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We perform sensitive nuclear magnetic resonance (NMR) with spin ensembles which are polarized by nitrogen vacancy centers (NV centers) in diamond at room-temperature. With a near shot-noise-limited photoluminescence detection and a highly…

J-driven Dynamic Nuclear Polarization (JDNP) was recently proposed for enhancing the sensitivity of solution-state nuclear magnetic resonance (NMR), while bypassing the limitations faced by conventional (Overhauser) DNP at magnetic fields…

Chemical Physics · Physics 2023-01-03 Maria Grazia Concilio , Lucio Frydman

In heavy atoms and ions, nuclear structure effects are significantly enhanced due to the overlap of the electron wave functions with the nucleus. This overlap rapidly increases with the nuclear charge $Z$. We study the energy level shifts…

Atomic Physics · Physics 2021-03-17 V. V. Flambaum , I. B. Samsonov , H. B. Tran Tan , A. V. Viatkina

We present dynamic nuclear polarization (DNP) in the simplest pseudospin quantum Hall ferromagnet (QHF) of an InSb two-dimensional electron gas with a large g factor using tilted magnetic fields. The DNP-induced amplitude change of a…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 H. W. Liu , K. F. Yang , T. D. Mishima , M. B. Santos , Y. Hirayama

Optically-pumped color centers in semiconductor powders can potentially induce high levels of nuclear spin polarization in surrounding solids or fluids at or near ambient conditions, but complications stemming from the random orientation of…

The interplay between disorder and transport is a problem central to the understanding of a broad range of physical processes, most notably the ability of a system to reach thermal equilibrium. Disorder and many body interactions are known…

In dissolution-dynamic nuclear polarization, nuclear spins are hyperpolarized at cryogenic temperatures using radicals and microwave irradiation. The hyperpolarized solid is dissolved with hot solvent and the solution is transferred to a…

Instrumentation and Detectors · Physics 2019-06-20 Karel Kouřil , Hana Kouřilová , Samuel Bartram , Malcolm H. Levitt , Benno Meier

Dynamic nuclear polarization (DNP) involves a polarization transfer from unpaired electrons to hyperfine coupled nuclei and can increase the sensitivity of nuclear magnetic resonance (NMR) signals by several orders of magnitude. The…

Chemical Physics · Physics 2024-07-16 Gevin von Witte , Sebastian Kozerke , Matthias Ernst

Nuclear spin ensembles in diamond are promising candidates for quantum sensing applications, including rotation sensing. Here we perform a characterization of the optically detected nuclear-spin transitions associated with the 14N nuclear…

The nitrogen-vacancy (NV) center is a well utilized system for quantum technology, in particular quantum sensing and microscopy. Fully employing the NV center's capabilities for metrology requires a strong understanding of the behavior of…

Mesoscale and Nanoscale Physics · Physics 2019-03-13 M. S. J. Barson , P. M. Reddy , S. Yang , N. B. Manson , J. Wrachtrup , M. W. Doherty

We report {\beta} detected nuclear magnetic resonance ({\beta}NMR) measurements of 8Li+ implanted into high purity Pt. The frequency of the 8Li {\beta}NMR resonance and the spin-lattice relaxation rates 1/T1 were measured at temperatures…

We report on measurements of the photoluminescence (PL) properties of single nitrogen-vacancy (NV) centers in diamond at temperatures between 4-300 K. We observe a strong reduction of the PL intensity and spin contrast between ca. 10-100 K…

Mesoscale and Nanoscale Physics · Physics 2023-09-01 Stefan Ernst , Patrick J. Scheidegger , Simon Diesch , Luca Lorenzelli , Christian L. Degen

The study establishes that the degree of optically induced spin polarization that can be achieved for NV$^- $in 1b diamond is limited by the concentration of single substitutional nitrogen, N$^0$ . The polarization of the individual NV…

The hyperpolarisation of nuclear spins within target molecules is a critical and complex challenge in magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) spectroscopy. Hyperpolarisation offers enormous gains in signal and…

We report on a study of Dynamic Nuclear Polarization and electron and nuclear spin relaxation of atomic hydrogen and deuterium in solid molecular matrices of H$_{2}$, D$_{2}$, and HD mixtures. The electron and nuclear spin relaxation times…

Atomic and Molecular Clusters · Physics 2017-02-08 S. Sheludiakov , J. Ahokas , J. Järvinen , O. Vainio , L. Lehtonen , S. Vasiliev , D. M. Lee , V. V. Khmelenko

Enhancing the polarization of nuclear spins surrounding the nitrogen-vacancy (NV) center in diamond has attracted widespread attention recently due to its various applications. Here we present an analytical theory and comprehensive…

Quantum Physics · Physics 2016-07-15 Ping Wang , Bao Liu , Wen Yang

Here we propose and analyse in detail protocols that can achieve rapid hyperpolarization of 13C nuclear spins in randomly oriented ensembles of nanodiamonds at room temperature. Our protocols exploit a combination of optical polarization of…

Quantum Physics · Physics 2015-11-25 Q. Chen , I. Schwarz , F. Jelezko , A. Retzker , M. B. Plenio

We study the linear polarization properties of the photoluminescence of the neutral and negatively charged nitrogen vacancies and neutral vacancies in diamond crystals as function of their symmetry and their response to strong external…

Mesoscale and Nanoscale Physics · Physics 2018-03-28 D. Braukmann , V. P. Popov , E. R. Glaser , T. A. Kennedy , M. Bayer , J. Debus

We use field-cycling-assisted dynamic nuclear polarization and continuous radio-frequency (RF) driving over a broad spectral range to demonstrate magnetic-field-dependent activation of nuclear spin transport from strongly-hyperfine-coupled…

Quantum sensors have attracted broad interest in the quest towards sub-micronscale NMR spectroscopy. Such sensors predominantly operate at low magnetic fields. Instead, however, for high resolution spectroscopy, the high-field regime is…

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