standard characterization techniques are based on detecting the nanoscopic charge compensation current (switching current)…

Materials Science · Physics 2022-10-19 Sambit Mohapatra , Wolfgang Weber , Martin Bowen , Samy Boukari , Victor Da Costa

Antiferroelectricity (AFE) is a fundamental concept in physics and materials science. Conventional AFEs have the picture of alternating local electric dipoles defined in real space. Here, we discover a new class of AFEs, termed type-II…

Materials Science · Physics 2026-03-26 Yang Wang , Zhi-Ming Yu , Chaoxi Cui , Yilin Han , Tingli He , Weikang Wu , Run-Wu Zhang , Shengyuan A. Yang , Yugui Yao

In the paper we consider size effects of phase transitions and polar properties of the thin antiferroelectric films. We modified phenomenological approach proposed by Kittel. The Euler-Lagrange equations were solved by direct variational…

Materials Science · Physics 2007-05-23 E. A. Eliseev , M. D. Glinchuk , A. N. Morozovska

Antiferroelectrics exhibit unique double-hysteresis polarization loops, which have garnered significant attention due to their potential applications such as energy storage, electromechanical transduction, as well as synapse devices.…

HfO$_{2}$-based ferroelectric thin films are promising for their application in ferroelectric devices. Predicting the ultimate magnitude of polarization and understanding its switching mechanism are critical to realize the optimal…

Materials Science · Physics 2023-04-04 Yao Wu , Yuke Zhang , Jie Jiang , Limei Jiang , Minghua Tang , Yichun Zhou , Min Liao , Qiong Yang , Evgeny Y. Tsymbal

An accurate estimate of the ferroelectric polarization in ferroelectric-dielectric stacks is important from a materials science perspective, and it is also crucial for the development of ferroelectric based electron devices. This paper…

Materials Science · Physics 2022-04-13 Mattia Segatto , Riccardo Fontanini , Francesco Driussi , Daniel Lizzit , David Esseni

Over the last fifteen years, ferroelectric and antiferroelectric ultra thin films based on fluorite-structured materials have drawn significant attention for a wide variety of applications requiring high integration density.…

Polycrystalline hafnia-based thin films exhibit mixed ferroelectric (FE), antiferroelectric (AFE), and dielectric (DE) behavior, with switching characteristics strongly influenced by microstructure and phase distribution. Here, we develop a…

Materials Science · Physics 2026-02-17 P. Pankaj , Sandeep Sugathan , Si Joon Kim , Pil-Ryung Cha

Antiferroelectrics exhibit reversible antipolar-polar phase transitions under electric fields, yielding large electrostrain suitable for electromechanical devices. Nevertheless, in thin-film form, the antiferroelectric behavior is often…

By performing standard PUND (positive-up-negative-down), hysteresis-loop and dielectric measurements on the ferroelectric lead zirconate titanate (PZT) thin-film capacitors subject to bipolar/unipolar electrical cycling, we show that…

Materials Science · Physics 2010-08-09 X. J. Lou , J. Wang

The switching characteristics of ferroelectrics and multiferroics are influenced by the interaction of topological defects with domain-walls. We report on the pinning of polarization due to antiphase boundaries in thin films of the…

Materials Science · Physics 2024-12-04 Guodong Ren , Pravan Omprakash , Xin Li , Yu Yun , Arashdeep S. Thind , Xiaoshan Xu , Rohan Mishra

The coupling between antiferrodistortion (AFD) and ferroelectric (FE) polarization, universal for all tilted perovskite multiferroics, is known to strongly correlate with domain wall functionalities in the materials. The intrinsic…

Applied Physics · Physics 2019-09-18 M. J. Han , E. A. Eliseev , A. N. Morozovska , Y. L. Zhu , Y. L. Tang , Y. J. Wang , X. W. Guo , X. L. Ma

While $Hf_{0.5}Zr_{0.5}O_2$ (HZO) thin films hold significant promise for modern nanoelectronic devices, a comprehensive understanding of the interplay between their polycrystalline structure and electrical properties remains elusive. Here,…

Materials Science · Physics 2025-01-10 Kévin Alhada-Lahbabi , Brice Gautier , Damien Deleruyelle , Grégoire Magagnin

Neuromorphic computing, inspired by biological intelligence, offers a pathway to revolutionize artificial intelligence (AI) by unifying memory and processing in an energy-efficient, sustainable framework for data-intensive tasks.…

Materials Science · Physics 2025-09-10 Xinye Li , Sayani Majumdar

The discovery of two-dimensional (2D) materials possessing switchable spontaneous polarization with atomic thickness opens up exciting opportunities to realize ultrathin, high-density electronic devices with potential applications ranging…

Materials Science · Physics 2020-11-04 Jiawei Huang , Sang-Hoon Lee , Andrew Supka , Young-Woo Son , Shi Liu

In the realm of ferroelectric memories, HfO2-based ferroelectrics stand out because of their exceptional CMOS compatibility and scalability. Nevertheless, their switchable polarization and switching speed are not on par with those of…

Under a sufficiently high applied electric field, a non-polar antiferroelectric material, such as \ce{PbZrO3}, can undergo a rapid transformation to a polar ferroelectric phase. While this behavior is promising for energy storage and…

Magnetoelectric coupling is crucial for uncovering fundamental phenomena and advancing technologies in high-density data storage and energy-efficient devices. The emergence of altermagnets, which unify the advantages of ferromagnets and…

Materials Science · Physics 2025-03-18 Xunkai Duan , Jiayong Zhang , Ziye Zhu , Yuntian Liu , Zhenyu Zhang , Igor Zutic , Tong Zhou

A wake-up free Hf0.5Zr0.5O2 (HZO) ferroelectric film with the highest remnant polarization (Pr) value to-date was achieved through tuning of the ozone pulse duration, the annealing process, and the metal/insulator interface. The ozone…

Materials Science · Physics 2021-01-14 Alireza Kashir , Hyung Woo Kim , Seungyeol Oh , Hyunsang Hwang

Antiferroelectrics have received blooming interests because of a wide range of potential applications in energy storage, solid-state cooling, thermal switch, transducer, actuation, and memory devices. Many of those applications are the most…

Materials Science · Physics 2023-12-29 Yangyang Si , Tianfu Zhang , Chenhan Liu , Sujit Das , Bin Xu , Roman G Burkovsky , Xian-Kui Wei , Zuhuang Chen
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